Lithium chloride - ≥99.9% metals basis , CAS No.7447-41-8

CAS: 7447-41-8 Cat. No.: L573372 分子式: LiCl 分子量: 42.39 EC番号: 231-212-3

GRADE & PURITY ≥99.9% metals basis

Synonyms

CCRIS 5924 | HSDB 4281 | Lithium chloride, puriss. p.a., ACS reagent, anhydrous, >=99.0% (AT) | NCGC00093980-01 | (2R)-2-({[(1,1-dimethylethyl)oxy]carbonyl}amino)-3-naphthalen-2-ylpropanoic acid | (S)-N-(9-FLUORENYLMETHOXYCARBONYL)-2-AMINO-4-PENTYNOIC ACI

Storage

Room temperature,Argon charged,Desiccated

Shipped In

Normal

概要

Lithium chloride can be used as:

The source of chloride anions, used to convert alcohols into alkyl chlorides under photochemical conditions.

Additives in palladium-catalyzed coupling and carbonylation coupling reactions of organosilanes and trifluoroethylene esters.

Reagent for the cleavage of protecting groups under mild conditions. It readily converts acetal and ketone compounds into the corresponding carbonyl compounds.

In the DMF environment, the reagent for dehydrohalogenating α-halocarbonyl compounds into α,β-unsaturated carbonyl compounds.

LiCl can also be used in combination with other reagents:

LiCl:DIPEA (1:1 molar ratio) is used in the Horeau–Worsham–Emmons alkylation reaction.

Trimethylphosphine oxide is used in decarboxylative alkylation and chloride ion displacement reactions.

LiCl is used as an additive in solid-phase peptide synthesis because it increases resin expansion and improves the efficiency of complex coupling steps.

Specifications

同義語

CCRIS 5924 | HSDB 4281 | Lithium chloride, puriss. p.a., ACS reagent, anhydrous, >=99.0% (AT) | NCGC00093980-01 | (2R)-2-({[(1,1-dimethylethyl)oxy]carbonyl}amino)-3-naphthalen-2-ylpropanoic acid | (S)-N-(9-FLUORENYLMETHOXYCARBONYL)-2-AMINO-4-PENTYNOIC ACI

仕様と純度

≥99.9% metals basis

保管条件

Room temperature,Argon charged,Desiccated

入荷

Normal

純度

≥99.9% metals basis

名前と識別子

カノニカル・スマイル

[Li+].[Cl-]

IUPAC Name

lithium;chloride

InChIKey

KWGKDLIKAYFUFQ-UHFFFAOYSA-M

INCHI

1S/ClH.Li/h1H;/q;+1/p-1

異性体SMILES

[Li+].[Cl-]

WGKドイツ

3

RTECS

OJ5950000

分子量

42.39

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • 分類 Alkali metal salts
      • Subclass Alkali metal chlorides

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• 分類: Alkali metal salts
• Subclass: Alkali metal chlorides
• Intermediate Tree Nodes: Not available
• Direct Parent: Alkali metal chlorides
• Alternative Parents: Inorganic lithium salts Inorganic chloride salts
• Molecular Framework: Not available
• Substituents: Alkali metal chloride - Inorganic lithium salt - Inorganic chloride salt - Inorganic salt
• 説明: This compound belongs to the class of inorganic compounds known as alkali metal chlorides. These are inorganic compounds in which the largest halogen atom is Chlorine, and the heaviest metal atom is an alkali metal.
• External Descriptors: inorganic chloride - lithium salt

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

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作用メカニズム

化学的性質と物理的性質

• 感度: Hygroscopic；Moisture sensitive
• 沸点（°C）: 1360℃
• 融点（°C）: 605 °C (lit.)
• 分子量: 42.400 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 41.9849 Da
• Monoisotopic Mass: 41.9849 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 2
• Formal Charge: 0
• Complexity: 2.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3