Lithium phosphate monobasic - ≥99.9% metals basis, used for Precursors for LiMX2O7 (M = Fe, V; x = P, As) cathode materials. various applications , CAS No.13453-80-0

CAS: 13453-80-0 Cat. No.: L196237 Formula: LiH₂PO₄ Peso molecolare: 103.93 Numero EC: 236-633-6

GRADE & PURITY ≥99.9% metals basis

Synonyms

Lithium dihydrogen phosphate | Li H2 P O4 | Lithium phosphate (LiH2PO4) | Lithium phosphate monobasic | EINECS 236-633-6 | Lithiumdihydrogenphosphate | Monolithium phosphate | Phosphoric acid, lithium salt (1:1) | J-006555 | AKOS030228263 | lithium;dihydr

Storage

Room temperature,Desiccated

Shipped In

Normal

Panoramica

Lithium phosphate monobasic (LiH2PO4) supports high-power, high-capacity lithium-ion electrodes by fostering stable, phosphate-based interfaces that can enhance safety and durability helping extend cycle life and reduce reliance on more hazardous additives for more sustainable energy storage.

Specifications

Sinonimi

Lithium dihydrogen phosphate | Li H2 P O4 | Lithium phosphate (LiH2PO4) | Lithium phosphate monobasic | EINECS 236-633-6 | Lithiumdihydrogenphosphate | Monolithium phosphate | Phosphoric acid, lithium salt (1:1) | J-006555 | AKOS030228263 | lithium;dihydr

Specifiche e purezza

≥99.9% metals basis

Applicazione

Precursors for LiMX2O7 (M = Fe, V; x = P, As) cathode materials.

Condizioni di conservazione di stoccaggio

Room temperature,Desiccated

Spedito in

Normal

Purezza

≥99.9% metals basis

Nomi e identificatori

• Pubchem Sid: 504769564
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504769564
• Sorrisi canonici: [Li+].OP(=O)(O)[O-]
• IUPAC Name: lithium;dihydrogen phosphate
• InChIKey: SNKMVYBWZDHJHE-UHFFFAOYSA-M
• INCHI: 1S/Li.H3O4P/c;1-5(2,3)4/h;(H3,1,2,3,4)/q+1;/p-1
• Isomeri SMILES: [Li+].OP(=O)(O)[O-]
• Peso molecolare: 103.93
• Reaxy-Rn: 11461040
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=11461040&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Classe Alkali metal oxoanionic compounds
      • Subclass Alkali metal phosphates

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Classe: Alkali metal oxoanionic compounds
• Subclass: Alkali metal phosphates
• Intermediate Tree Nodes: Not available
• Direct Parent: Alkali metal phosphates
• Alternative Parents: Inorganic oxides Inorganic lithium salts
• Molecular Framework: Not available
• Substituents: Alkali metal phosphate - Inorganic lithium salt - Inorganic oxide - Inorganic salt
• Descrizione: This compound belongs to the class of inorganic compounds known as alkali metal phosphates. These are inorganic compounds in which the largest oxoanion is phosphate, and in which the heaviest atom not in an oxoanion is an alkali metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Proprietà chimiche e fisiche

• Punto di fusione (°C): >100℃
• Peso molecolare: 104.000 g/mol
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 103.985 Da
• Monoisotopic Mass: 103.985 Da
• Topological Polar Surface Area: 80.600 Ų
• Heavy Atom Count: 6
• Formal Charge: 0
• Complexity: 61.900
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

Riferimenti

1. Kai Xia, Rui Liang, Yi Luo, Anqiao Zheng, Guodong Jiang, Mingxia Fan, Jian Xiong, Songdong Yuan.  (2023)  Solid-State Preparation and Electrochemical Properties of Mg2+-doped LiFe0.7Mn0.3PO4/C as Cathode Material for Lithium-Ion Batteries.  International Journal of Electrochemical Science,      [PMID:] [10.20964/2022.12.72]

2. Tu Lan, Xiaolong Guo, De Li, Yong Chen.  (2021)  Preparation of LiFePO4 Powders by Ultrasonic Spray Drying Method and Their Memory Effect.  Materials,  14  (12): (3193).  [PMID:34200534] [10.3390/ma14123193]

3. Guodong Du, Yakun Xi, Xiaohui Tian, Yanbin Zhu, Yingke Zhou, Chengji Deng, Hongxi Zhu, Angulakshmi Natarajan.  (2019)  One-step hydrothermal synthesis of 3D porous microspherical LiFePO4/graphene aerogel composite for lithium-ion batteries.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2019.06.035]

4. Guodong Du, Yingke Zhou, Xiaohui Tian, Guan Wu, Yakun Xi, Shengyu Zhao.  (2018)  High-performance 3D directional porous LiFePO4/C materials synthesized by freeze casting.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2018.05.142]

5. Xiaofeng Tu, Yingke Zhou, Yijie Song.  (2016)  Freeze-drying synthesis of three-dimensional porous LiFePO4 modified with well-dispersed nitrogen-doped carbon nanotubes for high-performance lithium-ion batteries.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2016.12.220]

6. Han Xu, Jun Zong, Fei Ding, Zhi-wei Lu, Wei Li, Xing-jiang Liu.  (2016)  Effects of Fe2+ ion doping on LiMnPO4 nanomaterial for lithium ion batteries.  RSC Advances,  6  (32): (27164-27169).  [PMID:] [10.1039/C6RA02977A]

