Chlorotrimethylsilane (TMCS) - for GC derivatization, ≥99%(GC) , CAS No.75-77-4

CAS: 75-77-4 Cat. No.: C131616 Formula: C₃H₉ClSi Peso molecolare: 108.64 Beilstein Registry Number: 1209232 Numero EC: 200-900-5

GRADE & PURITY for GC derivatization, ≥99%(GC)

Synonyms

TMCS | UN1298 | 62UO4690X6 | Chlorotrimethylsilane, puriss., >=99.0% (GC) | TMS chloride | trimethyichlorosilane | SCHEMBL1319 | Trimethyl chlorosilane | Trimethylsilylchloride | trimethylsilyl-chloride | trimethylsilanyl chloride | (CH3)3SiCl | F0001-190

Storage

Room temperature,Argon charged,Desiccated

Shipped In

FedEx DG Service

Panoramica

Chloro Trimethylsilane is a Silane based reagent, which can be used to derive triglycerides into volatile fatty esters by gas chromatography (GC)

Specifications

Sinonimi

TMCS | UN1298 | 62UO4690X6 | Chlorotrimethylsilane, puriss., >=99.0% (GC) | TMS chloride | trimethyichlorosilane | SCHEMBL1319 | Trimethyl chlorosilane | Trimethylsilylchloride | trimethylsilyl-chloride | trimethylsilanyl chloride | (CH3)3SiCl | F0001-190

Specifiche e purezza

for GC derivatization, ≥99%(GC)

Condizioni di conservazione di stoccaggio

Room temperature,Argon charged,Desiccated

Spedito in

FedEx DG Service

Grado

for GC derivatization

Purezza

≥99%(GC)

Nomi e identificatori

• Pubchem Sid: 504751085
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504751085
• Sorrisi canonici: C[Si](C)(C)Cl
• IUPAC Name: chloro(trimethyl)silane
• InChIKey: IJOOHPMOJXWVHK-UHFFFAOYSA-N
• INCHI: 1S/C3H9ClSi/c1-5(2,3)4/h1-3H3
• Isomeri SMILES: C[Si](C)(C)Cl
• WGK Germania: 2
• RTECS: VV2710000
• Numero UN: 1298
• Gruppo di imballaggio: II
• Peso molecolare: 108.64
• Beilstein: 1209232
• Reaxy-Rn: 1209232
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1209232&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Classe Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Organoheterosilanes
          • Level6 Trialkylheterosilanes
            • Level7 Trialkylchlorosilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Classe: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Organoheterosilanes - Trialkylheterosilanes
• Direct Parent: Trialkylchlorosilanes
• Alternative Parents: Silyl monohalides Organochlorosilanes Organic metalloid salts Alkylhalosilanes Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkylchlorosilane - Silyl monohalide - Organochlorosilane - Organic metalloid salt - Alkylhalosilane - Hydrocarbon derivative - Organic salt - Aliphatic acyclic compound
• Descrizione: This compound belongs to the class of organic compounds known as trialkylchlorosilanes. These are organoheterosilanes, bearing a silicon atom linked to three alkyl groups and one chlorine atom.
• External Descriptors: silyl chloride

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Obiettivi associati (umani)

AR Tclin Androgen Receptor (11781 Activities)

Discover Target: AR

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

ALDH1A1 Tchem Aldehyde dehydrogenase 1A1 (77053 Activities)

Discover Target: ALDH1A1

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Obiettivi associati (non umani)

Ppard Peroxisome proliferator-activated receptor delta (358 Activities)

Discover Target: Ppard

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Meccanismi d'azione

Proprietà chimiche e fisiche

• Indice di rifrazione: 1.3884
• Punto di infiammabilità (°F): -4 °F
• Punto di infiammabilità (°C): -28℃
• Punto di ebollizione (°C): 57°C
• Punto di fusione (°C): -40°C
• Peso molecolare: 108.640 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 108.016 Da
• Monoisotopic Mass: 108.016 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 5
• Formal Charge: 0
• Complexity: 28.400
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

Riferimenti

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58. Ni Tan, Yang Feng, Ping Hu, Qi Li, Chuan-Huang Lin, Yu-Hao Ning, Hao-Nan Zhou, Lin-Ping Yu, Zhong Cao, Ju-Lan Zeng.  (2021)  Hydrophobic modification of silica/exfoliated graphite nanoplatelets aerogel and its application as supporting material for form-stable phase change materials.  JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,      [PMID:] [10.1016/j.jiec.2021.04.054]

59. Zhang Xueting, Chen Zhenzhen, Tao Chun, Zhang Jing, Zhang Minxin, Zhang Jialiang, Liu Zhihong, Lin Jiao, Xu Hang, Zhang Qian, Song Hongtao.  (2021)  Effect of Surface Property on the Release and Oral Absorption of Solid Sirolimus-Containing Self-microemulsifying Drug Delivery System.  AAPS PHARMSCITECH,  22  (3): (1-12).  [PMID:33718989] [10.1208/s12249-021-01978-z]

60. Panlei Liu, Na Sun, Yuanyuan Mi, Xiaohang Luo, Xiaoxiao Dong, Jiaye Cai, Xilai Jia, Melvin A. Ramos, Travis Shihao Hu, Quan Xu.  (2021)  Ultra-low CNTs filled high-performance fast self-healing triboelectric nanogenerators for wearable electronics.  COMPOSITES SCIENCE AND TECHNOLOGY,      [PMID:] [10.1016/j.compscitech.2021.108733]

61. Tangping Peng, Jundong Zhu, Tao Huang, Chongwen Jiang, Fuxing Zhao, Shengzhuo Ge, Le Xie.  (2021)  Facile preparation for gelatin/hydroxyethyl cellulose-SiO2 composite aerogel with good mechanical strength, heat insulation, and water resistance.  JOURNAL OF APPLIED POLYMER SCIENCE,  138  (23): (50539).  [PMID:] [10.1002/app.50539]

62. Yue Sheng, Li Xiaolei, Yu Huijun, Tong Zongwei, Liu Zhengdao.  (2021)  Preparation of high-strength silica aerogels by two-step surface modification via ambient pressure drying.  JOURNAL OF POROUS MATERIALS,  28  (3): (651-659).  [PMID:] [10.1007/s10934-020-00990-1]

63. Shuaijun Yu, Jiajie Zhu, Junbin Liao, Huimin Ruan, Arcadio Sotto, Jiangnan Shen.  (2020)  Homogeneous trimethylamine-quaternized polysulfone-based anion exchange membranes with crosslinked structure for electrodialysis desalination.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2020.117874]

64. Gong Zhang, Jiahui Wang, Yuefei Wang, Wei Qi, Rongxin Su, Zhimin He.  (2020)  Self-Assembly of Ferrocene-Phenylalanine@Graphene Oxide Hybrid Hydrogels for Dopamine Detection.  ChemPlusChem,  85  (10): (2341-2348).  [PMID:33094928] [10.1002/cplu.202000579]

65. Ha N. Giang, Truyen X. Nguyen, Tien V. Huynh, Lam H. Tran, Hoa N. Nguyen, Khanh B. Vu, Van V. Vu.  (2020)  Fabrication of superhydrophobic surface using one-step chemical treatment.  Surfaces and Interfaces,      [PMID:] [10.1016/j.surfin.2020.100673]

66. Haoji Lao, Nafeesa Mushtaq, Guofei Chen, Hongyu Jiang, Yang Jiao, Anjiang Zhang, Xingzhong Fang.  (2020)  Transparent polyamide-imide films with high Tg and low coefficient of thermal expansion: Design and synthesis.  POLYMER,      [PMID:] [10.1016/j.polymer.2020.122889]

