Allyltrimethoxysilane - ≥97%(GC) , CAS No.2551-83-9

CAS: 2551-83-9 Cat. No.: A151275 分子式: C₆H₁₄O₃Si 分子量: 162.26 Beilstein Registry Number: 2350750 EC番号: 219-855-8

GRADE & PURITY ≥97%(GC)

Synonyms

A901416 | Allyltrimethoxysilane, 95% | SCHEMBL93295 | J-016033 | FT-0694825 | FS-4958 | LFRDHGNFBLIJIY-UHFFFAOYSA-N | Silane, trimethoxy-2-propenyl- | MFCD00053865 | AKOS008901195 | Silane, allyltrimethoxy- | Allyltrimethoxysilane, >=98%, deposition grade

Storage

Room temperature,Argon charged

Shipped In

Normal

概要

Allyltrimethoxysilane is an allylating reagent that can be used for the allylation of carbonyl compounds such as aldehydes, ketones, and imines. Homoallylic alcohols and amines are obtained via the C-C bond forming reaction.It can also be used to synthesize homoallylic α-branched amines from aromatic and aliphatic aldehyde hydrazones, and ketone hydrazones.

Specifications

同義語

A901416 | Allyltrimethoxysilane, 95% | SCHEMBL93295 | J-016033 | FT-0694825 | FS-4958 | LFRDHGNFBLIJIY-UHFFFAOYSA-N | Silane, trimethoxy-2-propenyl- | MFCD00053865 | AKOS008901195 | Silane, allyltrimethoxy- | Allyltrimethoxysilane, >=98%, deposition grade

仕様と純度

≥97%(GC)

保管条件

Room temperature,Argon charged

入荷

Normal

純度

≥97%(GC)

名前と識別子

• パブケム・シド: 488185156
• パブケム・シド・ウル: https://pubchem.ncbi.nlm.nih.gov/substance/488185156
• カノニカル・スマイル: CO[Si](CC=C)(OC)OC
• IUPAC Name: trimethoxy(prop-2-enyl)silane
• InChIKey: LFRDHGNFBLIJIY-UHFFFAOYSA-N
• INCHI: 1S/C6H14O3Si/c1-5-6-10(7-2,8-3)9-4/h5H,1,6H2,2-4H3
• 異性体SMILES: CO[Si](CC=C)(OC)OC
• WGKドイツ: 3
• UN番号: 1993
• 包装グループ: III
• 分子量: 162.26
• Beilstein: 2350750
• Reaxy-Rn: 2350745
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=2350745&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • 分類 Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Alkoxysilanes
          • Level6 Trialkoxysilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• 分類: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Alkoxysilanes
• Direct Parent: Trialkoxysilanes
• Alternative Parents: Silyl ethers Organoheterosilanes Organic metalloid salts Organooxygen compounds Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkoxysilane - Silyl ether - Organoheterosilane - Organic metalloid salt - Organic oxygen compound - Hydrocarbon derivative - Organic salt - Organooxygen compound - Aliphatic acyclic compound
• 説明: This compound belongs to the class of organic compounds known as trialkoxysilanes. These are organosilicon compounds with the general formula RO[Si](R')(OR'')OR''' (R-R''' = aliphatic organyl group).
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

化学的性質と物理的性質

• 感度: Moisture sensitive
• 屈折率: 1.405
• 引火点（°F）: 114.8 °F
• 引火点（°C）: 31°C
• 沸点（°C）: 136°C
• 分子量: 162.260 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 162.071 Da
• Monoisotopic Mass: 162.071 Da
• Topological Polar Surface Area: 27.700 Ų
• Heavy Atom Count: 10
• Formal Charge: 0
• Complexity: 92.900
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

参考文献

1. Bo Wang, Jianhua Sha, Shuaishuai Chen, Weiyan Yin, Yude Li, Qinyan Yue, Haiyan Yu, Shiping Xu.  (2023)  Enhanced adsorption-photocatalysis synergy and stability of polypropylene photocatalytic floating ball benefitted from click chemistry connection.  JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,      [PMID:] [10.1016/j.jphotochem.2023.114883]