7. Jugong Zheng, Cancan Qin, Tongfu Wu, Shuangfei Xie, Liang Ni, Muyang Peng, Yuefeng Tang, Yanfeng Chen.  (2015)  High-performance LiMnPO4/C nanoplates synthesized by negative pressure immersion and a solid state reaction using nanoporous Mn2O3 precursors.  Journal of Materials Chemistry A,  3  (29): (15299-15306).  [PMID:] [10.1039/C5TA02431E]

8. Jugong Zheng, Liang Ni, Yanwen Lu, Cancan Qin, Panxing Liu, Tongfu Wu, Yuefeng Tang, Yanfeng Chen.  (2015)  High-performance, nanostructure LiMnPO4/C composites synthesized via one-step solid state reaction.  JOURNAL OF POWER SOURCES,      [PMID:] [10.1016/j.jpowsour.2015.02.048]

9. Xue Zhou, Ye Xie, Yuanfu Deng, Xusong Qin, Guohua Chen.  (2014)  The enhanced rate performance of LiFe0.5Mn0.5PO4/C cathode material via synergistic strategies of surfactant-assisted solid state method and carbon coating.  Journal of Materials Chemistry A,  3  (3): (996-1004).  [PMID:] [10.1039/C4TA05431H]

10. Xinglin Tang, Jiaqi Huang, Fangzhou Zhao, Yuqi Zhou, Yulin Xu, Ye Tao, Wanglai Cen, Yangjie Dai, Yongzhi Zhang.  (2025)  A 3D continuous mesoporous carbon framework enhances electronic/ionic kinetics of LiMn0.6Fe0.4PO4 cathode for high-performance lithium-ion batteries.  CARBON,      [PMID:] [10.1016/j.carbon.2025.120257]

11. Wei Lin, Yulu Wu, Xinyu Hu, Peng Yang, Hong Wen, Tianfu Zhao, Lianbang Wang, Chaoqi Shen.  (2025)  Achieving Fast Mn Redox Kinetics with Solvothermal Synthesized (010) Facet Preferential LiMn0.5Fe0.5PO4 Nanoplates for Li-Ion Batteries.  Advanced Sustainable Systems,      [PMID:] [10.1002/adsu.202400814]

12. Jinping Mu, Xiaohui Li, Rui He, Lijing Sun, Xue Bai, Lihui Zhang, Peng Liu, Zhenfa Liu, Jing Gao, Aijia Wei.  (2024)  Effect of lithium-containing inorganic phosphate additives in stabilization of carbonate-based electrolyte for 5 V LiNi0.5Mn1.5O4-based lithium-ion batteries.  Journal of Energy Storage,      [PMID:] [10.1016/j.est.2024.112538]

13. Qi You, Xuan Zhou, Chengxiang Yang, Mu Liu, Wei Liu, Jinkai Li, Xuchuan Jiang.  (2024)  Preparation and Luminescence Property Study of Red-Emitting Na3.6Y1.8(PO4)3:Eu3+,Li+/K+ Phosphors with Excellent Thermal Stability for Light-Conversion Application.  Nanomaterials,  14  (21): (1721).  [PMID:39513801] [10.3390/nano14211721]

14. Hui Zhuang, Jie Wang.  (2024)  Preparation of lithium ferromanganese phosphate by non-stoichiometric strategy.  International Journal of Electrochemical Science,      [PMID:] [10.1016/j.ijoes.2024.100636]

15. Yuqing Li, Weixing Xiong, Qunting Qu, Jie Shao, Ying Yan, Ru Wang, Linze Lv, Honghe Zheng.  (2025)  pH-Dependent Phosphates Conformal Coating Enabling 5.0 V Graphite Cathodes Over 10,000 Cycles via Reinforced Mechanical Strength and Optimized Interphase.  ADVANCED MATERIALS,      [PMID:41085066] [10.1002/adma.202513729]

16. Peng Xu, Haiwei Wu, Haiwen Li, Hanbin Liu, Zhijian Li.  (2025)  Synergistic effect of ball milling time and Mn-Fe ratio on the electrochemical performance of paper-based LiMn1-XFeXPO4/C cathodes for Lithium-ion batteries.  SOLID STATE IONICS,      [PMID:] [10.1016/j.ssi.2025.116898]

17. Fan Xiao, Lehan Zhu, Zhangjun Wu, Haotian Zhu, Juan Xia, Jiannan Zhu, Zeheng Yang, Weixin Zhang.  (2025)  Upcycling the Lithium Extraction By-products from Spent Lithium-ion Batteries into High-voltage Polyanionic LiMnxFe1-xPO4.  GREEN CHEMISTRY,      [PMID:] [10.1039/D5GC03642A]

18. Wenjing Chen, Rong Li, Fangxiang Song, Xiaozhi Chen, Qianlin Chen.  (2026)  Optimisation of LiFe1−xMnxPO4 cathode material via a defect engineering strategy controlled by lattice mismatch.  Journal of Energy Chemistry,      [PMID:] [10.1016/j.jechem.2026.02.021]

19. Jian Zhi, Yunfeng Luo, Chenyi Liao, Zhongyi Liu, Mei Han, Kaihang Yue, Lei Zhang, Guohui Li, P Chen.  (2026)  Methanesulfonate in Phosphate Electrolyte Superstructure Enables Ampere-Hour Practical Aqueous Batteries.  Research,      [PMID:41756720] [10.34133/research.1170]