67. Gaohui Sun, Tianjiao Duan, Cheng Liu, Liu Zhang, Rongrong Chen, Jun Wang, Shihui Han.  (2020)  Fabrication of flame-retardant and smoke-suppressant isocyanate-based polyimide foam modified by silica aerogel thermal insulation and flame protection layers.  POLYMER TESTING,      [PMID:] [10.1016/j.polymertesting.2020.106738]

68. Chengdong Xiong, Zhenzhen Quan, Hongnan Zhang, Liming Wang, Xiaohong Qin, Rongwu Wang, Jianyong Yu.  (2020)  Hierarchically tunable structure of polystyrene-based microfiber membranes for separation and selective adsorption of oil-water.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2020.147400]

69. Ming Wei, Linjuan Huang, Yuxia Liu, Wanjun Jin, Xinbo Yao, Jinqiao Rong, Fan Bai, Xuezheng Song, Zhongfu Wang.  (2020)  Strategy for Isolation, Preparation, and Structural Analysis of Chondroitin Sulfate Oligosaccharides from Natural Sources.  ANALYTICAL CHEMISTRY,      [PMID:32709191] [10.1021/acs.analchem.0c01410]

70. Yeyang Li, Meisheng Li, Shouyong Zhou, Ailian Xue, Yan Zhang, Yijiang Zhao, Jing Zhong, Qi Zhang, Dawei Yang.  (2020)  Enhancement of hydroxide conductivity by incorporating nanofiber-like palygorskite into quaternized polysulfone as anion exchange membranes.  APPLIED CLAY SCIENCE,      [PMID:] [10.1016/j.clay.2020.105702]

71. Ruizhang Xu, Lei Ding, Dandan Chen, Tianyu Liu, Yunqi Wu, Ya Cao, Jinyao Chen, Feng Yang, Jian Kang, Ming Xiang.  (2020)  Enhancing the Chlorine Stability and Antifouling Properties of Thin-Film Composite Reverse Osmosis Membranes via Surface Grafting L-Arginine-Functionalized Polyvinyl Alcohol.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.0c00904]

72. Qilin Mei, Honghua Wang, Xiaocheng Chen, Ying Wang, Zhixiong Huang.  (2020)  A Novel Zirconium Modified Arylacetylene Resin: Preparation, Thermal Properties and Ceramifiable Mechanism.  Polymers,  12  (3): (684).  [PMID:32204398] [10.3390/polym12030684]

73. Yujie Zhang, Hui Zhong, Zi'ang Cao, Shouyong Zhou, Dabing Zhang, Renling Lu, Haifeng Han, Mingliang Zhang, Hongdeng Qiu.  (2020)  Design and evaluation of polar-embedded stationary phases containing triacontyl group for liquid chromatography.  JOURNAL OF CHROMATOGRAPHY A,      [PMID:32188564] [10.1016/j.chroma.2020.461035]

74. Kai Li, Qingming Luo, Juan Xu, Kun Li, Wenwen Zhang, Lanxiang Liu, Jinju Ma, Hong Zhang.  (2020)  A Novel Freeze-Drying-Free Strategy to Fabricate a Biobased Tough Aerogel for Separation of Oil/Water Mixtures.  JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY,      [PMID:32142264] [10.1021/acs.jafc.9b07629]

75. Mengxin Zhang, Ruiqin Wang, Zuwei Wang, Ying Guan, Yongjun Zhang.  (2020)  Periodic pattern of iron oxide using 2D microgel colloidal crystal as template.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2020.145737]

76. Nafeesa Mushtaq, Qiaodi Wang, Guofei Chen, Beenish Bashir, Haoji Lao, Yuanming Zhang, Lala Rukh Sidra, Xingzhong Fang.  (2020)  Synthesis of polyamide-imides with different monomer sequence and effect on transparency and thermal properties.  POLYMER,      [PMID:] [10.1016/j.polymer.2020.122218]

77. Xueyang Li, Hao Liu, Xiaoyan Xu, Bing Yang, Hong Yuan, Jingwei Guo, Fengting Sang, Yuqi Jin.  (2020)  Lotus-Leaf-Inspired Flexible and Tunable Random Laser.  ACS Applied Materials & Interfaces,      [PMID:31957437] [10.1021/acsami.9b23524]

78. Jianmei Wang, Xueying Wang, Pingan Zhu, Chengmin Chen, Jianchun Wang, Yan Li, Liqiu Wang.  (2019)  Microfluidic Rapid Fabrication of Tunable Polyvinyl Alcohol Microspheres for Adsorption Applications.  Materials,  12  (22): (3712).  [PMID:31717907] [10.3390/ma12223712]

79. Wu Xiaoxu, Zhang Wei, Li Zhi, Zhang Yan, Huang Siqi, Liu Qiong.  (2019)  Effects of various methylchlorosilanes on physicochemical properties of ambient pressure dried silica aerogels.  JOURNAL OF NANOPARTICLE RESEARCH,  21  (11): (1-13).  [PMID:] [10.1007/s11051-019-4685-0]

80. Chao Wang, Nengxiu Pan, Yuliang Jiang, Junbin Liao, Arcadio Sotto, Huimin Ruan, Congjie Gao, Jiangnan Shen.  (2019)  A facile approach to prepare crosslinked polysulfone-based anion exchange membranes with enhanced alkali resistance and dimensional stability.  RSC Advances,  9  (62): (36374-36385).  [PMID:35540625] [10.1039/C9RA07433C]

81. Long Zhao, Zhanlin Zhang, Maohua Chen, Yuan Liu, Tao Wang, Xiaohong Li.  (2019)  Fluorescent fibrous mats assembled with self-propagating probes for visual sensing of hydrogen peroxide and choline.  ANALYST,  144  (18): (5624-5636).  [PMID:31432883] [10.1039/C9AN01120J]

82. Jian Chen, Zhijie Wu, Haiyan Liu, Xiaojun Bao, Pei Yuan.  (2019)  A Surface-Cofunctionalized Silica Supported Palladium Catalyst for Selective Hydrogenation of Nitrile Butadiene Rubber with Enhanced Catalytic Activity and Recycling Performance.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.9b01468]

83. Jing-Wen Hao, Nai-Dong Chen, Xu-Cheng Fu, Jian Zhang.  (2019)  Predicting the contents of polysaccharides and its monosugars in Dendrobium huoshanense by partial least squares regression model using attenuated total reflectance Fourier transform infrared spectroscopy.  SPECTROSCOPY LETTERS,      [PMID:] [10.1080/00387010.2019.1630445]

84. Jingjing Sun, Jiumei Hu, Tong Gou, Xiong Ding, Qi Song, Wenshuai Wu, Guoping Wang, Juxin Yin, Ying Mu.  (2019)  Power-free polydimethylsiloxane femtoliter-sized arrays for bead-based digital immunoassays.  BIOSENSORS & BIOELECTRONICS,      [PMID:31132722] [10.1016/j.bios.2019.111339]

85. Xun Zhao, Yilin Zhu, Yingzi Wang, Zhipeng Li, Yatong Sun, Songfang Zhao, Xiangwen Wu, Duxia Cao.  (2019)  Hydrophobic, blocky silica-reduced graphene oxide hybrid sponges as highly efficient and recyclable sorbents.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2019.05.017]

86. Naeem Akhtar Qaisrani, Lingling Ma, Jiafei Liu, Manzoor Hussain, Lv Li, Panyue Li, Shoutao Gong, Fengxiang Zhang, Gaohong He.  (2019)  Anion exchange membrane with a novel quaternized ammonium containing long ether substituent.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2019.03.054]

