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Synthetic lipopeptides1 T-cell exhaustion1 Ionomycin1 PMA4 TCR-CD31 T-cell activation1 Saturated nitrogen-containing heterocyclic ring1 Sebaceous gland1 Zinc PCA1 Sebum regulation1 7-Azaindoles1 Gentiopicroside1 Gentiana Root Extract1 Gentiana rigescens1 Gentiana triflora1 Gentiana scabra1 Gentiana manshurica1 Tumor Biomarker1 Carcinoembryonic Antigen1 CEACAM61 CEACAM51 CEACAM11 CEACAM1 treatment response1 tumor biomarkers1 autoimmune diseases1 PAPP-A1 IGF1R1 IGF-II1 IGF-I1 IGFBP1 Precision Therapy1 Malignant Identity Characterization1 Tumor Heterogeneity1 Patient-Derived Organoid1 Tumor Organoid1 chemoresistance1 tumor stemness1 damage-associated molecular pattern1 CXCR42 CXCL121 RAGE1 TLR41 DAMP1 HMGB11 Thietanes1 DMF1 N,N-dimethylformamide1 TMSCl1 trimethylsilyl chloride1