Phosphorus tribromide - PrimorTrace™, ≥99.99% metals basis , CAS No.7789-60-8

CAS: 7789-60-8 Cat. No.: P108401 Molecular Weight: 270.69 EC Number: 232-178-2 PubChem CID: 24614

GRADE & PURITY PrimorTrace™, ≥99.99% metals basis

Synonyms

Phosphorus(III) bromide | PHOSPHORUS TRIBROMIDE [HSDB] | 58R3866PUA | Br3P | A839279 | Phosphorous tribromide | Phosphorous bromide | HSDB 1217 | Phosphorus tribromide, 99% | AKOS015856778 | Phosphorus(III) tribromide | Tribromo phosphine | tribromophosph

Storage

Room temperature,Argon charged

Shipped In

FedEx DG Service

Overview

Phosphorus tribromide (PBr3) is commonly used in Hell-Volhard-Zelinsky halogenation for the α-bromination of carboxylic acids to form the corresponding acyl bromide. It is also useful for the conversion of primary and secondary alcohols to alkyl bromides.

Phosphorus tribromide may be used as a reagent:

· In a novel protocol for synthesizing 7-ethoxy-1-(p-ethylphenoxy)-3,7-dimethyl-2-octene, a synthetic juvenile hormone mimic of trans,trans,cis-10,11-epoxy-7-ethyl-3,11-dimethyltrideca-2,6-dienoate. 

· To synthesize 1,2,3-diazaphosphinane, 1,2,3-thiazaphosphinine and 1,2-azaphosphole bearing a chromone ring. 

· To synthesize 1-Bromoundec-1-ene from 10-undecen-1-ol.

Specifications

Synonyms

Phosphorus(III) bromide | PHOSPHORUS TRIBROMIDE [HSDB] | 58R3866PUA | Br3P | A839279 | Phosphorous tribromide | Phosphorous bromide | HSDB 1217 | Phosphorus tribromide, 99% | AKOS015856778 | Phosphorus(III) tribromide | Tribromo phosphine | tribromophosph

Specifications & Purity

PrimorTrace™, ≥99.99% metals basis

Storage

Room temperature, Argon charged

Shipped In

FedEx DG Service

This product requires cold chain shipping. Ground and other economy services are not available.

Grade

PrimorTrace™

Purity

≥99.99% metals basis

Names and Identifiers

• Canonical Smiles: P(Br)(Br)Br
• IUPAC Name: tribromophosphane
• InChIKey: IPNPIHIZVLFAFP-UHFFFAOYSA-N
• INCHI: 1S/Br3P/c1-4(2)3
• Isomeric SMILES: P(Br)(Br)Br
• WGK Germany: 2
• RTECS: TH4460000
• PubChem CID: 24614
• UN Number: 1808
• Packing Group: II
• Molecular Weight: 270.69

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Homogeneous non-metal compounds
    • Class Other non-metal halides

• Kingdom: Inorganic compounds
• Superclass: Homogeneous non-metal compounds
• Class: Other non-metal halides
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Other non-metal halides
• Alternative Parents: Not available
• Molecular Framework: Not available
• Substituents: Other non-metal halide
• Description: This compound belongs to the class of inorganic compounds known as other non-metal halides. These are inorganic compounds containing 'other non-metals' and halogen.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Micible in acetone, carbon disulfide, hydrogen sulfide, chloroform, diethyl ether and decomposes in water and alcohol.
• Sensitivity: Moisture Sensitive
• Refractive Index: 1.697
• Boil Point(°C): 173.2°C
• Melt Point(°C): -41.5°C
• Molecular Weight: 270.690 g/mol
• XLogP3: 2.800
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 269.727 Da
• Monoisotopic Mass: 267.729 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 4
• Formal Charge: 0
• Complexity: 8.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

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