MOPS - ≥99%(T) , CAS No.1132-61-2

CAS: 1132-61-2 Cat. No.: M105133 Molecular Weight: 209.26 Beilstein Registry Number: 1106776 EC Number: 214-478-5

GRADE & PURITY ≥99%(T)

Synonyms

4-Morpholinepropanesulfonic acid | BBL010801 | MOPS | NCGC00255922-01 | Q4030654 | 3-Morpholinopropane-1-sulfonic acid | 3-(morpholin-4-yl)propane-1-sulfonic acid (MOPS) | MFCD11100867 | MOPS, BioUltra, for molecular biology, >=99.5% (T) | MOPS, BioXtra,

Storage

Room temperature

Shipped In

Normal

Overview

useful pH range 6.5 - 7.9 pKa (25 °C) 7.2
Good's buffer component for biological research Satisfactory for electron transport studies and phosphorylation in chloroplast lamella preparations; non-toxic buffering system for the extensive growth of Streptomyces clavuligerus and cephalosporin production, in a chemically defined medium; electrolyte system component for the IEF of 2-D gel electrophoresis

Specifications

Synonyms

4-Morpholinepropanesulfonic acid | BBL010801 | MOPS | NCGC00255922-01 | Q4030654 | 3-Morpholinopropane-1-sulfonic acid | 3-(morpholin-4-yl)propane-1-sulfonic acid (MOPS) | MFCD11100867 | MOPS, BioUltra, for molecular biology, >=99.5% (T) | MOPS, BioXtra,

Specifications & Purity

≥99%(T)

Biochemical and Physiological Mechanisms

Multi purpose buffering agent used in biological research. Working pH range in aqueous solution: 6.5 - 7.9. Commonly used in cell culture media, as a running buffer for gel eletrophoresis, and within protein purification in chromatography.

Storage

Room temperature

Shipped In

Normal

Purity

≥99%(T)

Names and Identifiers

• Pubchem Sid: 488184600
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488184600
• Canonical Smiles: C1COCCN1CCCS(=O)(=O)O
• IUPAC Name: 3-morpholin-4-ylpropane-1-sulfonic acid
• InChIKey: DVLFYONBTKHTER-UHFFFAOYSA-N
• INCHI: 1S/C7H15NO4S/c9-13(10,11)7-1-2-8-3-5-12-6-4-8/h1-7H2,(H,9,10,11)
• Isomeric SMILES: C1COCCN1CCCS(=O)(=O)O
• WGK Germany: 1
• RTECS: QE9104530
• Molecular Weight: 209.26
• Beilstein: 1106776
• Reaxy-Rn: 1106776
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1106776&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organoheterocyclic compounds
    • Class Oxazinanes
      • Subclass Morpholines

• Kingdom: Organic compounds
• Superclass: Organoheterocyclic compounds
• Class: Oxazinanes
• Subclass: Morpholines
• Intermediate Tree Nodes: Not available
• Direct Parent: Morpholines
• Alternative Parents: Sulfonyls Organosulfonic acids Alkanesulfonic acids Trialkylamines Oxacyclic compounds Dialkyl ethers Azacyclic compounds Organopnictogen compounds Organic oxides Hydrocarbon derivatives
• Molecular Framework: Aliphatic heteromonocyclic compounds
• Substituents: Morpholine - Organic sulfonic acid or derivatives - Organosulfonic acid or derivatives - Organosulfonic acid - Sulfonyl - Alkanesulfonic acid - Tertiary amine - Tertiary aliphatic amine - Dialkyl ether - Ether - Oxacycle - Azacycle - Organopnictogen compound - Organic oxygen compound - Organosulfur compound - Organooxygen compound - Organonitrogen compound - Organic nitrogen compound - Organic oxide - Hydrocarbon derivative - Amine - Aliphatic heteromonocyclic compound
• Description: This compound belongs to the class of organic compounds known as morpholines. These are organic compounds containing a morpholine moiety, which consists of a six-member aliphatic saturated ring with the formula C4H9NO, where the oxygen and nitrogen atoms lie at positions 1 and 4, respectively.
• External Descriptors: an aliphatic sulfonate