87. Yuliang Jiang, Chao Wang, Jiefeng Pan, Arcadio Sotto, Jiangnan Shen.  (2019)  Constructing an internally cross-linked structure for polysulfone to improve dimensional stability and alkaline stability of high performance anion exchange membranes.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2019.02.098]

88. Xunli Mao, Zhen Li, Guangwei He, Zongyu Li, Jing Zhao, Yun Zhang, Zhongyi Jiang.  (2019)  Enhancing hydroxide conductivity of anion exchange membrane via incorporating densely imidazolium functionalized graphene oxide.  SOLID STATE IONICS,      [PMID:] [10.1016/j.ssi.2019.01.023]

89. Jing Lyu, Guangyong Li, Meinan Liu, Xuetong Zhang.  (2019)  Aerogel-Directed Energy-Storage Films with Thermally Stimulant Multiresponsiveness.  LANGMUIR,      [PMID:30609377] [10.1021/acs.langmuir.8b04028]

90. Minxin Cui, Yiwei Zhuang, Gang Zou, Bing Zhu, Qijin Zhang.  (2018)  Fabrication of composite optical fiber taper through “click” polymerization initiated by evanescent field for sensing.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2018.12.138]

91. Cong Li, Feng Luo, Haojie Duan, Feilong Dong, Xiaoyang Chen, Mingbao Feng, Zuoran Zhang, Leslie Cizmas, Virender K. Sharma.  (2018)  Degradation of chloramphenicol by chlorine and chlorine dioxide in a pilot-scale water distribution system.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2018.10.019]

92. Zhang Wei, Li Shu-ming, Zhang Jing.  (2018)  Preparation and Chromatographic Features of Fibrous Core–Shell HPLC Packing Material.  CHROMATOGRAPHIA,  81  (9): (1249-1256).  [PMID:] [10.1007/s10337-018-3571-8]

93. Hui Zhang, Qi Tang, Lilong Gao, Hua Yuan, Hai-Lin Cong, Bing Yu.  (2018)  Fabrication and study of superficially porous core-shell SiO2@SiO2 microspheres.  FERROELECTRICS,      [PMID:] [10.1080/00150193.2018.1454099]

94. Xiaohan Wu, Jing Lyu, Guo Hong, Xiang-cui Liu, Xuetong Zhang.  (2018)  Inner Surface-Functionalized Graphene Aerogel Microgranules with Static Microwave Attenuation and Dynamic Infrared Shielding.  LANGMUIR,      [PMID:29958495] [10.1021/acs.langmuir.8b01410]

95. Wang Chao, Li Zhenhuan, Cao Lei, Cheng Bowen.  (2018)  A Superhydrophilic and Anti-Biofouling Polyphenylene Sulfide Microporous Membrane with Quaternary Ammonium Salts.  MACROMOLECULAR RESEARCH,  26  (9): (800-807).  [PMID:] [10.1007/s13233-018-6108-y]

96. Zhang Binbin, Li Yang, Wang Gaoshang, Jia Zhidong, Li Haiyan, Peng Qing, Gao Yi.  (2018)  Fabrication of agarose concave petridish for 3D-culture microarray method for spheroids formation of hepatic cells.  JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE,  29  (5): (1-9).  [PMID:29675647] [10.1007/s10856-018-6058-0]

97. Liu Hai-Ning, Wu Hao, Tseng Yu-Jen, Chen Yan-Jie, Zhang Dan-Ying, Zhu Lin, Dong Ling, Shen Xi-Zhong, Liu Tao-Tao.  (2018)  Serum microRNA signatures and metabolomics have high diagnostic value in gastric cancer.  BMC CANCER,  18  (1): (1-11).  [PMID:29653559] [10.1186/s12885-018-4343-4]

98. Yang Mu, Miao Cui, Shaoqing Zhang, Jing Zhao, Changgong Meng, Qi Sun.  (2018)  Comparison study between a series of new type functional diatomite on methane adsorption performance.  MICROPOROUS AND MESOPOROUS MATERIALS,      [PMID:] [10.1016/j.micromeso.2018.03.037]

99. Zhanying Li, Lin Shao, Wenbin Hu, Tingting Zheng, Lingbin Lu, Yang Cao, Yongjun Chen.  (2018)  Excellent reusable chitosan/cellulose aerogel as an oil and organic solvent absorbent.  CARBOHYDRATE POLYMERS,      [PMID:29661308] [10.1016/j.carbpol.2018.03.027]

100. Zhen Li, Guangwei He, Zongyu Li, Yun Zhang, Jing Zhao, Mingzhao Xu, Shengming Xu, Zhongyi Jiang.  (2018)  Enhancing the hydroxide conductivity of imidazolium-functionalized polysulfone by incorporating organic microsphere with ionic brushes.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2018.02.045]

101. Jiefeng Pan, Jincheng Ding, Yu Zheng, Congjie Gao, Bart. Van der Bruggen, Jiangnan Shen.  (2018)  One-pot approach to prepare internally cross-linked monovalent selective anion exchange membranes.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2018.02.035]

102. Xiaoling Duan, Cunwen Wang, Tielin Wang, Xiaolin Xie, Xingping Zhou, Yunsheng Ye.  (2018)  A polysulfone-based anion exchange membrane for phosphoric acid concentration and purification by electro-electrodialysis.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2018.02.004]

103. Ze Wu, Lei Zhang, Ji Li, Xiaolu Zhao, Chunhui Yang.  (2018)  Organic–inorganic hybridization for the synthesis of robust in situ hydrophobic polypropylsilsesquioxane aerogels with fast oil absorption properties.  RSC Advances,  8  (11): (5695-5701).  [PMID:35539583] [10.1039/C7RA13165H]

104. Xiu-zhong Zhu, Xiao-dong Fan, Na Zhao, Xin Min, Jie Liu, Zi-chao Wang.  (2017)  Influence of mono-lithium based initiators with different steric volumes on 1,4 unit content of hydroxyl terminated polybutadiene using anionic polymerization.  RSC Advances,  7  (83): (52712-52718).  [PMID:] [10.1039/C7RA11117G]

105. Yanping Zhang, Binghai Dong, Shimin Wang, Li Zhao, Li Wan, Erjing Wang.  (2017)  Mechanically robust, thermally stable, highly transparent superhydrophobic coating with low-temperature sol–gel process.  RSC Advances,  7  (75): (47357-47365).  [PMID:] [10.1039/C7RA08578H]

106. Qi Song, Jingjing Sun, Ying Mu, Yanan Xu, Qiangyuan Zhu, Qinhan Jin.  (2017)  A new method for polydimethylsiloxane (PDMS) microfluidic chips to maintain vacuum-driven power using Parylene C.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2017.10.006]

107. Zhonghui Chen, Mi Sun, Fang Luo, Kefeng Xu, Zhenyu Lin, Lan Zhang.  (2017)  Stimulus-response click chemistry based aptamer-functionalized mesoporous silica nanoparticles for fluorescence detection of thrombin.  TALANTA,      [PMID:29136862] [10.1016/j.talanta.2017.09.043]

108. Zhang Jing, Song Huanchun, Jiang Shuying, Chen Zhibin, Tong Shuhua, Lin Feiyan, Wen Congcong, Zhang Xiuhua, Hu Lufeng.  (2017)  Fisher Discrimination of Metabolic Changes in Rats Treated with Aspirin and Ibuprofen.  PHARMACOLOGY,      [PMID:28728150] [10.1159/000477971]

