Poly(methylhydrosiloxane) - viscosity ：15 - 40 mPa.s(20°C) , CAS No.9004-73-3

CAS: 9004-73-3 Cat. No.: P107083 EC Number: 618-393-8 PubChem CID: 12487658

GRADE & PURITY viscosity ：15 - 40 mPa.s(20°C)

Synonyms

SCHEMBL20166 | 2-Methyl-1,2-oxasilinanato | DTXSID20733323

Storage

Room temperature

Shipped In

Normal

Overview

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Harnessing the reactivity of poly(methylhydrosiloxane) for the reduction and cyclization of biomass to high-value products

Reducing agent.

Used in greener amine synthesis by reductive amination as an alternative to borohydrides.

Synthesis of substituted amines and isoindolinones: catalytic reductive amination using abundantly available AlCl3/PMHS

Amine Synthesis through Mild Catalytic Hydrosilylation of Imines using Polymethylhydroxysiloxane and [RuCl2(arene)]2 Catalysts

Specifications

Synonyms

SCHEMBL20166 | 2-Methyl-1, 2-oxasilinanato | DTXSID20733323

Specifications & Purity

viscosity ：15 - 40 mPa.s(20°C)

Storage

Room temperature

Shipped In

Normal

Names and Identifiers

• Pubchem Sid: 504767131
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504767131
• Canonical Smiles: C[Si]1CCCCO1
• InChIKey: TXYXVOOPRILIHR-UHFFFAOYSA-N
• INCHI: 1S/C5H11OSi/c1-7-5-3-2-4-6-7/h2-5H2,1H3
• Isomeric SMILES: C[Si]1CCCCO1
• Alternate CAS: 63148-57-2
• PubChem CID: 12487658

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organoheterocyclic compounds
    • Class Oxacyclic compounds

• Kingdom: Organic compounds
• Superclass: Organoheterocyclic compounds
• Class: Oxacyclic compounds
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Oxacyclic compounds
• Alternative Parents: Organic metalloid salts Organosilicon compounds Organooxygen compounds Hydrocarbon derivatives
• Molecular Framework: Aliphatic heteromonocyclic compounds
• Substituents: Oxacycle - Organic metalloid salt - Organic oxygen compound - Hydrocarbon derivative - Organic salt - Organosilicon compound - Organooxygen compound - Aliphatic heteromonocyclic compound
• Description: This compound belongs to the class of organic compounds known as oxacyclic compounds. These are organic compounds containing an heterocycle with at least one oxygen atom linked to a ring carbon.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Not miscible or difficult to mix in water
• Flash Point(°F): 399.2°F
• Flash Point(°C): 204°C
• Molecular Weight: 115.230 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 115.058 Da
• Monoisotopic Mass: 115.058 Da
• Topological Polar Surface Area: 9.200 Ų
• Heavy Atom Count: 7
• Formal Charge: 0
• Complexity: 56.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 1
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

References

1. Jing Wang, Zhehao Wang, Zhonglin Chen, Pengwei Yan, Jimin Shen, Jing Kang.  (2023)  Preparation of Molecularly Imprinted Magnetic Stir Bar for Bisphenol A and Its Analysis on Trace Bisphenol A in Actual Water Samples.  Water,  15  (19): (3361).  [PMID:] [10.3390/w15193361]

2. Shuai-Yin Ma, Yuan-Sen Zhi, Hong-Shuang Zhang, Xiao-Zhi He, Bao-Yan Zhang, Fan-Bao Meng, Zhi-Na Ji.  (2023)  Fluorescent cholesteric liquid crystal polymers with dual properties: design, synthesis and characterisation.  LIQUID CRYSTALS,      [PMID:] [10.1080/02678292.2023.2206376]

3. Xiang-Yu Ma, Qiu-Cheng Li, Cheng-Han Song, Hong-Shuang Zhang, Yuan-Sen Zhi, Xiao-Zhi He.  (2022)  The effect of different photoluminescent side-chain length on the phase behaviour of chiral liquid crystal polymer.  LIQUID CRYSTALS,      [PMID:] [10.1080/02678292.2022.2044527]

4. Zhongshao Li, Shuwen Zhao, Zewei Shao, Hanxiang Jia, Aibin Huang, Ping Jin, Xun Cao.  (2022)  Deterioration mechanism of vanadium dioxide smart coatings during natural aging: Uncovering the role of water.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2022.137556]

5. Anhang Li, Sifan Chen, Zhidong Ma, Min Sun, Guiyu Zhu, Yue Zhang, Wei Wang.  (2021)  Corrosion protection properties of polyvinyl butyral/polyaniline-graphene oxide/poly (methylhydrosiloxane) composite coating for AA2024 aluminum alloy.  DIAMOND AND RELATED MATERIALS,      [PMID:] [10.1016/j.diamond.2021.108397]

6. Panlei Liu, Na Sun, Yuanyuan Mi, Xiaohang Luo, Xiaoxiao Dong, Jiaye Cai, Xilai Jia, Melvin A. Ramos, Travis Shihao Hu, Quan Xu.  (2021)  Ultra-low CNTs filled high-performance fast self-healing triboelectric nanogenerators for wearable electronics.  COMPOSITES SCIENCE AND TECHNOLOGY,      [PMID:] [10.1016/j.compscitech.2021.108733]

