Diethoxymethylsilane [Hydrosilylating Reagent] - ≥95%(GC) , CAS No.2031-62-1

CAS: 2031-62-1 Cat. No.: D155451 Formula: C₅H₁₄O₂Si Molecular Weight: 134.25 EC Number: 217-982-3 PubChem CID: 6327387

GRADE & PURITY ≥95%(GC)

Synonyms

FT-0624765 | NSC 139844 | AKOS030227951 | diethoxy(methyl)silicon | diethoxymethylsilane [hydrosilylating reagent] | methyldiethoxysilane, >=96% | D2403 | diethoxy(methyl)silane | DTXSID40893418 | FS-4896 | MFCD00026749 | EINECS 217-982-3 | NSC139844 | NS

Storage

Argon charged,Room temperature

Shipped In

Normal

Overview

Diethoxymethylsilane is used in the preparation of N,N'-methylsilanediyl-bis-phthalimide by reacting with phthalimide. It is used as a reagent in the selective reduction of carbonyl compounds, hydorosilylation of alkenes, tandem reductive aldol reaction and rhodium-catalyszed silylcarbocyclization

Specifications

Synonyms

FT-0624765 | NSC 139844 | AKOS030227951 | diethoxy(methyl)silicon | diethoxymethylsilane [hydrosilylating reagent] | methyldiethoxysilane, >=96% | D2403 | diethoxy(methyl)silane | DTXSID40893418 | FS-4896 | MFCD00026749 | EINECS 217-982-3 | NSC139844 | NS

Specifications & Purity

≥95%(GC)

Storage

Argon charged,Room temperature

Shipped In

Normal

Purity

≥95%(GC)

Names and Identifiers

• Pubchem Sid: 504764049
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504764049
• Canonical Smiles: CCO[Si](C)OCC
• InChIKey: GAURFLBIDLSLQU-UHFFFAOYSA-N
• INCHI: 1S/C5H13O2Si/c1-4-6-8(3)7-5-2/h4-5H2,1-3H3
• Isomeric SMILES: CCO[Si](C)OCC
• WGK Germany: 3
• PubChem CID: 6327387
• UN Number: 1993
• Packing Group: II
• Molecular Weight: 134.25
• Reaxy-Rn: 1733975

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Class Organometalloid compounds
      • Subclass Organosilicon compounds

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Class: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Not available
• Direct Parent: Alkoxysilanes
• Alternative Parents: Silyl ethers Organic metalloid salts Organooxygen compounds Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Alkoxysilane - Silyl ether - Organic metalloid salt - Organic oxygen compound - Hydrocarbon derivative - Organooxygen compound - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as alkoxysilanes. These are organosilicon compounds with the general formula RO[Si](OR')(R'')(R''') (R,R' = organyl; R'',R''' = any atom).
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Miscible with water, 1,4-dioxane, tetrahydrofuran, acetonitrile, dichloromethane, chloroform, dimethyl sulfoxide, hexamethylphosphoric triamide and toluene. Insoluble in diethyl ether and hexane.
• Sensitivity: light & Moisture sensitive
• x_refractive_index: 1.38
• x_flash_point_drop_fahrenheit: 50 °F
• x_flash_point_drop_centigrade: 10°C
• x_boil_point_char: 94-95 °C
• Molecular Weight: 133.240 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 133.068 Da
• Monoisotopic Mass: 133.068 Da
• Topological Polar Surface Area: 18.500 Ų
• Heavy Atom Count: 8
• Formal Charge: 0
• Complexity: 43.700
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

References

1. Hongmei Chen, Shu Yu, Yunping Li.  (2023)  Bioactivity of SiOC and SiCaMgOC coatings prepared by sol-gel method.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2023.08.138]

2. Yanli Dou, Shixiang Sun, Shanshan Lu, Weiguo Yao, Dongbo Guan.  (2022)  Preparation of carbon black/silicone rubber composites with large-area-homogeneous-low electrical-resistance used as electroplating matrix.  RSC Advances,  12  (50): (32448-32458).  [PMID:36425691] [10.1039/D2RA06510J]

3. Xunzhu Jiang, Xiang-Ting Min, Xiaoli Pan, Botao Qiao.  (2025)  Density effect of Re1 electronic promoter on the activity of Pt1-catalyzed hydrosilylation.  Molecular Catalysis,      [PMID:] [10.1016/j.mcat.2025.114851]