BMIMPF6 - ≥97% , CAS No.174501-64-5

CAS: 174501-64-5 Cat. No.: B107646 Molecular Weight: 284.18 EC Number: 678-095-9 PubChem CID: 2734174

GRADE & PURITY ≥97%

Synonyms

1-Butyl-3-methylimidazolium hexafluorophosphate, for catalysis, >=98.5% (T) | 1-n-Butyl-3-methylimidazolium hexafluorophosphate | 1-Butyl-3-methylimidazolium hexafluorophosphate | DTXCID7027887 | 1-Butyl-3-methyl-1H-imidazol-3-iumhexafluorophosphate(V) |

Storage

Room temperature,Argon charged,Desiccated,Cool

Shipped In

Normal

Overview

1-Butyl-3-methylimidazolium hexafluorophosphate is a high-purity ionic liquid (HPIL) with low water and halogen content, which makes it an effective solvent for transition-metal-catalyzed reactions. Some of its other advantageous properties include hydrophobicity and lack of vapor pressure. 1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL).It can be prepared by reacting 1-methylimidazole with chlorobutane.Gaseous hydrofluorocarbons (HFCs) such as fluoromethane, fluoroethane and 1,1,2,2-tetrafluoroethane are soluble in BMIMPF6
Ionic liquid employed in many environmentally friendly reactions

Specifications

Synonyms

1-Butyl-3-methylimidazolium hexafluorophosphate, for catalysis, >=98.5% (T) | 1-n-Butyl-3-methylimidazolium hexafluorophosphate | 1-Butyl-3-methylimidazolium hexafluorophosphate | DTXCID7027887 | 1-Butyl-3-methyl-1H-imidazol-3-iumhexafluorophosphate(V) |

Specifications & Purity

≥97%

Storage

Room temperature, Argon charged, Desiccated, Cool

Shipped In

Normal

Purity

≥97%

Names and Identifiers

• Pubchem Sid: 488192495
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488192495
• Canonical Smiles: CCCCN1C=C[N+](=C1)C.F[P-](F)(F)(F)(F)F
• IUPAC Name: 1-butyl-3-methylimidazol-3-ium;hexafluorophosphate
• InChIKey: IXQYBUDWDLYNMA-UHFFFAOYSA-N
• INCHI: 1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1
• Isomeric SMILES: CCCCN1C=C[N+](=C1)C.F[P-](F)(F)(F)(F)F
• WGK Germany: 3
• PubChem CID: 2734174
• Molecular Weight: 284.18
• Reaxy-Rn: 8026031

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organoheterocyclic compounds
    • Class Azoles
      • Subclass Imidazoles
        • Level5 Substituted imidazoles
          • Level6 N-substituted imidazoles

• Kingdom: Organic compounds
• Superclass: Organoheterocyclic compounds
• Class: Azoles
• Subclass: Imidazoles
• Intermediate Tree Nodes: Substituted imidazoles
• Direct Parent: N-substituted imidazoles
• Alternative Parents: Heteroaromatic compounds Azacyclic compounds Organopnictogen compounds Organonitrogen compounds Organic salts Hydrocarbon derivatives
• Molecular Framework: Aromatic heteromonocyclic compounds
• Substituents: N-substituted imidazole - Heteroaromatic compound - Azacycle - Organic nitrogen compound - Organopnictogen compound - Hydrocarbon derivative - Organic salt - Organonitrogen compound - Aromatic heteromonocyclic compound
• Description: This compound belongs to the class of organic compounds known as n-substituted imidazoles. These are heterocyclic compounds containing an imidazole ring substituted at position 1.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Miscible with dichloromethane, chloroform, ethyl acetate. Immiscible with water, diethyl ether and hexane.
• Sensitivity: Hygroscopic
• Refractive Index: 1.411
• Boil Point(°C): >350°C
• Melt Point(°C): 6.5°C
• Molecular Weight: 284.180 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 3
• Exact Mass: 284.088 Da
• Monoisotopic Mass: 284.088 Da
• Topological Polar Surface Area: 8.800 Ų
• Heavy Atom Count: 17
• Formal Charge: 0
• Complexity: 156.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

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62. Jin Yun Peng, Chuan Tao Hou, Xiao Xian Liu, Hong Bo Li, Xiao Ya Hu.  (2011)  Electrochemical behavior of azithromycin at graphene and ionic liquid composite film modified electrode.  TALANTA,      [PMID:22063535] [10.1016/j.talanta.2011.09.005]