109. Qin Wang, Zhuo Chen, Sufen Deng, Shaokun Song, Chuanxi Xiong, Lijie Dong.  (2017)  Fluxible poly(p-phenyleneterephthalamide)-based polymer with tunable condensed state structure and controllable rheology behaviors.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2017.06.185]

110. Wang Liang, Li Zhu, Jing Qiangshan, Liu Peng.  (2017)  Synthesis of composite insulation materials—expanded perlite filled with silica aerogel.  JOURNAL OF POROUS MATERIALS,  25  (2): (373-382).  [PMID:] [10.1007/s10934-017-0448-4]

111. Jia-Ling Dai, Li-Hua Zhao, Jie-Hua Shi.  (2017)  Preparation and evaluation of a novel bonded imidazolium ionic liquid as stationary phase for gas chromatography.  JOURNAL OF SEPARATION SCIENCE,  40  (13): (2769-2778).  [PMID:28481044] [10.1002/jssc.201700130]

112. Qi Tang, Li-Long Gao, Bing Yu, Hai-Lin Cong.  (2017)  Fabrication of core-shell TiO2@SiO2 composites and investigation on its photocatalytic performance of methyl orange from aqueous solution.  INTEGRATED FERROELECTRICS,      [PMID:] [10.1080/10584587.2017.1331388]

113. Houbo Zhou, Yi Chen, Christopher M. Plummer, Huahua Huang, Yongming Chen.  (2017)  Facile and efficient bromination of hydroxyl-containing polymers to synthesize well-defined brominated polymers.  Polymer Chemistry,  8  (14): (2189-2196).  [PMID:] [10.1039/C7PY00283A]

114. Baohua Yue, Guangbo Zeng, Yepei Zhang, Sheng Tao, Xiaoming Zhang, Liuming Yan.  (2016)  Improved performance of acid-base composite of phosphonic acid functionalized polysulfone and triazolyl functionalized polysulfone for PEM fuel cells.  SOLID STATE IONICS,      [PMID:] [10.1016/j.ssi.2016.11.011]

115. Xiaobing Tang, Aihua Sun, Chengyi Chu, Mingli Yu, Si Ma, Yuchuan Cheng, Jianjun Guo, Gaojie Xu.  (2016)  A novel silica nanowire-silica composite aerogels dried at ambient pressure.  MATERIALS & DESIGN,      [PMID:] [10.1016/j.matdes.2016.11.080]

116. Na Du, Xiaoyu Zhu, Ruiying Song, Shue Song, Wanguo Hou.  (2016)  Formation of simple single-tailed vesicles mediated by lipophilic solid surfaces.  Soft Matter,  12  (41): (8574-8580).  [PMID:27714326] [10.1039/C6SM01711H]

117. Zhihong Zhang, Zhengqi Liu, Xueying Tao, Hua Wei.  (2016)  Characterization and sulfated modification of an exopolysaccharide from Lactobacillus plantarum ZDY2013 and its biological activities.  CARBOHYDRATE POLYMERS,      [PMID:27561468] [10.1016/j.carbpol.2016.07.084]

118. Zhao Xiaohui, Liang Weiping, An Dong, Ye Zhiwen.  (2015)  Synthesis and properties of tetrasiloxane Gemini imidazolium surfactants.  COLLOID AND POLYMER SCIENCE,  294  (3): (491-500).  [PMID:] [10.1007/s00396-015-3805-3]

119. Liang HAO, Da-Peng WU, Ya-Feng GUAN.  (2015)  Determination of Dicarboxylic Acids in Fine Atmospheric Particles by Micro-Pressurized Liquid Extraction Coupled with Gas Chromatography-Mass Spectrometer.  CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,      [PMID:] [10.1016/S1872-2040(15)60869-6]

120. Xuemin Yu, Fu Liu, Linghui Wang, Zhu Xiong, Yunze Wang.  (2015)  Robust poly(lactic acid) membranes improved by polysulfone-g-poly(lactic acid) copolymers for hemodialysis.  RSC Advances,  5  (95): (78306-78314).  [PMID:] [10.1039/C5RA15816H]

121. Qishu Qu, Yi Min, Lihua Zhang, Qin Xu, Yadong Yin.  (2015)  Silica Microspheres with Fibrous Shells: Synthesis and Application in HPLC.  ANALYTICAL CHEMISTRY,      [PMID:26321588] [10.1021/acs.analchem.5b02511]

122. Li Ping, Yang Xiaoyi, Guo Chaohua, Wang Guoyong, Zhang Wei.  (2015)  Tetrasiloxane room temperature ionic liquids: adsorption and aggregation properties in aqueous solution.  COLLOID AND POLYMER SCIENCE,  293  (9): (2625-2634).  [PMID:] [10.1007/s00396-015-3664-y]

123. Song Qi, Gao Yibo, Zhu Qiangyuan, Tian Qingchang, Yu Bingwen, Song Bofan, Xu Yanan, Yuan Maokai, Ma Congcong, Jin Wei, Zhang Tao, Mu Ying, Jin Qinhan.  (2015)  A nanoliter self-priming compartmentalization chip for point-of-care digital PCR analysis.  BIOMEDICAL MICRODEVICES,  17  (3): (1-8).  [PMID:26022215] [10.1007/s10544-015-9970-9]

124. Xilun Weng, Zongbi Bao, Zhiguo Zhang, Baogen Su, Huabin Xing, Qiwei Yang, Yiwen Yang, Qilong Ren.  (2014)  Preparation of porous cellulose 3,5-dimethylphenylcarbamate hybrid organosilica particles for chromatographic applications.  Journal of Materials Chemistry B,  3  (4): (620-628).  [PMID:32262344] [10.1039/C4TB01547A]

125. Qiao Wang, Guang-shan Zhang, Zhan-shuang Li, Sheng Deng, Han Chen, Peng Wang.  (2014)  Preparation and properties of polyamide/titania composite nanofiltration membrane by interfacial polymerization.  DESALINATION,      [PMID:] [10.1016/j.desal.2014.08.001]

126. Ma Xiaolei, Cao Xuejun.  (2014)  Separation of ursodeoxycholic acid by silylation crystallization.  Bioresources and Bioprocessing,  1  (1): (1-8).  [PMID:] [10.1186/s40643-014-0005-9]

127. Yongzhao Zhang, Xia Guo, Jianbing Ji.  (2014)  Solubility Determination and Correlation of (2R,3S,4S,5S)-6-(Hydroxymethyl)-tetrahydro-2H-pyran-2,3,4, 5-tetraol in Fatty Alcohol.  JOURNAL OF CHEMICAL AND ENGINEERING DATA,      [PMID:] [10.1021/je4011097]

128. Lei Peng, Shuai Yuan, Ge Yan, Ping Yu, Yunbai Luo.  (2014)  Hydrophobic sponge for spilled oil absorption.  JOURNAL OF APPLIED POLYMER SCIENCE,  131  (20):   [PMID:] [10.1002/app.40886]

129. Xun Yang, Ruiling Wang, Weihua Wang, Hongyuan Yan, Mande Qiu, Yanxue Song.  (2013)  Synthesis of a novel molecularly imprinted organic–inorganic hybrid polymer for the selective isolation and determination of fluoroquinolones in tilapia.  JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES,      [PMID:24334223] [10.1016/j.jchromb.2013.11.040]

130. Qing-hua Niu, Zhi-qiang He, Yun Fang.  (2013)  Synthesis and Physicochemical Properties of Silicon-Terminated Octyl/Decyl Polyethylene Oxide as Novel Low-Foam Penetrating Agents.  JOURNAL OF SURFACTANTS AND DETERGENTS,  17  (4): (759-765).  [PMID:] [10.1007/s11743-013-1543-4]

