TEMPO - ≥98% , CAS No.2564-83-2

CAS: 2564-83-2 Cat. No.: T106827 Formule: C₉H₁₈NO Poids moléculaire: 156.25 Beilstein Registry Number: 1422418 Numéro CE: 219-888-8 PubChem CID: 2724126

GRADE & PURITY ≥98%

Synonyms

2,2,6,6-Tetramethylpiperidine 1-oxyl | TEMPO free radical | 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Vue d’ensemble

Catalytic oxidant for copper-catalyzed, greener oxidation of alcohols under aerobic conditions. Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air. TEMPO (2,2,6,6-Tetramethyl-1-piperidinyloxy) was used for trapping the styrenyl radical generated from benzoyl peroxide during nitroxide-mediated radical polymerization of styrene. TEMPO-mediated oxidation was employed for the carboxylation of water-resistant nanofibrillated cellulose (NFC) films.

Specifications

Synonymes

2,2,6,6-Tetramethylpiperidine 1-oxyl | TEMPO free radical | 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

Spécifications et pureté

≥98%

Mécanismes biochimiques et physiologiques

Widely used as a radical trap, as a structural probe for biological systems in conjunction with electron spin resonance spectroscopy and as a catalyst for the oxidation of primary alcohols to aldehydes.

Conditions de stockage de stockage

Store at 2-8°C,Argon charged

Expédié en

Wet ice

Ce produit nécessite l'expédition en chaîne froide. Les services terrestres et autres services économiques ne sont pas disponibles.

Type d'action

INHIBITOR

Note

Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20°C. Generally, these will be useable for up to one month. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour. Need more advice on solubility, usage and handling? Please visit our frequently asked questions (FAQ) page for more details.

Pureté

≥98%

Noms et identifiants

• Pubchem Sid: 488192247
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488192247
• Sourires canoniques: CC1(CCCC(N1[O])(C)C)C
• InChIKey: QYTDEUPAUMOIOP-UHFFFAOYSA-N
• INCHI: 1S/C9H18NO/c1-8(2)6-5-7-9(3,4)10(8)11/h5-7H2,1-4H3
• Isomères SMILES: CC1(CCCC(N1[O])(C)C)C
• WGK Allemagne: 3
• RTECS: TN8991900
• PubChem CID: 2724126
• Numéro ONU: 3263
• Poids moléculaire: 156.25
• Beilstein: 1422418
• Reaxy-Rn: 1422418

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organoheterocyclic compounds
    • Classe Piperidines

• Kingdom: Organic compounds
• Superclass: Organoheterocyclic compounds
• Classe: Piperidines
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Piperidines
• Alternative Parents: Azacyclic compounds Organopnictogen compounds Organonitrogen compounds Organic oxygen compounds Hydrocarbon derivatives
• Molecular Framework: Aliphatic heteromonocyclic compounds
• Substituents: Piperidine - Azacycle - Organic nitrogen compound - Organic oxygen compound - Organopnictogen compound - Hydrocarbon derivative - Organonitrogen compound - Aliphatic heteromonocyclic compound
• Description: This compound belongs to the class of organic compounds known as piperidines. These are compounds containing a piperidine ring, which is a saturated aliphatic six-member ring with one nitrogen atom and five carbon atoms.
• External Descriptors: piperidines - aminoxyls

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Cibles associées (non humaines)

Plasmodium falciparum (966862 Activities)

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Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Mécanismes d'action

Propriétés chimiques et physiques

• Solubilité: Soluble in all organic solvents. Insoluble in water.
• Sensibilité: heat sensitive；Air sensitive
• Point d'éclair (°F): 152.6 °F
• Point d'éclair (°C): 67℃
• Point d'ébullition (°C): 193°C
• Point de fusion (°C): 39°C
• Poids moléculaire: 156.250 g/mol
• XLogP3: 1.400
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 156.139 Da
• Monoisotopic Mass: 156.139 Da
• Topological Polar Surface Area: 4.200 Ų
• Heavy Atom Count: 11
• Formal Charge: 0
• Complexity: 136.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1