63. Fenglong Li, Zhengyang Kong, Xiaolin Wang, Guyue Wang, Chao Chen, Ying Tian, Zhiyi Lyu, Kyung Jin Lee, Do Hwan Kim, Jung-Yong Lee, Jin Zhu, Wu Bin Ying.  (2024)  A bio-based, sweat-resistant and markedly sensitive iontronic skin for advancing central sleep apnea monitoring.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.150541]

64. Jintao He, Junyuan Hua, Xiaohua Ma, Ranil Wickramasinghe, Jianxin Li.  (2024)  A mixed solvent system of amino crown ether and ionic liquids for a high-efficient extraction of cesium.  JOURNAL OF MOLECULAR LIQUIDS,      [PMID:] [10.1016/j.molliq.2024.125868]

65. Haidong Zhao, Xiangfei Xiao, Shuping Jin, Xin Jia.  (2025)  Breathable, durable, and ultrathin ionogel fiber sensors for strain and temperature sensing based on TPU and few-layer black phosphorus.  Materials Today Nano,      [PMID:] [10.1016/j.mtnano.2025.100599]

66. Gangyi Zeng, Guangyao Liu, Tiantian Wang, Lingling Wen, Jiangning Li, Yan Meng, Ziqiu Ren, Xin Li.  (2024)  Buried interface modification by multifunctional ionic liquids for triple-cation perovskite solar cells made in a fully ambient air.  Journal of Materials Chemistry C,      [PMID:] [10.1039/D4TC00254G]

67. Wang Mengge, Chen Xiaofeng, Wang Zhigang, Li Ming.  (2025)  Confirmation of radicals auto-generated in [Bmim][PF6]/[C16mim][PF6]/water reverse micelles and the radical quantification based on the 1,1-diphenyl-2-picrylhydrazine (DPPHH) spectroscopic probe.  ANALYTICAL SCIENCES,      [PMID:40113732] [10.1007/s44211-025-00744-6]

68. Qingyun Zhao, Xiaohui Liu, Shuo Deng, Xianghong Zheng, Birong Zeng, Xinyu Liu, Yiting Xu, Conghui Yuan, Lizong Dai.  (2024)  Construction of phosphorus-containing polyimine vitrimer film by incorporating ionic liquid BMIM∙PF6 for enhanced mechanical, flame-retardant and reprocessable properties.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.153283]

69. Ke Wang, Xiao-Xue Wang, Chen-Yu Wang, Meng Yin, Shou-Shan Yu, Ke-Zheng Chen, Sheng-Lin Qiao.  (2024)  Customizable and scalable manufacture of aesthetic ionic conductive silk yarns for e-textile devices.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.150645]

70. Yaqi Liu, Han Quan, Huo Yanyan, Yang Xiaohui.  (2024)  Determination of Trace Cobalt in Water Samples by Ionic Liquid-Dispersive Liquid–Liquid Microextraction and Graphite Furnace Atomic Absorption Spectrometry.  Journal of Water Chemistry and Technology,  46  (5): (480-490).  [PMID:] [10.3103/S1063455X24050102]

71. Qi Xiao, Jiawen Li, Shuai Liu, Mingli Yang, Yi Fang, Shan Huang.  (2024)  Fabrication of ultrafine PtPd alloy/ionic liquid-carbon dots nanocomposites modified flexible carbon fiber as enzyme-free amperometric sensing for H2O2 in living cells.  MICROCHEMICAL JOURNAL,      [PMID:] [10.1016/j.microc.2024.110942]

72. Chengqing Huang, Shiyue Zhang, Xinying Ma, Fei Yan, Weizhong Tang.  (2024)  Highly Sensitive Electrochemical Determination of Butylated Hydroxyanisole in Food Samples Using Electrochemical-Pretreated Three-Dimensional Graphene Electrode Modified with Silica Nanochannel Film.  Nanomaterials,  14  (7): (569).  [PMID:38607104] [10.3390/nano14070569]

73. Gongheng Zhang, Abdullah Ali Mohammed Ahmed Al-Anzah, Fengxiang Yin, Jie Zhang, Guoru Li, Biaohua Chen, Qiuyue Gao, Xian Tong Yu, Yuqian Sun.  (2024)  Ionic liquid modified Co-N-C catalyst derived from ZIF-67/C with enhanced catalytic activity for oxygen reduction reaction in alkaline electrolyte.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2024.133910]