131. Wen-Wen Yue, Hui-Juan Li, Tao Xiang, Hui Qin, Shu-Dong Sun, Chang-Sheng Zhao.  (2013)  Grafting of zwitterion from polysulfone membrane via surface-initiated ATRP with enhanced antifouling property and biocompatibility.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2013.06.029]

132. Gang Zhang, Dong-ting Bai, Dong-sheng Li, Sheng-ru Long, Xiao-jun Wang, Jie Yang.  (2013)  Synthesis and properties of polyamides derived from 4,6-bis(4-chloroformylphenylthio)pyrimidine and 3,6-bis(4-chloroformylphenylthio)pyridazine.  POLYMER INTERNATIONAL,  62  (9): (1358-1367).  [PMID:] [10.1002/pi.4431]

133. Gang Zhang, Jiangjun Hu, Huiwen Yang, Xiaojun Wang, Shengru Long, Jie Yang.  (2012)  Effects of thioether content on thermal and optical properties of polyamides.  POLYMER INTERNATIONAL,  61  (5): (800-809).  [PMID:] [10.1002/pi.4142]

134. Yang Tang, Hong-Mei Li, Ya-Jie Tang.  (2011)  Comparison of sterol composition between Tuber fermentation mycelia and natural fruiting bodies.  FOOD CHEMISTRY,      [PMID:29243602] [10.1016/j.foodchem.2011.11.077]

135. Gang Zhang, Dong-sheng Li, Guang-shun Huang, Xiao-jun Wang, Sheng-ru Long, Jie Yang.  (2011)  Synthesis and properties of polyamides containing high contents of thioether units.  REACTIVE & FUNCTIONAL POLYMERS,      [PMID:] [10.1016/j.reactfunctpolym.2011.04.008]

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153. Yanxia Zheng, Yubo Yang, Yixuan Li, Lu Cai, Xuanjiao Zhao, Bing Xue, Yuchao Li, Jiutao An, Jialiang Zhang.  (2024)  Preparation of Hydrophobic Au Catalyst and Application in One-Step Oxidative Esterification of Methacrolein to Methyl Methacrylate.  MOLECULES,  29  (8): (1854).  [PMID:38675674] [10.3390/molecules29081854]

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157. Huanxi Xu, Peihua Lin, Pei-Jun Liu, Hai-Gang Liu, Hui-Bin Guo, Chao-Xiang Wu, Ming Fang, Xu Zhang, Guan-Ping Jin.  (2024)  Removal of rubidium from brine by an integrated film of sulfonated polysulfone/graphene/potassium copper ferricyanide.  CHINESE JOURNAL OF CHEMICAL ENGINEERING,      [PMID:] [10.1016/j.cjche.2023.11.028]

158. Zhang Louwen, Zhou Hai, Chen Yibo, Zheng Zhimiao, Huang Lishuai, Wang Chen, Dong Kailian, Hu Zhongqiang, Ke Weijun, Fang Guojia.  (2024)  Spontaneous crystallization of strongly confined CsSnxPb1-xI3 perovskite colloidal quantum dots at room temperature.  Nature Communications,  15  (1): (1-9).  [PMID:38383585] [10.1038/s41467-024-45945-1]

159. Di Zhang, Xiao-Hua Song, Dan Yang, Mu-Zi Ge, Jun Qiu, Han-Qing Jiang, Yan-Yan Sun, Xiang-dong Li, Yi-Jun Wu.  (2025)  Subchronic Exposure to Low-Dose Chlorfenapyr and Emamectin Benzoate Disrupts Kidney Metabolism in Rats.  Toxics,  13  (1): (65).  [PMID:39853063] [10.3390/toxics13010065]

160. Yu Shen, Shihao Wu, Mingming Song, Huiming Zhang, Hong Zhao, Lili Wu, Hongbo Zhao, Hongbin Qiu, Yu Zhang.  (2024)  The Isolation, Structural Characterization and Anti-Inflammatory Potentials of Neutral Polysaccharides from the Roots of Isatis indigotica Fort.  MOLECULES,  29  (11): (2683).  [PMID:38893558] [10.3390/molecules29112683]

161. Liang Zhao, Dingyuan Tang, Qingxia Liu.  (2025)  The mechanisms of bubble-particle detachment in a turbulence.  MINERALS ENGINEERING,      [PMID:] [10.1016/j.mineng.2025.109257]

162. Naeem Akhtar Qaisrani, Waheed Afzal, Usman Khalid, Muther Mansoor Qaisrani, Subhan Azeem, Ali Ahmad, Lingling Ma, Lv Li, Fengxiang Zhang.  (2024)  The role of cross-linkers in the performance of anion exchange membrane for fuel cell applications.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2024.135561]

163. Enwen Liu, Yijuan Chang, Haiqiao Zhang, Zhangbei Chen, Zhihui Wu.  (2025)  Trimethylchlorosilane (TMCS) modified hydrophobic silica dry gel (TSA) enhanced the optical, aging behavior and thermal properties of polyvinyl butyral composite coatings.  Case Studies in Construction Materials,      [PMID:] [10.1016/j.cscm.2025.e04429]

164. Dun Wang, Yinyin Liang, Zhichao Wu, Zhonglin Liu, Yanming Li.  (2025)  Enhanced Thermal Stability and Water Resistance in Silylated Starch/Poly(Propylene Carbonate) Composites via Hydrophobic Modification.  JOURNAL OF APPLIED POLYMER SCIENCE,      [PMID:] [10.1002/app.57680]

165. Hongye Lv, Xuyong Tian, Haowei Feng, Chunlei Wang, Liying Wei, Xiuping Li, Haolong Xue, Changfa Xiao, Dawei Ji.  (2025)  Constructing of stable intermediate layers among the positively charged composite nanofiltration membranes for Mg2+/Li+ efficient separation.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2025.134936]

166. Ke Wang, Wei Gao.  (2025)  Synthesis and comparative analysis of silica aerogel and single/double-shell hollow microspheres for silicone coatings: thermal stability/insulation and mechanical property.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2025.109580]

167. Qingji Wang, Yilin Wang, Dan Wang, Xueying Yang, Ying Tang, Mingna Feng, Mingxia Wang, Xuemin Li, Feng Yan.  (2025)  Ultraefficiency Mg2+/Li+ Separation by Loose Nanofiltration Membrane: The Host–Guest Recognition of Crown Ether.  LANGMUIR,      [PMID:40854884] [10.1021/acs.langmuir.5c03056]

168. Mengmeng Fang, Wenshuo Cui, Qin Shen, Shuai Wang, Chuanjie Fang, Liping Zhu.  (2025)  Narrowed pore size distribution of positively charged nanofiltration membranes via interlayer-tailored interfacial polymerization for lithium extraction.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2025.124771]

169. Mengnan Duan, Jingwei Chen, Yaohui Zhang, Zhijin Yang, Yule Zhang, Qixun Wu, Mengya Chen, Zhiwei Xue, Zhaofeng Huang, Songlin Zhuang, Zhengqin Gu, Lulu Zheng.  (2025)  One-step microfluidic platform driven by π-valve with self-cleaning for high-sensitivity prostate cancer diagnosis.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2025.138764]

170. Yiqing Chen, Yujiao Wang, Shangze Jiang, Xiaolei Guo, Xuanhe Zhang, Zhenwei Liang, Huayu Yang, Yuan Ma, Jiadao Wang.  (2025)  Rapid, Large-scale, and Precise Cell Assembly for Tumor Model Fabrication via Template-modulated Flow-driven Strategy.  Advanced Materials Technologies,      [PMID:] [10.1002/admt.202500295]

