dichloronickel,1,2-dimethoxyethane - ≥98% , CAS No.29046-78-4

CAS: 29046-78-4 Cat. No.: D299631 Molecular Weight: 219.72 EC Number: 627-461-6 PubChem CID: 15773433

GRADE & PURITY ≥98%

Synonyms

FT-0638826 | MFCD00013481 | A903139 | Dichloro(dimethoxyethane)nickel | dichloronickel,1,2-dimethoxyethane | dichloronickel;1,2-dimethoxyethane | OCMNCWNTDDVHFK-UHFFFAOYSA-L | nickel(II) chloride dimethoxyethane | SCHEMBL1486833 | nicl2(dme) | NICKEL(II)

Storage

Store at 2-8°C,Protected from light,Argon charged

Shipped In

Wet ice

Overview

Application：

Nickel(II) chloride ethylene glycol dimethyl ether complex can be used:
As a catalyst for the borylation of racemic benzylic chloride to synthesize enantioenriched benzylic boronic esters.
As a promoter for the trifluoromethylation of alkyl iodides to synthesize broad range of alkyl-CF3 compounds.
For the synthesis of nickel bis(benzimidazol-2-ylidene) pincer complexes which can be used for electrocatalytic reduction of CO2 to CO.
As a Lewis acid catalyst for C-acylation β-ketoesters through photoactivation by visible light.

Specifications

Synonyms

FT-0638826 | MFCD00013481 | A903139 | Dichloro(dimethoxyethane)nickel | dichloronickel, 1, 2-dimethoxyethane | dichloronickel;1, 2-dimethoxyethane | OCMNCWNTDDVHFK-UHFFFAOYSA-L | nickel(II) chloride dimethoxyethane | SCHEMBL1486833 | nicl2(dme) | NICKEL(II)

Specifications & Purity

≥98%

Storage

Store at 2-8°C, Protected from light, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥98%

Names and Identifiers

• Canonical Smiles: COCCOC.Cl[Ni]Cl
• IUPAC Name: dichloronickel;1,2-dimethoxyethane
• InChIKey: OCMNCWNTDDVHFK-UHFFFAOYSA-L
• INCHI: 1S/C4H10O2.2ClH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2
• Isomeric SMILES: COCCOC.Cl[Ni]Cl
• WGK Germany: 3
• PubChem CID: 15773433
• Molecular Weight: 219.72

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic oxygen compounds
    • Class Organooxygen compounds
      • Subclass Ethers

• Kingdom: Organic compounds
• Superclass: Organic oxygen compounds
• Class: Organooxygen compounds
• Subclass: Ethers
• Intermediate Tree Nodes: Not available
• Direct Parent: Dialkyl ethers
• Alternative Parents: Organic transition metal salts Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Organic metal salt - Organic transition metal salt - Dialkyl ether - Hydrocarbon derivative - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as dialkyl ethers. These are organic compounds containing the dialkyl ether functional group, with the formula ROR', where R and R' are alkyl groups.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Hygroscopic；light and moisture and heat sensitive
• Melt Point(°C): >300 °C
• Molecular Weight: 219.720 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 217.941 Da
• Monoisotopic Mass: 217.941 Da
• Topological Polar Surface Area: 18.500 Ų
• Heavy Atom Count: 9
• Formal Charge: 0
• Complexity: 20.300
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

References

1. Xiaobing Wei, Jiahui Li, Dan Li, Lijun Guo, Yanling Xiao, Cuiqin Li.  (2025)  Study on the Catalytic Performance of Nickel(II) Complexes with Distinct Triazine Support Structures in Ethylene Oligomerization via Different Experiment Designs.  MOLECULES,  30  (9): (1977).  [PMID:40363783] [10.3390/molecules30091977]