74. Li Chen, Hang Zhu, Dai Shi, Jianxiang Lv, Xingkai Zhang, Changning Bai.  (2024)  Macroscale Ultradurable Antiwear Achieved on Graphene-Based Films via Multiphase Combination.  ADVANCED ENGINEERING MATERIALS,  26  (13): (2400411).  [PMID:] [10.1002/adem.202400411]

75. Zi-jie Huang, Rui-qing Wang, Wan-jun Jiang, Yu-long Liu, Ting-yu Zhu, De-xiang Sun, Jing-hui Yang, Xiao-dong Qi, Yong Wang.  (2024)  Nacre-inspired flexible and thermally conductive phase change composites with parallelly aligned boron nitride nanosheets for advanced electronics thermal management.  COMPOSITES SCIENCE AND TECHNOLOGY,      [PMID:] [10.1016/j.compscitech.2024.110736]

76. Li Zhang, Yu Han, Ming Sun, Shaobin Li.  (2024)  Non-enzymatic electrochemical sensor based on ionic liquid [BMIM][PF6] functionalized zirconium‑copper bimetallic MOF composite for the detection of nitrite in food samples.  FOOD CHEMISTRY,      [PMID:38878537] [10.1016/j.foodchem.2024.140023]

77. Junjie Zhu, Huawei Gao, Zhifan Zheng, Yunzhong Cao, Tengyue Wang, Ranjith Kumar Kankala, Lixin Wu, Ai-Zheng Chen, Shi-Bin Wang, Yuewei Li.  (2024)  Photocuring 3D printable flexible strain sensor enhanced by in situ grown silk fibroin nanoparticles.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.154762]

78. Hao Han, Penglei Yan, Qingye Li, Shuyi Zhang, Binglei Jiao, Gaolei Wei, Zhao Wang, Muhan Cao, Panpan Xu, Qiao Zhang, Jinxing Chen.  (2024)  Photothermal Upcycling of Waste Polyvinyl Chloride Plastics.  ENVIRONMENTAL SCIENCE & TECHNOLOGY,      [PMID:39602778] [10.1021/acs.est.4c07350]

79. Zhang Chengpeng, Bei Pengzhi, Liu Hongjing, Zhao Xu, Shi Meiling, Jing Xiaochun, Li Zhao, Yao Hui.  (2025)  Preparation of M2070-UiO-66-OH@[BMim][PF6]/Pebax mixed matrix membranes and CO2 separation.  POLYMER BULLETIN,      [PMID:] [10.1007/s00289-025-05696-5]

80. Shuang Meng, Yan Zhuang, Xue Yang, Dongxuan Guo, Jinlong Li.  (2025)  Removal of volatile organic compounds using a membrane catalytic process involving a [BMIM]PF6 ionic liquid membrane and visible light-driven N–La–TiO2 photocatalysts.  NEW JOURNAL OF CHEMISTRY,  49  (9): (3526-3535).  [PMID:] [10.1039/D4NJ05267F]

81. Haidong Zhao, Xiangfei Xiao, Hao Xing, Xin Jia, Shuping Jin.  (2024)  Synthesis of an ultrathin, self-adhesive, tough, and frigostable BP@PVP/TPU ionogel for strain sensors by electrospinning.  Materials Today Chemistry,      [PMID:] [10.1016/j.mtchem.2024.102102]

82. Chao Chen, Zhe Yu, Ying Tian, Fenglong Li, Zhengyang Kong, Xu Ran, Xing Wu, Kyung Jin Lee, Do Hwan Kim, Jung-Yong Lee, Jin Zhu, Wu Bin Ying.  (2024)  Transmembrane Inspired Mechano-Responsive Elastomers with Synergized Traction-Assisted Healing and Dual-Channel Sensing.  ADVANCED FUNCTIONAL MATERIALS,      [PMID:] [10.1002/adfm.202402380]

83. Shanqin Ge, Long Chen, Wei Li, Qingzhao Cai, Genxiang Gong, Junhao Wu, Jinhong Yu, Kazuhito Nishimura, Nan Jiang, Tao Cai.  (2025)  Tris-based protic ionic liquids with multiple adsorption effects enabling excellent anti-wear and anti-corrosion performances.  JOURNAL OF MOLECULAR LIQUIDS,      [PMID:] [10.1016/j.molliq.2025.127231]