171. Jun Liu, Qiu-Yu Hu, Meng-Jie Chang, Xin Li, Shi-Shun Cao.  (2025)  Water glass-based aerogel monolith prepared with formamide catalyst and SiO2 nanofiber reinforcement: Nanoarchitectonics and enhanced mechanical property.  JOURNAL OF SOLID STATE CHEMISTRY,      [PMID:] [10.1016/j.jssc.2025.125651]

172. Wu Xiaoxu, Liu Miao, Hu Min, Chen Zikang, Zhou Fang, Yao Shengjie, Liu Qiong, Li Zhi.  (2025)  Thermal safety of hydrophobic silica aerogels under controlled incorporation of phytic acid-modified graphene oxide.  JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY,      [PMID:] [10.1007/s10971-025-06956-6]

173. Yunna Li, Fan Qi, Jinsong Liu, Yunfei Zhao, Jiale Fang, Xueliang Li, Kezhi Jiang.  (2025)  Determination of Trace Ethephon in Fruit by Catalytic Methylation with (Trimethylsilyl) Diazomethane (TMSD) and Gas Chromatography-Mass Spectrometry (GC-MS).  ANALYTICAL LETTERS,      [PMID:] [10.1080/00032719.2025.2559414]

174. Xiaojuan Bai, Shengqi Yang, Chaohong Tan, Tianqi Jia, Linlong Guo, Wei Song, MeiPeng Jian, Xiaoran Zhang, Ziyang Zhang, Liyuan Wu, Hua Yang, Haiyan Li, Derek Hao.  (2022)  Synthesis of TiO2 based superhydrophobic coatings for efficient anti-corrosion and self-cleaning on stone building surface.  Journal of Cleaner Production,      [PMID:] [10.1016/j.jclepro.2022.134975]

175. Jinfeng Shi, Zhengyang Liu, Na Zhao, Shaofeng Liu, Zhibo Li.  (2022)  Controlled Ring-Opening Polymerization of Hexamethylcyclotrisiloxane Catalyzed by Trisphosphazene Organobase to Well-Defined Poly(dimethylsiloxane)s.  MACROMOLECULES,      [PMID:] [10.1021/acs.macromol.1c02654]

176. Naeem Akhtar Qaisrani, Lingling Ma, Manzoor Hussain, Jiafei Liu, Lv Li, Ruiting Zhou, Yabin Jia, Fengxiang Zhang, Gaohong He.  (2019)  Hydrophilic Flexible Ether Containing, Cross-Linked Anion-Exchange Membrane Quaternized with DABCO.  ACS Applied Materials & Interfaces,      [PMID:31880910] [10.1021/acsami.9b15435]

177. Kaiying Jia, Xueying Tao, Zhengqi Liu, Hui Zhan, Weijun He, Zhihong Zhang, Zheling Zeng, Hua Wei.  (2018)  Characterization of novel exopolysaccharide of Enterococcus faecium WEFA23 from infant and demonstration of its in vitro biological properties.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:30594615] [10.1016/j.ijbiomac.2018.12.245]

178. Jia-Lin Pan, Wan-Shan Shen, Hua-Hui Li, Lei Huang, Zong-Shuo Liu, Zhao-Kui Wang, Bao-Quan Sun, Ya-Kun Wang, Liang-Sheng Liao.  (2025)  Trap-State Suppression via Dual Defect Healing Enables Stable Near-Infrared Lanthanide-Based Quantum Dot LEDs.  ADVANCED FUNCTIONAL MATERIALS,      [PMID:] [10.1002/adfm.202507724]

179. Qishu Qu, Yang Si, Han Xuan, Kehua Zhang, Xiaoming Chen, Yi Ding, Shaojie Feng, Han-Qing Yu, M. Asiri Abdullah, Khalid A. Alamry.  (2018)  Dendritic core-shell silica spheres with large pore size for separation of biomolecules.  JOURNAL OF CHROMATOGRAPHY A,      [PMID:29426717] [10.1016/j.chroma.2018.02.002]

180. Yujia Wang, Shucheng Sun, Irfan Azhar, Qian Zhang, Qishu Qu, Li Yang.  (2017)  Core-shell silica microsphere-based trypsin nanoreactor for low molecular-weight proteome analysis.  ANALYTICA CHIMICA ACTA,      [PMID:28864190] [10.1016/j.aca.2017.07.012]

181. Fenglong Chen, Lingxin Meng, Jingmei Xu, Hongqi Liang, Kuirong Feng, Tian Lan, Jiayin Wang, Qingyuan Shi.  (2025)  Enhanced proton conductivity of sulfonated poly(aryl ether ketone sulfone) containing fluorene group by inserting bifunctionalized MOFs.  RENEWABLE ENERGY,      [PMID:] [10.1016/j.renene.2025.123046]

182. Zhang Yiyan, Zhao Tianyu, Deng Yuming, Liu Xinyue, Zhang Xiaorong, Zhu Tong, Ågren Hans, Chen Guanying.  (2025)  Near infrared sensitized exciton upconversion luminescence from inorganic perovskite nanocrystals.  Nature Communications,  16  (1): (1-9).  [PMID:40603851] [10.1038/s41467-025-61293-0]

183. Yang You, Ben Zheng, Xiang Xu, Huaqiang Zhang, Fuchong Li.  (2025)  Synthesis of a Novel Siloxane Crosslinker Containing Aromatic Rings and Its Effect on the Heat Resistance of Fluorosilicone Rubber.  POLYMERS FOR ADVANCED TECHNOLOGIES,  36  (10): (e70379).  [PMID:] [10.1002/pat.70379]

184. Yang Qihang, He Yuening, Wang Shuo, Li Zengting, Wang Jiaxuan, Sun Zehao, Yang Wenbo, Zhong Xiang, Peng Bo, Chen Zaozao, Gu Zhongze, Zhu Dan, Yu Tingting.  (2025)  Multidirectional interstitial flow promotes microvascular network formation: insights from a square chip-based platform.  ANGIOGENESIS,  29  (1): (1-20).  [PMID:41176522] [10.1007/s10456-025-10010-y]

185. Han Songyue, He Linhai, Chen Nan, Fan Dong, Tian Peng, Liu Zhongmin.  (2025)  CO2 hydrogenation to acetic acid and methyl acetate via tandem catalysis.  Nature Communications,      [PMID:41387674] [10.1038/s41467-025-66117-9]

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Application Protocols

Not applicable as validated assay protocols.

• No WB/IHC/IF/FC or similar bioassay protocols are provided for this chemical reagent. For practical usage, see Reaction Conditions and Reaction & Applications for representative chemistry workflows, and consult method-specific literature for GC derivatization procedures relevant to your analytes.

Biological Roles

Applicability

• Chlorotrimethylsilane is a synthetic organosilicon reagent with no known endogenous biological role. It is not a metabolite, cofactor, or signaling molecule.

Analytical/biochemical context (general)

• In bioanalytical chemistry, TMCS is widely used to derivatize polar biomolecules (e.g., organic acids, small carbohydrates, amino acids after suitable protection) to their trimethylsilyl derivatives to enable GC or GC-MS analysis. This improves volatility and reduces adsorption on active sites.
• TMCS often functions as an activator (with HMDS) to convert carboxylic acids to TMS esters; for amines, more specialized silylating agents (e.g., BSTFA with 1% TMCS) are common.

