Lithium methoxide - ≥99.9% metals basis , CAS No.865-34-9

CAS: 865-34-9 Cat. No.: L107391 Formula: CH₃OLi Peso molecolare: 37.97 Beilstein Registry Number: 3552389 Numero EC: 212-737-7

GRADE & PURITY ≥99.9% metals basis

Synonyms

Lithium methoxide|865-34-9|Lithium methanolate|lithium;methanolate|Methanol, lithium salt|Lithium methylate|MFCD00036357|Lithium methanolate; Lithium methylate; Methoxylithium|LIOME|liom|lithium methylat|Methanol, lithium salt (1:1)|EINECS 212-737-7|LiOCH

Storage

Room temperature,Argon charged,Desiccated

Shipped In

Normal

Panoramica

Employed in sol-gel synthesis of lithium borophosphates

Specifications

Sinonimi

Lithium methoxide | 865-34-9 | Lithium methanolate | lithium;methanolate | Methanol, lithium salt | Lithium methylate | MFCD00036357 | Lithium methanolate; Lithium methylate; Methoxylithium | LIOME | liom | lithium methylat | Methanol, lithium salt (1:1) | EINECS 212-737-7 | LiOCH

Specifiche e purezza

≥99.9% metals basis

Condizioni di conservazione di stoccaggio

Room temperature,Argon charged,Desiccated

Spedito in

Normal

Purezza

≥99.9% metals basis

Nomi e identificatori

• Pubchem Sid: 508815006
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/508815006
• Sorrisi canonici: [Li+].C[O-]
• IUPAC Name: lithium;methanolate
• InChIKey: JILPJDVXYVTZDQ-UHFFFAOYSA-N
• INCHI: 1S/CH3O.Li/c1-2;/h1H3;/q-1;+1
• Isomeri SMILES: [Li+].C[O-]
• WGK Germania: 3
• Numero UN: 3206
• Gruppo di imballaggio: II
• Peso molecolare: 37.97
• Beilstein: 3552389
• Reaxy-Rn: 3552389
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=3552389&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic salts
    • Classe Organic metal salts
      • Subclass Organic alkali metal salts

• Kingdom: Organic compounds
• Superclass: Organic salts
• Classe: Organic metal salts
• Subclass: Organic alkali metal salts
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic lithium salts
• Alternative Parents: Organic zwitterions Organic oxides Hydrocarbon derivatives Alkoxides
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Organic lithium salt - Organic oxygen compound - Organic oxide - Hydrocarbon derivative - Organic zwitterion - Alkoxide - Organooxygen compound - Aliphatic acyclic compound
• Descrizione: This compound belongs to the class of organic compounds known as organic lithium salts. These are organic compounds containing a lithium ion.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Proprietà chimiche e fisiche

• Sensibilità: Air & Moisture Sensitive
• Punto di infiammabilità (°F): 68 °F
• Punto di infiammabilità (°C): 20 °C
• Punto di fusione (°C): 204-206°C
• Peso molecolare: 38.000 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 38.0344 Da
• Monoisotopic Mass: 38.0344 Da
• Topological Polar Surface Area: 23.100 Ų
• Heavy Atom Count: 3
• Formal Charge: 0
• Complexity: 4.800
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

Riferimenti

1. Jing Gao, Jinghua Hao, Yuan Gao, Xiaolin Sun, Yuan Zhang, Depeng Song, Qing Zhao, Fuhua Zhao, Wenyan Si, Kun Wang, Takeo Ohsaka, Futoshi Matsumoto, Jianfei Wu, Haijiao Xie.  (2023)  Scalable wet-slurry fabrication of sheet-type electrodes for sulfide all-solid-state batteries and performance enhancement via optimization of Ni-rich cathode coating layer.  eTransportation,      [PMID:] [10.1016/j.etran.2023.100252]

2. Bo Liu, Meijie Cai, Xiangling Feng, Siyu Lu, Song Lin, Feng Tian.  (2023)  Enzyme-free carbon dots@MgO nanocomposite as an efficient sensor for on-site detection and degradation of paraoxon toxins.  CARBON,      [PMID:] [10.1016/j.carbon.2023.118003]

3. Lining Chen, Ping Xue, Qian Liang, Xuezhi Liu, Junyan Tang, Jing Li, Junjie Liu, Mi Tang, Zhengbang Wang.  (2022)  A Single-Ion Polymer Composite Electrolyte Via In Situ Polymerization of Electrolyte Monomers into a Porous MOF-Based Fibrous Membrane for Lithium Metal Batteries.  ACS Applied Energy Materials,      [PMID:] [10.1021/acsaem.2c00282]

4. Junjin Duan, Yi Gong, Dong Chen, Yuhong Ma, Changtong Song, Wantai Yang.  (2022)  Radical homopolymerization of vinyl ethers activated by Li+-π complexation in the presence of CH3OLi and LiI.  Polymer Chemistry,  13  (8): (1098-1106).  [PMID:] [10.1039/D1PY01619A]

5. Wen Liu, Xifei Li, Youchen Hao, Hirbod Maleki Kheimeh Sari, Jian Qin, Wei Xiao, Xiujuan Wang, Huijuan Yang, Wenbin Li, Liang Kou, Zhanyuan Tian, Le Shao, Cheng Zhang, Jiujun Zhang.  (2020)  Ionic Conductive Interface Boosting High Performance LiNi0.8Co0.1Mn0.1O2 for Lithium Ion Batteries.  ACS Applied Energy Materials,      [PMID:] [10.1021/acsaem.9b02008]

6. Dongxia Li, Lingli Liu, Xuan Song, Qiong Lin, Yuxin Xue, Xiangfeng Sun, Chongxian Luo, Xuefeng Gui, Kai Xu.  (2025)  Multilayer Separator-Driven interface stabilization and dendrite suppression for Long-Cycling lithium metal batteries.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:40245827] [10.1016/j.jcis.2025.137586]

7. Jiaying Tong, Dan Zhao, Jingwen Yao, Dong Chen, Junjin Duan, Yuhong Ma, Wantai Yang.  (2025)  Hexafluoroisopropanol-LiI Initiated Cationic Polymerization of Alkyl Vinyl Ethers.  JOURNAL OF POLYMER SCIENCE,  63  (8): (1947-1957).  [PMID:] [10.1002/pol.20250218]

8. Xinyu Yang, Demeng Liu, Siyu Pan, Delong Hou, Yao Jin, Zhonghui Wang, Yi Chen.  (2026)  Electrocatalytic synthesis of bio-based branched alkanes towards sustainable aviation fuel.  BIORESOURCE TECHNOLOGY,      [PMID:42492732] [10.1016/j.biortech.2026.135488]