84. Fan Zheyuan, Yu Wei, Liu Zhongling.  (2025)  Ultra performance liquid chromatography with ultrasound assisted magnetic ionic liquid dispersive liquid liquid microextraction for determination of 20 neurotransmitters in spinal cords.  Scientific Reports,  15  (1): (1-19).  [PMID:39934216] [10.1038/s41598-025-89692-9]

85. Yuxi Sun, Min Sang, Wenwen Li, Zimu Li, Yu Wang, Huaxia Deng, Xinglong Gong.  (2025)  Multi-stimulus responsive soft actuator with thermotropic shape memory and local magnetic programming properties.  COMPOSITES PART B-ENGINEERING,      [PMID:] [10.1016/j.compositesb.2025.112964]

86. Li Bingchun, Zhang Guoliang, Zheng Wenxuan, Yang Duo, Li Yang.  (2025)  Intelligent Current-Controlled Behavior of Intercalated MXene@Triethanolamine Borate Nanocomposite as Lubricant Additives.  TRIBOLOGY LETTERS,  73  (4): (1-14).  [PMID:] [10.1007/s11249-025-02053-5]

87. Haikun Zhu, Jinquan Huang, Zhenxin Yang, Junzhan Wang, Xuanhe Li, Dengke Wang, Zhenghong Lu, Qiang Zhu.  (2025)  Polymeric gel-mediated grain boundary self-healing for the fabrication of high-performance and durable organic thin-film transistors.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.168170]

88. Chang Li, Yanbin Yun, Fengguang Huang, Jiaming Mao, Jia Liu, Wenjuan Yang, Chunyun Zhou, Meng Li.  (2025)  Enhanced carbon dioxide capture via amphiphobic PVDF membrane modification for membrane contactors: Overcoming wettability challenges.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.162475]

89. Lu Wang, Gang Wang, Zhuoting Zhang, Kuang Wang, Qingxia Qiao, Jiayi Jiang, Guan Wang, Tao Liu.  (2025)  Efficient degradation of alkyl imidazole ionic liquids by MnFe2O4-activated peracetic acid: Performance, mechanisms, and ecotoxicity assessment.  Journal of Water Process Engineering,      [PMID:] [10.1016/j.jwpe.2025.107653]

90. Li Wen, Jinxia Zheng, Zhijie Ke, Jian Dong.  (2025)  Macromolecular crowding effect on the β-galactosidase cascade reaction under multivalency and chain overlapping conditions of glycopolymers.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:40389007] [10.1016/j.ijbiomac.2025.144343]

91. Meng Wang, Wendong Li, Yadong Lv, Guangxian Li, Zhijun Zhao, Yaobing Wang, Qinghua Zhou, Wei Pu, Miqiu Kong.  (2025)  Highly stable and wide-range flexible pressure sensors with a gradient modulus and selective foaming layer.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.163761]

92. Jinjian Hou, Wenjuan Wang, Zanli Fu, Yuting Hu, Zhongchi Wu, Xiaojin Wu, Jianan Hu, Haiming Yu, Gaobo Yu, Jiacheng Li.  (2025)  Imidazole-ionic liquid-assisted solvent extraction mechanism-macro perspective and molecular aspect.  JOURNAL OF HAZARDOUS MATERIALS,      [PMID:40378748] [10.1016/j.jhazmat.2025.138617]

93. Sanoober Bhagat, Sana-ul-Nisa, Tania Ghumro, Jamil A Buledi, Amber R Solangi, S Tufail H Sherazi.  (2025)  Enhanced electrochemical sensing of lead in environmental samples using Bi2O3/IL/rGO hybrid nanocomposite.  RSC Advances,  15  (23): (18444).  [PMID:40463342] [10.1039/d5ra01951f]

94. Yao Liu, Siyu Han, Panpan Gu, Bai Wang, Shiyan Tian, Xiaoxu Xu, Chunmei Yang, Shujun Liu, Jianshe Hu.  (2025)  Flexible wearable biosensors from poly (ionic liquid) for real-time signal monitoring.  Frontiers in Bioengineering and Biotechnology,      [PMID:40470509] [10.3389/fbioe.2025.1610197]

