Bromotrimethylsilane(TMBS) - ≥98%(GC), stabilized with copper , CAS No.2857-97-8

CAS: 2857-97-8 Cat. No.: B109499 Formula: C3H9BrSi Molecular Weight: 153.09 Beilstein Registry Number: 1731135 EC Number: 220-672-0
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GRADE & PURITY ≥98%(GC) stabilized with copper
Synonyms
0K2L2IJ59O | Bromotrimethylsilane | bromo-trimethyl-silane | Bromotrimethylsilane, 97% | EC 220-672-0 | trimethylsilylbromide | UNII-JHH5G299BX | J-519952 | EN300-29777 | Trimethylbromosilane | NSC139857 | NSC-139857 | (CH3)3SiBr | GS3K23H1Q8 | bromo trim
Storage
Store at 2-8°C,Argon charged
Shipped In
Wet ice
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Size
Germany (EU)
USA*
Price
Qty
5g
B109499-5g
—
9 In stock
€10.33
25g
B109499-25g
—
8 In stock
€14.66
100g
B109499-100g
—
1 In stock
€37.23
250g
B109499-250g
—
1 In stock
€82.35
500g
B109499-500g
—
9 In stock
€121.40
Enter a quantity for the sizes you want to add.
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Why this grade

≥98%(GC), stabilized with copper for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

🌡

Storage & shipping

Store at 2-8°C,Argon charged Ships Wet ice Check lot-specific COA for exact specifications.

📋

Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

📚

Literature proof

Cited in 19 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Specifications

Synonyms
0K2L2IJ59O | Bromotrimethylsilane | bromo-trimethyl-silane | Bromotrimethylsilane, 97% | EC 220-672-0 | trimethylsilylbromide | UNII-JHH5G299BX | J-519952 | EN300-29777 | Trimethylbromosilane | NSC139857 | NSC-139857 | (CH3)3SiBr | GS3K23H1Q8 | bromo trim
Specifications & Purity
≥98%(GC), stabilized with copper
Storage
Store at 2-8°C,Argon charged
Shipped In
Wet ice
This product requires cold chain shipping. Ground and other economy services are not available.
Purity
≥98%(GC)
Names and Identifiers
Pubchem Sid
Pubchem Sid Url
https://pubchem.ncbi.nlm.nih.gov/substance/508811605
Canonical Smiles
C[Si](C)(C)Br
IUPAC Name
bromo(trimethyl)silane
InChIKey
IYYIVELXUANFED-UHFFFAOYSA-N
INCHI
1S/C3H9BrSi/c1-5(2,3)4/h1-3H3
Isomeric SMILES
C[Si](C)(C)Br
WGK Germany
3
UN Number
2920
Packing Group
II
Molecular Weight
153.09
Beilstein
1731135
Reaxy-Rn
1731135
Reaxys-RN_link_address
https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1731135&ln=

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

Taxonomic Classification

Taxonomy Tree

KingdomOrganic compounds
SuperclassOrganometallic compounds
ClassOrganometalloid compounds
SubclassOrganosilicon compounds
Intermediate Tree Nodes Organoheterosilanes
Direct ParentTrialkylheterosilanes
Alternative Parents Silyl monohalides  Organic metalloid salts  Alkylhalosilanes  Hydrocarbon derivatives  
Molecular FrameworkAliphatic acyclic compounds
Substituents Trialkylheterosilane - Silyl monohalide - Organic metalloid salt - Alkylhalosilane - Hydrocarbon derivative - Organic salt - Aliphatic acyclic compound
DescriptionThis compound belongs to the class of organic compounds known as trialkylheterosilanes. These are organoheterosilanes, bearing a silicon atom linked to three alkyl groups and one heteroatom.
External Descriptors Not available
3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

30 results found

Lot NumberCertificate TypeDateItem
J2615153Certificate of AnalysisAug 03, 2026 B109499
H2614205Certificate of AnalysisAug 03, 2026 B109499
H2614204Certificate of AnalysisAug 03, 2026 B109499
H2614203Certificate of AnalysisAug 03, 2026 B109499
H2614202Certificate of AnalysisAug 03, 2026 B109499
H2614201Certificate of AnalysisAug 03, 2026 B109499
A2604094Certificate of AnalysisJan 12, 2026 B109499
K2520237Certificate of AnalysisNov 27, 2025 B109499
G2526088Certificate of AnalysisAug 08, 2025 B109499
F2525073Certificate of AnalysisJul 08, 2025 B109499
F2525019Certificate of AnalysisJul 05, 2025 B109499
F2512050Certificate of AnalysisJun 16, 2025 B109499
K2225209Certificate of AnalysisAug 22, 2024 B109499
L2001134Certificate of AnalysisJun 03, 2024 B109499
L2412419Certificate of AnalysisOct 09, 2023 B109499
K2315051Certificate of AnalysisOct 09, 2023 B109499
K2420077Certificate of AnalysisOct 09, 2023 B109499
A2203189Certificate of AnalysisOct 09, 2023 B109499
I2406025Certificate of AnalysisOct 09, 2023 B109499
I2403054Certificate of AnalysisOct 09, 2023 B109499
D2502060Certificate of AnalysisOct 09, 2023 B109499
D2419071Certificate of AnalysisOct 09, 2023 B109499
A2203192Certificate of AnalysisOct 09, 2023 B109499
A2203191Certificate of AnalysisOct 09, 2023 B109499
A2203190Certificate of AnalysisOct 09, 2023 B109499
J2331018Certificate of AnalysisSep 22, 2022 B109499
L2001133Certificate of AnalysisSep 22, 2022 B109499
L2001132Certificate of AnalysisSep 22, 2022 B109499
L1817012Certificate of AnalysisAug 05, 2022 B109499
I2319070Certificate of AnalysisDec 15, 2021 B109499
Chemical and Physical Properties
SolubilityMiscible with carbon tetrachloride, chloroform, dichloroethane, acetonitrile, toluene, dichloromethane and hexane.
SensitivityLight sensitive.Hygroscopic.
x_refractive_index1.424
x_flash_point_drop_fahrenheit77 °F
x_flash_point_drop_centigrade32 °C
x_boil_point_char79°C
x_melt_point_char-43°C
Molecular Weight153.090 g/mol
XLogP3
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count0
Rotatable Bond Count0
Exact Mass151.966 Da
Monoisotopic Mass151.966 Da
Topological Polar Surface Area0.000 Ų
Heavy Atom Count5
Formal Charge0
Complexity28.400
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
The total count of all stereochemical bonds0
Covalently-Bonded Unit Count1
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