7. Yao Jianmei, Zhang Lingxue, Ran Jinfeng, Wang Shasha, Dong Nan.  (2020)  Specific recognition of cationic paraquat in environmental water and vegetable samples by molecularly imprinted stir-bar sorptive extraction based on monohydroxylcucurbit[7]uril–paraquat inclusion complex.  MICROCHIMICA ACTA,  187  (10): (1-10).  [PMID:32975594] [10.1007/s00604-020-04491-5]

8. Anhang Li, Min Sun, Zhidong Ma, Sifan Chen, Guiyu Zhu, Yue Zhang, Wei Wang.  (2020)  Anticorrosion performance of polyvinyl butyral composite coatings improved by polyaniline-multiwalled carbon nanotubes/poly (methylhydrosiloxane).  THIN SOLID FILMS,      [PMID:] [10.1016/j.tsf.2020.138347]

9. Shang Gao, Ze-ping Liu, Yue-hua Cong, Xiao-zhi He, Bao-yan Zhang, Fan-bao Meng, Ying-gang Jia.  (2020)  Cholesteric fluorescent liquid crystal polysiloxanes with different liquid crystal side chain lengths—Synthesis and properties.  DYES AND PIGMENTS,      [PMID:] [10.1016/j.dyepig.2020.108520]

10. Dong Nan, Zhang Lingxue, Yao Jianmei, Ma Peijian, He Jing, Li Tao, Wang Yuan.  (2019)  Monohydroxycucurbit[7]uril-coated stir-bar sorptive extraction coupled with high-performance liquid chromatography for the determination of apolar and polar organic compounds.  MICROCHIMICA ACTA,  186  (12): (1-10).  [PMID:31776838] [10.1007/s00604-019-3910-y]

11. Jun Zhang, Kaijun Dong, Weimin Luo.  (2019)  PdCl2-catalyzed hydrodeoxygenation of 5-hydroxymethylfurfural into 2,5-dimethylfuran at room-temperature using polymethylhydrosiloxane as the hydrogen donor.  CHEMICAL ENGINEERING SCIENCE,      [PMID:] [10.1016/j.ces.2019.03.011]

12. Tiemei Li, Yuefei Song, Jingjie Xu, Jing Fan.  (2018)  A hydrophobic deep eutectic solvent mediated sol-gel coating of solid phase microextraction fiber for determination of toluene, ethylbenzene and o-xylene in water coupled with GC-FID.  TALANTA,      [PMID:30625546] [10.1016/j.talanta.2018.11.085]

13. Hu Li, Wenfeng Zhao, Zhen Fang.  (2017)  Hydrophobic Pd nanocatalysts for one-pot and high-yield production of liquid furanic biofuels at low temperatures.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2017.05.039]

14. Nan Dong, Tao Li, Yujie Luo, Lin Shao, Zhu Tao, Chun Zhu.  (2016)  A solid-phase microextraction coating of sol–gel-derived perhydroxy cucurbit[6]uril and its application on to the determination of polycyclic aromatic hydrocarbon.  JOURNAL OF CHROMATOGRAPHY A,      [PMID:27702617] [10.1016/j.chroma.2016.09.066]

15. Miaomiao Tian, Rongmin Cheng, Juanjuan Ye, Xiaoting Liu, Qiong Jia.  (2013)  Preparation and evaluation of ionic liquid-calixarene solid-phase microextraction fibres for the determination of triazines in fruit and vegetable samples.  FOOD CHEMISTRY,      [PMID:24128445] [10.1016/j.foodchem.2013.08.029]

16. Na Sheng, Fangdi Wei, Wen Zhan, Zheng Cai, Shuhu Du, Xuemin Zhou, Fei Li, Qin Hu.  (2012)  Dummy molecularly imprinted polymers as the coating of stir bar for sorptive extraction of bisphenol A in tap water.  JOURNAL OF SEPARATION SCIENCE,      [PMID:22331819] [10.1002/jssc.201100883]

17. Jingrui Li, Xiaobo Xu, Xiaozhen Ma, Minghui Cui, Xiaolin Wang, Jing Chen, Jin Zhu, Jing Chen.  (2024)  Antimicrobial Nonisocyanate Polyurethane Foam Derived from Lignin for Wound Healing.  ACS Applied Bio Materials,      [PMID:38305746] [10.1021/acsabm.3c01257]

18. Yiran Bian, Yi Zhang, Taosuo Wang, Chuang Yang, Zhiming Feng, Kheng-Lim Goh, Yibin Zhou, Mingming Zheng.  (2024)  Insights into the enzymatic synthesis of alcoholic flavor esters with molecular docking analysis.  LWT-FOOD SCIENCE AND TECHNOLOGY,      [PMID:] [10.1016/j.lwt.2024.116206]

19. Cailang Lu, Qian Jia, Linlin Yu, Bin Zhang, Ruoyu Chen.  (2024)  Mechanistic Insight into the Synthesis and Morphological Evolution of Superhydrophobic Silica Nanotubes.  INORGANIC CHEMISTRY,      [PMID:38941071] [10.1021/acs.inorgchem.4c01856]