95. Tian Zhang, Leang Yin, Zengyu Hui, Runrun Zhang, Jiayan Fu, Hai Xu, Jingbo Zhou, Wenteng Hou, Yi Yao, Jianing An, Hongqing Pan, Gengzhi Sun.  (2025)  Biomimetic spinning of glassy ionogel fibers with tailorable mechanical properties for versatile applications.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.169443]

96. Du Qinqing, Liu Lingyan, Sun Shengtong, Wu Peiyi.  (2025)  Self-compliant ionic nanomesh for gas-permeable and stress-free on-skin electronics.  Nature Communications,      [PMID:41266357] [10.1038/s41467-025-66512-2]

97. Siyu Han, Shiyan Tian, Bai Wang, Yongxin Shang, Jie Ren, Jianshe Hu, Liqun Yang.  (2025)  Wearable flexible ionic gel based on ionic liquids with high flame-retardancy and multimodal sensing.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.171488]

98. Xiaoyu Li, Ruihong Li, Haiyang Xue, Chenyu Wang, Kang Peng.  (2025)  Interlayer functionalization of silica nanosheets derived from natural clay for stable ionic liquids immobilization and efficient carbon dioxide capture.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:41371175] [10.1016/j.jcis.2025.139628]

99. Peipei Gao, Wei Wang, Tao Tang, Rongge Hu, Mengyun Liu, Hanjie Wen, Ziyuan Zhou, Zhiqi Liu.  (2025)  Tributyl Phosphate-Ionic Liquid System for Selective Lithium Extraction from Acid Leachate of Waste LiFePO4 Battery Cathode.  Journal of Environmental Chemical Engineering,      [PMID:] [10.1016/j.jece.2025.120869]

100. Zhenpeng Wang, Yalu Liu, Yapeng Zhang, Jiutao Hu, Youjie Rong, Jing Lv, Xiaobo Huang.  (2026)  Photocurable 3D-printed anti-tearing ionogels for flexible sensors.  REACTIVE & FUNCTIONAL POLYMERS,      [PMID:] [10.1016/j.reactfunctpolym.2026.106643]

101. Jian Gao, Jialong Wang, Jiejin Song, Yue Xing, Yuzhao Hou, Fengchao Wang, Jinghui Du, Jiang Wu, Liming Wang.  (2026)  Green and rapid magnetic solid-phase extraction coupled with HPLC-UV for sensitive detection of multiple statins in tea-based functional foods.  LWT-FOOD SCIENCE AND TECHNOLOGY,      [PMID:] [10.1016/j.lwt.2026.119148]

102. Shisong Yang, Mingyang Lin, Zili Wang, E Yang, Yangyang Luo, Ran Zhu, Zheng Chen, Qian Lin, Hongyan Pan.  (2026)  Electronic Regulation and Hydrophobic Improvement of the Fe–Pd Alloys by an Ionic Liquid and an Amino Group Achieve High Selectivity of Methane for Methanol.  LANGMUIR,      [PMID:41569092] [10.1021/acs.langmuir.5c05613]

103. Ruirui Wang, Hasnain Nawaz, Linbo Huang, Sheng Zhong, Shuang Wei, Bin He, Ruixia Liu, Suojiang Zhang.  (2026)  Engineering CObridge adsorption in Cu(II)/Cu(I) interfaces modulated by ionic liquid for enhanced CO2 electroreduction to ethylene.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2026.126569]

104. Yiting Han, Yueyang Xu, Liming Kong, Guojun Shi, Yongping Zeng.  (2026)  Ionic liquid-integrated MOF-808 for thiophene capture: Insights from Monte Carlo simulations and cyclic stability tests.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2026.140093]

105. Tingyu Li, Yixin Wang, Li Hao, Yiping Sun, Shujuan Liu, Qian Ye, Feng Zhou.  (2026)  Fabrication of N, P, F Co-Doped MXene Nanosheets with Ionic Liquid-Assisted Carbonization as an Efficient Lubricant Additive.  LANGMUIR,      [PMID:] [10.1021/acs.langmuir.5c06675]

106. Huang Ziling, Yang Rongling, Zhao Xiangjie, Zhu Chun, Tong Yuli, Li Xiaoyan, Luo Hongzhen.  (2026)  Synergistic effects of ionic liquid-solvent systems on geniposide cinnamoylation catalyzed by whole-cell biocatalysts.  BIOPROCESS AND BIOSYSTEMS ENGINEERING,      [PMID:] [10.1007/s00449-026-03309-7]