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Solvent:water, Max Conc. mg/mL: 100, Max Conc. mM: 478
• Flash Point(°F): 116°C
• Flash Point(°C): 116°C
• Melt Point(°C): 277-282°C
• Molecular Weight: 209.270 g/mol
• XLogP3: -3.100
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 209.072 Da
• Monoisotopic Mass: 209.072 Da
• Topological Polar Surface Area: 75.200 Ų
• Heavy Atom Count: 13
• Formal Charge: 0
• Complexity: 227.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

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60. Lu He, Lin Yang, Hao Zhu, Wenkui Dong, Yujie Ding, Jun-Jie Zhu.  (2017)  A highly sensitive biosensing platform based on upconversion nanoparticles and graphene quantum dots for the detection of Ag+.  Methods and Applications in Fluorescence,  5  (2): (024010).  [PMID:28474602] [10.1088/2050-6120/aa6e0d]

61. Yaomin Yang, Xiaojuan Liu, Min Wu, Xiuzhong Wang, Ting Hou, Feng Li.  (2016)  Electrochemical biosensing strategy for highly sensitive pesticide assay based on mercury ion-mediated DNA conformational switch coupled with signal amplification by hybridization chain reaction.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2016.06.044]

62. Ruijuan Qu, Jiaoqin Liu, Liansheng Wang, Zunyao Wang.  (2016)  The toxic effect and bioaccumulation in aquatic oligochaete Limnodrilus hoffmeisteri after combined exposure to cadmium and perfluorooctane sulfonate at different pH values.  CHEMOSPHERE,      [PMID:27003372] [10.1016/j.chemosphere.2016.03.024]

63. Lingjun Meng, Shaogui Yang, Mingbao Feng, Ruijuan Qu, Yong Li, Jiaoqin Liu, Zunyao Wang, Cheng Sun.  (2015)  Toxicity and bioaccumulation of copper in Limnodrilus hoffmeisteri under different pH values: Impacts of perfluorooctane sulfonate.  JOURNAL OF HAZARDOUS MATERIALS,      [PMID:26686481] [10.1016/j.jhazmat.2015.11.048]

64. Qun He, Ruijuan Qu, Xinghao Wang, Zhongbo Wei, Ping Sun, Zunyao Wang.  (2015)  Toxicity of Arsenic to Photobacterium phosphoreum, Daphnia magna, and Danio rerio at Different pH Levels.  CLEAN-Soil Air Water,  44  (1): (72-77).  [PMID:] [10.1002/clen.201400124]

65. Wei Liu, Jiangnan Zheng, Shihua Li, Ruirui Wang, Zian Lin, Huanghao Yang.  (2015)  Aluminium glycinate functionalized silica nanoparticles for highly specific separation of phosphoproteins.  Journal of Materials Chemistry B,  3  (31): (6528-6535).  [PMID:32262560] [10.1039/C5TB01055A]

66. Jiangnan Zheng, Zian Lin, Guo Lin, Huanghao Yang, Lan Zhang.  (2015)  Preparation of magnetic metal–organic framework nanocomposites for highly specific separation of histidine-rich proteins.  Journal of Materials Chemistry B,  3  (10): (2185-2191).  [PMID:32262386] [10.1039/C4TB02007C]

67. Chao Wang, Zhongbo Wei, Mingbao Feng, Liansheng Wang, Zunyao Wang.  (2014)  The effects of hydroxylated multiwalled carbon nanotubes on the toxicity of nickel to Daphnia magna under different pH levels.  ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY,  33  (11): (2522-2528).  [PMID:25088764] [10.1002/etc.2704]

68. R.-J. Qu, X.-H. Wang, M.-B. Feng, Y. Li, H.-X. Liu, L.-S. Wang, Z.-Y. Wang.  (2013)  The toxicity of cadmium to three aquatic organisms (Photobacterium phosphoreum, Daphnia magna and Carassius auratus) under different pH levels.  ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY,      [PMID:23769002] [10.1016/j.ecoenv.2013.05.020]

69. Wang Shirong, Wei Zaiwa, Li Liangxian, Luo Yu, Huang Zhimei, Yang Xing, Tang Yafang.  (2024)  A label-free and rapid fluorometric strategy for microRNA detection using CRISPR-Cas12a coupled with copper nanoparticles.  MICROCHIMICA ACTA,  191  (7): (1-7).  [PMID:38896292] [10.1007/s00604-024-06496-w]

