Allyloxytrimethylsilane - ≥97%(GC) , CAS No.18146-00-4

CAS: 18146-00-4 Cat. No.: A151337 Molecular Weight: 130.26 Beilstein Registry Number: 1739520 EC Number: 242-031-4

GRADE & PURITY ≥97%(GC)

Synonyms

EINECS 242-031-4 | FT-0622051 | trimethyl(prop-2-en-1-yloxy)silane | Silane, trimethyl(2-propen-1-yloxy)- | 1-Trimethylsiloxy-2-propene | A0927 | 1-Trimethylsilyloxy-2-propene | Silane, (allyloxy)trimethyl- | Trimethyl Allyloxysilane | DTXSID6066319 | Me3

Storage

Argon charged,Room temperature

Shipped In

Normal

Overview

Allyloxytrimethylsilane [3-(Trimethylsiloxy)propene] was used in the synthesis of trimethylsilyl protected (3-hydroxypropyl)-trimethoxysilane.

Specifications

Synonyms

EINECS 242-031-4 | FT-0622051 | trimethyl(prop-2-en-1-yloxy)silane | Silane, trimethyl(2-propen-1-yloxy)- | 1-Trimethylsiloxy-2-propene | A0927 | 1-Trimethylsilyloxy-2-propene | Silane, (allyloxy)trimethyl- | Trimethyl Allyloxysilane | DTXSID6066319 | Me3

Specifications & Purity

≥97%(GC)

Storage

Argon charged, Room temperature

Shipped In

Normal

Purity

≥97%(GC)

Names and Identifiers

• Pubchem Sid: 504755886
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504755886
• Canonical Smiles: C[Si](C)(C)OCC=C
• IUPAC Name: trimethyl(prop-2-enoxy)silane
• InChIKey: MNMVKGDEKPPREK-UHFFFAOYSA-N
• INCHI: 1S/C6H14OSi/c1-5-6-7-8(2,3)4/h5H,1,6H2,2-4H3
• Isomeric SMILES: C[Si](C)(C)OCC=C
• WGK Germany: 3
• UN Number: 1993
• Packing Group: III
• Molecular Weight: 130.26
• Beilstein: 1739520
• Reaxy-Rn: 1739517
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1739517&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Class Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Organoheterosilanes
          • Level6 Trialkylheterosilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Class: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Organoheterosilanes
• Direct Parent: Trialkylheterosilanes
• Alternative Parents: Silyl ethers Organic metalloid salts Organooxygen compounds Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkylheterosilane - Silyl ether - Organic metalloid salt - Organic oxygen compound - Hydrocarbon derivative - Organic salt - Organooxygen compound - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as trialkylheterosilanes. These are organoheterosilanes, bearing a silicon atom linked to three alkyl groups and one heteroatom.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Moisture Sensitive
• Refractive Index: 1.397
• Flash Point(°F): 33.8 °F
• Flash Point(°C): 0°C
• Boil Point(°C): 100-102°C
• Molecular Weight: 130.259 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 130.081 Da
• Monoisotopic Mass: 130.081 Da
• Topological Polar Surface Area: 9.200 Ų
• Heavy Atom Count: 8
• Formal Charge: 0
• Complexity: 73.100
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

References

1. Chai Shuiqin, Chi Yuting, Sun Wanlin, Pei Xinyu, Pei Shuchen, Sun Chengyu, Luo Kang, Yao Bo.  (2023)  Bifunctional Silicon Quantum Dots for Antibacterial Application and Highly Sensitive Detection of Tetracycline.  Journal of Analysis and Testing,      [PMID:] [10.1007/s41664-023-00289-5]

2. Yuting Chi, Wanlin Sun, Lijia Zhou, Shuchen Pei, Haichun Zeng, Yunying Cheng, Shuiqin Chai.  (2023)  The preparation of hybrid silicon quantum dots by one-step synthesis for tetracycline detection and antibacterial applications.  Analytical Methods,  15  (9): (1145-1156).  [PMID:36787098] [10.1039/D2AY02102A]

3. Shuchen Pei, Xin Hou, Yuting Chi, Wanlin Sun, Fang Chen, Kang Luo, Shuiqin Chai.  (2024)  Facile synthesis of highly efficient fluorescent silicon quantum dots used for highly sensitive sensor of tetracycline in honey samples and antibacterial agent.  FOOD CHEMISTRY,      [PMID:39616761] [10.1016/j.foodchem.2024.141844]

4. Shuiqin Chai, Yuting Chi, Wanlin Sun, Xin Hou, Shuchen Pei, Kang Luo, Wenyi Lv.  (2024)  Synthesis of N-doped and P-doped silicon quantum dots and their applications for tetracycline detection in the honey samples and antibacterial properties.  FOOD CHEMISTRY,      [PMID:38615527] [10.1016/j.foodchem.2024.139324]