Triisopropylsilane（TIPS） - ≥98.5% , CAS No.6485-79-6

CAS: 6485-79-6 Cat. No.: T420182 分子式: C₉H₂₂Si 分子量: 158.36 Beilstein Registry Number: 1733718 EC番号: 464-880-1

グレード＆純度 ≥98.5%

Synonyms

EN300-117959 | J-525100 | tris(propan-2-yl)silane | PD118098 | AKOS006222744 | AS-19155 | Aksci Bulk ReagentTriisopropylsilane | Triisopropylsilane, 98% | A14931 | AKOS030228028 | Benzenesulfonic acid,5-[(4-amino-1-naphthalenyl)azo]-2-[2-[4-[(2-hydroxy-1-

Storage

Room temperature,Argon charged

Shipped In

Normal

概要

Triisopropylsilane (TIPS) is an organosilicon compound used as a reducing agent in organic synthesis due to its relatively low toxicity, ease of handling, and its ability to selectively reduce various functional groups. It is used in the presence of a Lewis acid such as titanium (IV) chloride to selectively reduce ketones and aldehydes to their corresponding alkanes and selective reduction of epoxides to the corresponding alcohols.
Purpose
Triisopropylsilane can be used as a reducing agent:
To synthesize 4-pyrrole phenylacyl peptide during solid-phase peptide synthesis. 
In transition metal complex-catalyzed reaction of amides with hydrosilanes. 
For the selective reduction of C-arylglucosides into β-C-aryl glucosides.
To facilitate the cleavage of acetamidomethyl (Acm), 4-methoxybenzyl (Mob), and tert-butyl (But) protecting groups from cysteine (Cys) residues in the presence of trifluoroacetic acid.
For the reduction of amides to corresponding amines in the presence of transition-metal catalysts.

仕様

同義語

EN300-117959 | J-525100 | tris(propan-2-yl)silane | PD118098 | AKOS006222744 | AS-19155 | Aksci Bulk ReagentTriisopropylsilane | Triisopropylsilane, 98% | A14931 | AKOS030228028 | Benzenesulfonic acid,5-[(4-amino-1-naphthalenyl)azo]-2-[2-[4-[(2-hydroxy-1-

仕様と純度

≥98.5%

保管条件

Room temperature,Argon charged

入荷

Normal

純度

≥98.5%

名前と識別子

パブケム・シド

508811475

パブケム・シド・ウル

https://pubchem.ncbi.nlm.nih.gov/substance/508811475

カノニカル・スマイル

CC(C)[Si](C(C)C)C(C)C

InChIKey

ZGYICYBLPGRURT-UHFFFAOYSA-N

INCHI

1S/C9H21Si/c1-7(2)10(8(3)4)9(5)6/h7-9H,1-6H3

異性体SMILES

CC(C)[Si](C(C)C)C(C)C

WGKドイツ

3

UN番号

1993

分子量

158.36

Beilstein

1733718

Reaxy-Rn

1733718

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Hydrocarbon derivatives

• Kingdom: Organic compounds
• Superclass: Hydrocarbon derivatives
• 分類: Not available
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Hydrocarbon derivatives
• Alternative Parents: Organosilicon compounds
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Hydrocarbon derivative - Organosilicon compound - Organic metalloid moeity - Aliphatic acyclic compound
• 説明: This compound belongs to the class of organic compounds known as hydrocarbon derivatives. These are derivatives of hydrocarbons obtained by substituting one or more carbon atoms by an heteroatom. They contain at least one carbon atom and heteroatom.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

化学的性質と物理的性質

• 溶解度: Immiscible with water.
• 感度: Moisture sensitive.
• 屈折率: 1.434
• 引火点（°F）: 100.4 °F
• 引火点（°C）: 38 °C
• 沸点（°C）: 84-86 °C/35 mmHg (lit.)
• 分子量: 157.350 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 157.141 Da
• Monoisotopic Mass: 157.141 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 10
• Formal Charge: 0
• Complexity: 65.700
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3