70. Yifeng Lan, Yingqi Ma, Yingwen Xu, Yuan Zhang, Rujia Deng, Lulu Liu, Boya Hou, Haiyan Cui, Keming Yun, Zhiwen Wei, Yanli Wei.  (2025)  A label-free fluorescent aptasensor for AFB1 and AFM1 based on the aptamer tailoring strategy and synergistic signal amplification of HCR and MoS2 nanosheets.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2025.137591]

71. Haolin Sun, Xiaoyu Zhang, Hainan Ma, Lina Zhang, Yang Zhang, Ruimeng Sun, Haoran Zheng, Han Wang, Jiayu Guo, Yanqi Liu, Yurou wang, Yanfei Qi.  (2024)  A programmable sensitive platform for pathogen detection based on CRISPR/Cas12a -hybridization chain reaction-poly T-Cu.  ANALYTICA CHIMICA ACTA,      [PMID:39030018] [10.1016/j.aca.2024.342888]

72. Tan Yan, Hu Jing, Tang Dongjin, Yu Peng.  (2025)  A simple fluorescent assay for thiocyanate based on Cu2+-triggered oxidation of o-phenylenediamine.  Journal of the Iranian Chemical Society,      [PMID:] [10.1007/s13738-025-03175-2]

73. Fangfang Wang, Yawen Liu, Wenping Liu, Huabing Yang, Haiming Hu, Zhigang Zhang, Songlin Liu, Junping Zheng, Hongtao Liu.  (2024)  A stable and specific hydrogel-based plasmonic nanosensor for histamine detection.  MICROCHEMICAL JOURNAL,      [PMID:] [10.1016/j.microc.2024.112047]

74. Zhang Xiaoyu, Sun Ruimeng, Zheng Haoran, Qi Yanfei.  (2025)  Amplification-free sensitive detection of Staphylococcus aureus by spherical nucleic acid triggered CRISPR/Cas12a and Poly T-Cu reporter.  MICROCHIMICA ACTA,  192  (2): (1-11).  [PMID:39806115] [10.1007/s00604-024-06931-y]

75. Xiaolu Wei, Guidan Ning, Huitong Ma, Yujiao Yin, Jianchun Ma, Liang Han, Danqi Chen, Zhongfeng Shi.  (2025)  Assessment of In Vitro Assays and Quantitative Determination of Selectivity and Modality of Inhibitors Targeting the Cell Cycle Regulating, Oncogenic Cyclin-Dependent Kinases.  ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS,      [PMID:39978616] [10.1016/j.abb.2025.110349]

76. Xiaozhuan Jia, Xiaohui Fan, Zhenzhong Yang.  (2024)  Carrier-free immobilized enzyme for ligand fishing of carbonic anhydrase inhibitors in Salvia miltiorrhiza.  TALANTA,      [PMID:39522281] [10.1016/j.talanta.2024.127160]

77. Jiangxiong Zhu, Hao Yin, Yang Wang, Lumei Wang, Xueqing Geng, Yun Deng.  (2024)  Conformational change-based fluorometric aptasensor for sensitive cadmium(II) detection in fruits and vegetables.  Analytical Methods,      [PMID:39143932] [10.1039/D4AY01333F]

78. Chengwei Li, Yanting Zhang, Yunsong Zheng, Chongwen Shi, Yuxi Lu, Yaoqiang Zhang, Songhu Yuan.  (2024)  Contaminant transformation during sediment oxygenation: Temporal variation of oxidation mechanisms mediated by hydroxyl radicals and aerobic microbes.  SCIENCE OF THE TOTAL ENVIRONMENT,      [PMID:38340822] [10.1016/j.scitotenv.2024.170855]

79. Fang Liu, Yongcheng Chen, Yue Huang, Qiao Jin.  (2024)  Copper-Polyphenol Nanocomplexes with Peroxidase-Like Activity for Enhanced Fungal Eradication.  ChemCatChem,      [PMID:] [10.1002/cctc.202401221]

80. Changyun Quan, Yue Zhang, Yuanyuan Liu, Liping Wen, Haixia Yang, Xueqin Huang, Minghui Yang, Binjie Xu.  (2024)  Electrochemical Glucose Sensor Based on Dual Redox Mediators.  Biosensors-Basel,  15  (1): (9).  [PMID:39852060] [10.3390/bios15010009]