Cautionary notes

• Any contact with aqueous biological matrices leads to rapid hydrolysis and HCl release; derivatizations should be performed in anhydrous organic media after appropriate sample drying/extraction.
• No clinical or therapeutic claims are made or implied for this product; Research Use Only (as per Product Data).

Buffer Applications

Not typically applicable.

• TMCS is not used to prepare aqueous buffers due to rapid hydrolysis and acid generation. For experimental planning, focus on the Reaction & Applications and Solvent Selection sections for non-aqueous workflows.
• If a buffer-compatible derivatization is required, dry the analyte (e.g., lyophilization or azeotropic drying) before adding anhydrous organic solvent and TMCS-based systems.

Green Alternatives

Context

• TMCS is effective but moisture-reactive and corrosive (HCl release). Where feasible, consider less hazardous silylation systems or alternative analytical strategies.

Comparative options (general literature guidance)

• HMDS with catalytic acid (e.g., ammonium sulfate) for GC derivatization: generates fewer corrosive byproducts than TMCS-catalyzed systems, but may require higher temperatures/longer times.
• BSTFA/MSTFA (N-trimethylsilyl amides): Highly efficient silylating reagents producing volatile byproducts; can reduce need for strong acid scavengers. More expensive and still moisture sensitive.
• Derivatization-free GC methods: Employ on-column derivatization or use GC columns and conditions tailored for polar analytes; may trade sensitivity/peak shape.
• LC-MS alternatives: Avoid derivatization entirely by switching to LC-MS for polar/thermolabile analytes; greener in terms of reagent hazards but may increase solvent consumption.

Trade-offs (illustrative)

• Reactivity vs hazard: TMCS is fast and broad-scope but releases HCl; alternatives can be milder yet slower.
• Cost vs waste: TMCS is economical; some alternatives are pricier but generate more benign wastes.
• Substrate scope: TMCS/HMDS often excels for carboxylic acids and polyfunctional substrates; amide-based silylating reagents may outperform for sterically hindered alcohols.

Sustainability practices with TMCS

• Use microliter-scale additions via gas-tight syringes; keep headspace minimal.
• Neutralize acidic off-gas through scrubbers; segregate halogenated waste.
• Optimize derivatization to minimize excess reagent.

Pharmaceutical Uses

Formulation/excipient status

• TMCS is not an excipient and is unsuitable for direct inclusion in dosage forms.

Process/research roles (general, non-clinical)

• Employed as a silylating reagent in process development to transiently protect alcohols/phenols (TMS ethers) or to activate functional groups for subsequent transformations.
• Utilized in analytical QC labs to derivatize polar impurities or intermediates for GC-based limit tests.
• Can participate in halide exchange chemistry (e.g., in situ TMSI formation) relevant to intermediate synthesis.

Regulatory note

• Any pharmacopeial status, residual limits, or impurity thresholds for this specific item are Not specified for this item; refer to CoA/Spec Sheet and governing guidelines (e.g., ICH Q3A/Q3C) for process residual evaluations.

Good manufacturing practice considerations

• Ensure validated removal of TMCS and derived siloxanes; monitor residuals by GC with appropriate derivatization controls.
• Implement closed, inert handling systems with off-gas scrubbing to manage HCl emissions.

Physical Properties

Item-specific (from Product Data)

• Appearance: Not specified for this item; refer to CoA/Spec Sheet.

Literature/typical values (for reference; not product specifications)

• State: Colorless, fuming liquid (literature)
• Boiling point: ~57–58 °C at 1 atm (literature)
• Melting point: ~−40 °C (literature)
• Density: ~0.855–0.860 g/mL at 20–25 °C (literature)
• Refractive index: nD20 ≈ 1.385–1.387 (literature)
• Vapor pressure: High at ambient temperatures; readily volatilizes (literature)
• Solubility: Reacts with water; miscible with many anhydrous organic solvents (e.g., ethers, hydrocarbons, chlorinated solvents) (literature)
• LogP (estimated): Positive; dominated by three methyl groups (literature/computed)
• Hydrolytic sensitivity: Rapid; generates HCl and silanols that can condense to siloxanes (literature)

Notes for practitioners

• Handle and measure under rigorously anhydrous conditions—physical constants can drift in the presence of moisture due to rapid hydrolysis.
• For precision values applicable to a given lot (e.g., density used for molar calculations), consult the lot-specific CoA.

Quality and Grades

Item-specific (from Product Data)

• Grade/Purity designation: for GC derivatization

What “for GC derivatization” typically implies (general guidance)

• Optimized for forming trimethylsilyl (TMS) derivatives of polar analytes prior to gas chromatography, where reagent purity and low background are important for baseline stability and reproducibility.
• Emphasis is commonly placed on low levels of hydrolyzable impurities (water, alcohols), acidic/halide contaminants, and volatile residues that can contribute to ghost peaks. However, exact impurity limits for this item are Not specified for this item; refer to CoA/Spec Sheet.

Stabilizer/antioxidant

• Any stabilizers used and their levels are Not specified for this item; refer to CoA/Spec Sheet.

Recommended quality checks for critical applications (general)

• Run a reagent blank under the intended GC method to assess background.
• Titrate or Karl Fischer test for water content prior to derivatization workflows when sensitivity is critical.
• Verify derivatization performance using a standard panel (e.g., alcohol/acid/amine mix) to ensure conversion under your method conditions.

Reaction and Applications

Item-specific note

• Catalog designation “for GC derivatization” highlights its use to generate TMS derivatives that improve volatility/thermal stability for gas chromatography.

Representative applications (literature; non-exhaustive)

• GC Derivatization: Catalyst/activator with HMDS (hexamethyldisilazane) to silylate acids, alcohols, phenols, and amines; TMCS promotes formation of TMS esters/amides/ethers, enhancing GC detectability.
• Silyl Ether Formation: Converts alcohols/phenols to TMS ethers in the presence of base (e.g., Et3N, imidazole, pyridine). TMS ethers serve as transient protecting groups; readily cleaved by mild acid or fluoride.
• Silyl Enol Ether Generation: With strong bases (e.g., LDA) or Lewis acids, TMCS traps enolates to give TMS enol ethers, enabling Mukaiyama aldol and related reactions.
• Halide Exchange/Iodination: TMCS + NaI (or catalytic I−) forms TMSI in situ, converting alcohols/epoxides to iodides and effecting deprotections.
• Chlorination of Alcohols/Acids: TMCS with catalytic DMF or in combination with oxalyl chloride systems can facilitate conversion to chlorides or acid chlorides (substrate-dependent).
• Activation/Promoters: Enhances amide bond-forming chemistry in presence of base and nucleophilic catalysts (e.g., TMCS/NaI/NEt3 systems) and promotes acylation of weak nucleophiles by in situ silylation.

Practical tips

• Rigorously dry glassware/solvents; trace moisture quenches TMCS and generates HCl.
• Add TMCS last and slowly; provide adequate base or HCl scavenger when appropriate.
• Verify completeness of derivatization by monitoring disappearance of polar peaks (TLC, GC-MS) and/or emergence of characteristic TMS fragments (m/z 73) in GC-MS.

Reaction Conditions

General conditions (literature; adjust to substrate)

• Anhydrous environment: Oven-dried glassware; inert gas blanket; dry solvents (e.g., DCM, acetonitrile, toluene, THF).
• Temperature: Typically 0–25 °C for silylations; −78 to 0 °C when trapping enolates to form TMS enol ethers.
• Bases/catalysts: Et3N, pyridine, imidazole, DMAP for alcohol/phenol silylation. LDA or LiHMDS to generate enolates before quenching with TMCS. Iodide salts (NaI, TBAI) for in situ TMSI formation.
• Times: Minutes to 2 h for simple silylations; 0.5–3 h for GC derivatization with HMDS/TMCS depending on matrix and temperature.

