Sodium amide - 50 wt. % suspension in toluene , CAS No.7782-92-5

CAS: 7782-92-5 Cat. No.: S434056 Molecular Weight: 39.01 EC Number: 231-971-0 PubChem CID: 24533

GRADE & PURITY 50 wt. % suspension in toluene

Synonyms

EC 231-971-0 | EINECS 231-971-0 | FT-0689068 | HSDB 692 | Q188260 | SODIUM AMIDE | SODIUM AMIDE [MI] | AKOS015960454 | 5DB3G6PX9D | SODIUM AMIDE [HSDB] | Sodium amide (Na(NH2)) | Sodium amide, 50 wt. % suspension in toluene | Sodium amide, hydrogen-storag

Storage

Room temperature

Overview

Sodium amide, an inorganic compound used in organic synthesis, is generally prepared by heating sodium metal in gaseous ammonia. It is used in some organic reactions like dehalogenation, deprotonation, anionic polymerization of ionic chains, and in cleavage of ketones.

Application

Reagent for: Synthesis of allylic amines and amides Synthesis of antibacterials Aggregative activation and heterocyclic chemistry Phenylation with diphenyliodonium chloride

Specifications

Synonyms

EC 231-971-0 | EINECS 231-971-0 | FT-0689068 | HSDB 692 | Q188260 | SODIUM AMIDE | SODIUM AMIDE [MI] | AKOS015960454 | 5DB3G6PX9D | SODIUM AMIDE [HSDB] | Sodium amide (Na(NH2)) | Sodium amide, 50 wt. % suspension in toluene | Sodium amide, hydrogen-storag

Specifications & Purity

50 wt. % suspension in toluene

Storage

Room temperature

Names and Identifiers

• Canonical Smiles: [NH2-].[Na+]
• IUPAC Name: sodium;azanide
• InChIKey: ODZPKZBBUMBTMG-UHFFFAOYSA-N
• INCHI: 1S/H2N.Na/h1H2;/q-1;+1
• Isomeric SMILES: [NH2-].[Na+]
• WGK Germany: 2
• PubChem CID: 24533
• UN Number: 1390
• Packing Group: II
• Molecular Weight: 39.01

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Class Alkali metal organides
      • Subclass Alkali metal nitrides

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Class: Alkali metal organides
• Subclass: Alkali metal nitrides
• Intermediate Tree Nodes: Not available
• Direct Parent: Alkali metal nitrides
• Alternative Parents: Inorganic sodium salts Inorganic nitrides
• Molecular Framework: Not available
• Substituents: Alkali metal nitride - Inorganic sodium salt - Inorganic nitride - Inorganic salt
• Description: This compound belongs to the class of inorganic compounds known as alkali metal nitrides. These are inorganic compounds of nitrogen where nitrogen has a formal oxidation state of -3, and the heaviest metal atom is an alkali metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Boil Point(°C): 400°C
• Melt Point(°C): 210°C
• Molecular Weight: 39.013 g/mol
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 39.0085 Da
• Monoisotopic Mass: 39.0085 Da
• Topological Polar Surface Area: 1.000 Ų
• Heavy Atom Count: 2
• Formal Charge: 0
• Complexity: 2.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

References

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