EH44 - ≥99%(HPLC) , CAS No.1879076-81-9

CAS: 1879076-81-9 Cat. No.: E465590 分子量: 733.94
注文可能
グレード&純度 ≥99%(HPLC)
Synonyms
9-(2-Ethylhexyl)-N,N,N,N-tetrakis(4-methoxyphenyl)- 9H-carbazole-2,7-diamine)
Storage
Room temperature
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サイズ
USA
ドイツ (EU)*
価格
個数
1g
E465590-1g
受注生産 · 8~12週間

$893.90

$1,043.90
保存 $150.00 (14.37%)
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このグレードを選ぶ理由

≥99%(HPLC) ベースライン干渉を最小限に抑える必要がある、感度の高いクロマトグラフィーおよび分析ワークフロー向け。

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保管・配送

Room temperature に出荷。正確な仕様については、ロット固有の COA をご確認ください。

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品質書類

SDS、COA、データシート、仕様書をダウンロードできます。ロット固有の COA はロット番号検索で入手可能です。

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文献的裏付け

クロマトグラフィー、有機合成、クロスカップリング反応に関する 0 件の査読済み論文で引用されています。

概要

Description

EH44 is a carbazole derivative used as interfacial, hole transporting and contact layer in perovskite solar cell (PSC). Using EH44 can increase the performance and the lifetime of the devices. EH44 is a Li+free, hydrophobic hole transporting material (HTM) which can eliminate degradation due to Li+migration, supresse degradation due to moisture absorption and has long-term stability in fabricated PSC.EH44 is a Li+ free, hydrophobic hole transporting material (HTM). It eliminates degradation due to Li+ migration, supresses degradation due to moisture absorption and thus showed promise for achieving long-term stability in fabricated perovskite solar cells.Using EH44 as HTM in a device configuration of: SnO2/PAL/EH44/MoOx /Al, not only generated high power conversion efficiency (PCE) comparable to the record PCE by using the state-of-the-art-HTM Spiro-OMeTAD, but also most importantly showed greatly improved device stability: even under the combined stresses of light (including ultraviolet light), oxygen and moisture, perovskite solar cells using EH44 as hole transporting layer were shown to retain 94% of their peak efficiency despite 1,000 hours of continuous unencapsulated operation in ambient air conditions (relative humidity of 10-20%). When stability tests were conducted in an inert atmosphere, degradation of only ∼2% over the course of 1,500 hours of continuous operation was observed.Note that in the above mentioned result, silver bis(trifluoromethanesulfonyl)imide (product 668001) was used to oxidize EH44 and yield EH44+TFSI−.EH44+TFSI−was then blended with neat EH44 at various ratios to control the conductivity (and optical transparency if desired) and optimize the device performance. The impressive power conversion efficiency (PCE) of 18.5% was achieved for a perovskite solar cell using EH44 layers of ∼60 nm thickness doped with 14wt% EH44+TFSI−and 25 mg/ml 4-tert-butylpyridine (product 142379), which is comparable to device performance using spiro-OMeTAD (19%) as the HTM.EH44 can be used as an HTM with a high power conversion efficiency (PCE) in comparison to PCE of spiro-OMETAD. It was used in PSC with 94% retention of peak efficiency after 1000 hours of operation.

仕様

同義語
9-(2-Ethylhexyl)-N,N,N,N-tetrakis(4-methoxyphenyl)- 9H-carbazole-2,7-diamine)
仕様と純度
≥99%(HPLC)
保管条件
Room temperature
純度
≥99%(HPLC)
名前と識別子
カノニカル・スマイル
CCC(CCCC)CN1C2=CC(N(C3=CC=C(OC)C=C3)C4=CC=C(OC)C=C4)=CC=C2C5=CC=C(N(C6=CC=C(OC)C=C6)C7=CC=C(OC)C=C7)C=C15
分子量
733.94
Reaxy-Rn
32142370
Reaxys-RN_link_address
https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=32142370&ln=

ドキュメント

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✅ 分析証明書(COA)

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📊 データシート

製品仕様と用途のクイックリファレンス概要。

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🔬 仕様書

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詳細データ

証明書(CoA、COO、BSE/TSEと分析図)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:
化学的性質と物理的性質
溶解度insoluble (Methanol and Hexane)soluble (DMSO, THF, Toluene, o-Xylene, Anisole, Chloroform, Chlorobenzene, and 1,2-Dichlorobenzene)
引火点(°F)Not applicable
引火点(°C)Not applicable
ソリューション計算機
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