Illustrative procedures

• Alcohol to TMS ether: ROH (1.0 eq), Et3N (1.2–2.0 eq), TMCS (1.1–1.5 eq) in dry DCM, 0–25 °C, 0.5–2 h; work up with aqueous bicarbonate then rapid separation to limit hydrolysis.
• Enolate trapping: Form enolate with LDA in THF at −78 °C, then add TMCS (1.2–1.5 eq); warm to 0 °C; isolate TMS enol ether.
• GC derivatization (acids): Analyte + HMDS (excess) + catalytic TMCS (1–10% v/v) in dry toluene, 60–120 °C as needed; vent carefully to manage HCl.

Monitoring & endpoints

• TLC/GC to confirm disappearance of starting polar substrate; GC-MS detection of m/z 73 and expected retention shift.

Safety overlay

• Add TMCS last; provide venting through acid gas trap. Quench residues cautiously with anhydrous alcohol before aqueous workup.

Safety and Handling

Item-specific (from Product Data)

• Storage conditions: Room temperature, Argon charged, Desiccated
• Shipment: FedEx DG Service
• GHS/Signal word/H-statements/Pictograms: Not specified for this item; refer to SDS.

General safety information (literature; always defer to SDS)

• Hazards: Moisture-sensitive silyl chloride; hydrolysis releases HCl gas and corrosive fumes. Causes severe skin/eye irritation or burns; harmful if inhaled. Reacts exothermically with water, alcohols, and bases.
• PPE: Use chemical-resistant gloves (e.g., butyl or Viton for chlorosilanes), splash goggles or face shield, lab coat; handle in a certified fume hood.
• Handling: Maintain under inert gas (argon or nitrogen). Use oven-dried glassware and anhydrous techniques. Avoid contact with moisture, acids, bases, and oxidizers. Add slowly to dry solvents/reaction mixtures.
• First aid (overview): Inhalation—move to fresh air; seek medical attention. Skin/Eye—immediate decontamination with copious water for at least 15 minutes; remove contaminated clothing; seek medical attention. Ingestion—not expected route; do not induce vomiting; seek medical attention.
• Spill/Quench: Small spills—absorb with dry, inert material; quench cautiously with anhydrous alcohol then aqueous base only after complete silyl chloride consumption. Prevent water entry until controlled quench.
• Storage notes: Keep tightly closed under dry inert gas with desiccant. Use a septum/seal to minimize air ingress after opening.

Solvent Selection

Applicability

• Chlorotrimethylsilane is primarily a reactive silylating agent rather than a bulk solvent. Solvent selection concerns focus on choosing an appropriate anhydrous medium for reactions or derivatizations.

General solvent compatibility (literature)

• Preferred dry solvents: Dichloromethane, toluene, hexanes/heptane, acetonitrile, ethyl acetate (anhydrous), and ethers such as THF or diethyl ether (well-dried). Avoid protic solvents.
• Incompatibilities: Water/alcohols (rapid hydrolysis); strong bases (can induce side reactions); amines (rapid HCl scavenging may form salts and reduce effective silylating power).
• Polarity: Nonpolar-to-moderately polar aprotic media are typically used. Ensure low basicity to avoid premature quench.

Selection tips (general)

• For GC derivatization with HMDS/TMCS systems, nonpolar solvents (e.g., toluene) minimize co-elution and stabilize analyte TMS derivatives.
• For generation of silyl enol ethers or in situ TMSI (from NaI + TMCS), acetonitrile or dichloromethane provides good solubility and control.
• For moisture exclusion, use molecular sieves (3Å or 4Å) and perform syringe/Schlenk transfers under inert gas.

Storage and Reconstitution

Item-specific (from Product Data)

• Storage conditions: Room temperature, Argon charged, Desiccated
• Shipped in: FedEx DG Service

General guidance for this reagent class

• Packaging: Store in airtight, moisture-tight containers (e.g., septum-capped bottles) under dry inert gas. Minimize headspace; consider Sure/Seal-type closures for repeated withdrawals.
• After opening: Maintain argon blanket; use dry needles/syringes. If possible, transfer to a dry, inert-atmosphere glovebox bottle for routine use.
• Stability: Sensitive to moisture; gradual formation of silanols/siloxanes and HCl upon trace water ingress. Avoid long-term storage with wet desiccants.
• Reconstitution: Not applicable—ready-to-use liquid reagent. Do not dilute with protic or wet solvents. Prepare any working solutions freshly in anhydrous, aprotic solvents immediately before use.
• Shelf life/Specifications: Not specified for this item; refer to CoA/Spec Sheet.

Waste and decontamination

• Quench small residues with anhydrous isopropanol or methanol under inert conditions, then neutralize and follow local regulations for halogenated/silicon-containing waste. Vent through an acid gas scrubber where applicable.

Structure and Identity

Item-specific (from Product Data)

• Product name: Chlorotrimethylsilane (TMCS)
• SKU: C131616
• CAS: 75-77-4
• PubChem CID: 6397
• InChIKey (as provided): 142672
• SMILES: Not specified for this item; refer to CoA/Spec Sheet.
• Grade: for GC derivatization

Literature/Computed identity (for reference only; not product specifications)

• Common synonyms: Trimethylsilyl chloride, TMSCl, TMCS
• Molecular formula (literature): C3H9ClSi
• Molecular weight (literature): 108.64 g/mol
• Canonical SMILES (literature): CSi(C)Cl
• InChIKey (literature): KXKVLQRXCPHEJC-UHFFFAOYSA-N
• Structural features: A tetra-coordinate silicon bearing three methyl groups and one chloride (silyl chloride). No rings, no stereocenters. The Si–Cl bond is highly polarized and moisture-sensitive, enabling silylation of nucleophilic heteroatoms (O, N, S).

2D structure description (general)

• Central Si atom bonded to three equivalent –CH3 substituents arranged trigonal pyramidal around Si, and one Si–Cl bond. The molecule is compact, non-aromatic, and hydrophobic aside from the reactive Si–Cl moiety.

Synthetic Utility

Functional group chemistry (literature)

• Electrophilic silyl chloride that transfers a trimethylsilyl group to nucleophiles (O, N, S, and C via enolates), forming TMS derivatives and liberating chloride or HCl.
• Converts enolates to TMS enol ethers—key intermediates for Mukaiyama aldol, Michael additions, and electrophilic substitutions.
• Forms TMS ethers from alcohols/phenols; serves as transient protecting groups that are rapidly installed and selectively removed.
• In situ generation of TMSI with iodide salts enables alcohol/epoxide iodination and selective deprotections.

Retrosynthetic value

• Strategic use of labile TMS protection allows chemoselective sequences where rapid deprotection is advantageous (e.g., orthogonal to TBDMS/TIPS protections).
• TMCS can activate carboxylic acids (via TMS esters) for subsequent conversion to acid chlorides or anhydrides.

Practical considerations

• Choose base and solvent to steer selectivity: imidazole or pyridine for alcohol silylation; hindered bases for minimizing acylation side reactions.
• Control temperature (0–25 °C) to moderate exotherm during additions. Use stoichiometric or slight excess TMCS to ensure completion, particularly in derivatization workflows.
• Analyze by GC-MS for the characteristic m/z 73 fragment (Si(CH3)3+) to confirm TMS incorporation.

Target Specificity

Not applicable.

• This product is a small-molecule chemical reagent, not a biological targeting agent. No antigen, epitope, clone, isotype, or species reactivity information applies.