[Ru(phen)₃]Cl₂ - ≥95% , CAS No.23570-43-6

CAS: 23570-43-6 Cat. No.: R463451 Molecular Weight: 712.59 EC Number: 856-463-1 PubChem CID: 168121

GRADE & PURITY ≥95%

Synonyms

(OC-6-11)-Tris(1,10-phenanthroline-N1,N10)ruthenium(2+) dichloride | Ruthenium(2+) chloride--1,10-phenanthroline (1/2/3) | A822790 | Ruthenium(2+), tris(1,10-phenanthroline-N1,N10)-, dichloride, (OC-6-11)- | 1,10-phenanthroline; ruthenium(2+); dichloride

Storage

Store at 2-8°C,Protected from light,Argon charged

Shipped In

Wet ice

Overview

Description

[Ru(phen)3]Cl2is a cyclometalated ruthenium complex that can be used in visible light mediated photocatalytic organic transformations.

Specifications

Synonyms

(OC-6-11)-Tris(1, 10-phenanthroline-N1, N10)ruthenium(2+) dichloride | Ruthenium(2+) chloride--1, 10-phenanthroline (1/2/3) | A822790 | Ruthenium(2+), tris(1, 10-phenanthroline-N1, N10)-, dichloride, (OC-6-11)- | 1, 10-phenanthroline; ruthenium(2+); dichloride

Specifications & Purity

≥95%

Storage

Store at 2-8°C, Protected from light, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥95%

Names and Identifiers

• Canonical Smiles: C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.[Cl-].[Cl-].[Ru+2]
• IUPAC Name: 1,10-phenanthroline;ruthenium(2+);dichloride
• InChIKey: UWXWBVKIJZGXQL-UHFFFAOYSA-L
• INCHI: 1S/3C12H8N2.2ClH.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h3*1-8H;2*1H;/q;;;;;+2/p-2
• Isomeric SMILES: C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.[Cl-].[Cl-].[Ru+2]
• PubChem CID: 168121
• Molecular Weight: 712.59

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organoheterocyclic compounds
    • Class Phenanthrolines

• Kingdom: Organic compounds
• Superclass: Organoheterocyclic compounds
• Class: Phenanthrolines
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Phenanthrolines
• Alternative Parents: Quinolines and derivatives Pyridines and derivatives Benzenoids Heteroaromatic compounds Organic transition metal salts Organic metal halides Azacyclic compounds Organopnictogen compounds Organonitrogen compounds Organic chloride salts Hydrocarbon derivatives
• Molecular Framework: Not available
• Substituents: 1,10-phenanthroline - Quinoline - Benzenoid - Pyridine - Heteroaromatic compound - Organic metal halide - Azacycle - Organic transition metal salt - Organic nitrogen compound - Organopnictogen compound - Hydrocarbon derivative - Organic chloride salt - Organic salt - Organonitrogen compound - Aromatic heteropolycyclic compound
• Description: This compound belongs to the class of organic compounds known as phenanthrolines. These are aromatic polycyclic compounds containing the phenanthroline skeleton, which is a derivative of phenanthrene, and consists of two pyridine rings non-linearly joined by a benzene ring.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: light sensitive
• Flash Point(°F): Not applicable
• Flash Point(°C): Not applicable
• Melt Point(°C): >300℃

References

1. Kaiyue Hu, Lingxia Qin, Xinxin Ren, Zhiyong Guo, Sui Wang, Yufang Hu.  (2022)  Deoxyribonucleic acid-guided dual-mode electro-chemical/chemiluminescent platform for sensitive and selective examination of Pb2+.  JOURNAL OF ELECTROANALYTICAL CHEMISTRY,      [PMID:] [10.1016/j.jelechem.2022.116757]

2. Biaoliang Wu, Xiaoqing Wen, Jiuying Cui, Xiaojie Qin, Zheng Li, Yuanxun Gong, Qianli Tang, Xianjiu Liao, Zhenqiang Fan, Kai Zhang.  (2022)  Exploring an ultra-sensitive electrochemiluminescence monitoring strategy for SARS-CoV-2 using hairpin-assisted cycling and dumbbell hybridization chain amplification.  JOURNAL OF HAZARDOUS MATERIALS,      [PMID:] [10.1016/j.jhazmat.2022.129868]

3. Qingqing Zhang, Tingting Hao, Dandan Hu, Zhiyong Guo, Sui Wang, Yufang Hu.  (2020)  RNA aptamer-driven ECL biosensing for tracing histone acetylation based on nano-prism substrate and cascade DNA amplification strategy.  ELECTROCHIMICA ACTA,      [PMID:] [10.1016/j.electacta.2020.136828]

4. Qingqing Zhang, Dandan Hu, Tianyu Zhan, Yufang Hu, Zhiyong Guo, Sui Wang.  (2020)  Tailored DNA nano-framework-enabled Medusa electrochemiluminescence immunosensor for quantitative detection of histone acetyltransferase.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2020.128165]

5. Hu Yufang, Zhang Qingqing, Hu Dandan, Wang Jiao, Rao Jiajia, Xu Lihua, Guo Zhiyong, Wang Sui, Liu Xin, Tang Shiyun, Shen Qinpeng.  (2019)  Ultrasensitive electrochemiluminescence immunosensor for the transcriptional co-activator p300 by using a graphene oxide monolayer and tetrahedral DNA-mediated signal amplification.  MICROCHIMICA ACTA,  186  (5): (1-10).  [PMID:31049723] [10.1007/s00604-019-3435-4]