81. Xin Wang, Shengyan Pu, Jiaqi Ding, Jing Chen, Peng Liao, Delai Zhong, Daniel C. W. Tsang, John C. Crittenden, Linling Wang.  (2024)  Enhanced Arsenate Immobilization by Kaolinite via Heterogeneous Pathways during Ferrous Iron Oxidation.  ENVIRONMENTAL SCIENCE & TECHNOLOGY,      [PMID:38934384] [10.1021/acs.est.4c01976]

82. Yikai Chen, Binggang Ye, Mengling Ning, Meng Li, Yixuan Pu, Zhiming Liu, Huiqing Zhong, Chaofan Hu, Zhouyi Guo.  (2024)  Food-borne bacteria analysis using a diatomite bioinspired SERS platform.  Journal of Materials Chemistry B,  12  (24): (5974-5981).  [PMID:38809058] [10.1039/D4TB00488D]

83. Meng-Fan Feng, Li-Miao Qin, Bo Sun, Xianghui Yu, Yuqing Wu.  (2024)  Harnessing HPV Virus-like Nanoparticles for Efficient Circular RNA Delivery.  ACS Applied Nano Materials,      [PMID:] [10.1021/acsanm.4c03770]

84. Wahid Ehtisham, Ocheja Ohiemi Benjamin, Oguntomi Sunday Olakunle, Pan Run, Grattieri Matteo, Guaragnella Nicoletta, Guaragnella Cataldo, Marsili Enrico.  (2025)  Immobilized Saccharomyces cerevisiae viable cells for electrochemical biosensing of Cu(II).  Scientific Reports,  15  (1): (1-11).  [PMID:39838043] [10.1038/s41598-025-86702-8]

85. Yongxia Yu, Keren Chen, Zaihui Du, Bing Fang, Jing Zhan, Longjiao Zhu, Wentao Xu.  (2024)  Magnetic aptamer copper nanoclusters fluorescent biosensor for the visual detection of zearalenone based on docking-aided rational tailoring.  FOOD CHEMISTRY,      [PMID:38608399] [10.1016/j.foodchem.2024.139127]

86. Pingping Fan, Kui Li, Tian Li, Panke Zhang, Shuo Huang.  (2024)  Nanopore signatures of major alcoholic beverages.  Matter,      [PMID:] [10.1016/j.matt.2024.11.025]

87. Bojia Li, Hongyu Liang, Yueqi Hu, Xinyue Zhou, Peiyu Yang, Xiaojuan Chen, Hongshan Liang, Can Wu, Bin Zhou.  (2024)  Tannic acid coordination assembly enhances the interfacial properties of salted egg white gel particles.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:39732233] [10.1016/j.ijbiomac.2024.139181]

88. Cui Gan, Zhaobo Luo, Chengyuan Su, Caixi Hu, Lei Tong, Jianbo Shi.  (2024)  Temperature-dependent co-transport behavior of goethite, Fe2+, and antibiotic in the hyporheic zone.  JOURNAL OF HYDROLOGY,      [PMID:] [10.1016/j.jhydrol.2024.132487]

89. Zezhou Zhao, Wei Lou, Delai Zhong, Yao Shi, Fengjiao Zhang, Linling Wang, Xiaohui Wu, Anxu Sheng, Jing Chen.  (2024)  Time-varying contributions of FeII and FeIII to AsV immobilization under anoxic/oxic conditions: The impacts of biochar and dissolved organic carbon.  SCIENCE OF THE TOTAL ENVIRONMENT,      [PMID:39098410] [10.1016/j.scitotenv.2024.175241]

90. Xiaocui Lai, Wenkai Cao, Ganggang Zhang, Edison Huixiang Ang, Liu Su, Cong Liu, Weihua He, Weihua Lai, Shengliang Deng.  (2024)  Traffic signal-inspired fluorescence lateral flow immunoassay utilizing self-assembled AIENP@Ni/EC for simultaneous multi-pesticide residue detection.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.157565]

91. Ying Liu, Miao Wang, Guang-Xiong Zhou.  (2025)  Activity of 6-methoxydihydrosanguinarine from Hylomecon japonica against wild-type and fluconazole-resistant Candida albicans biofilms.  JOURNAL OF ASIAN NATURAL PRODUCTS RESEARCH,      [PMID:40720099] [10.1080/10286020.2025.2532041]

92. Jie Cao, Jin Huang, Huaping Dong, Jianfa Li, Jianxin Shou, Yimin Li.  (2019)  Effects of surfactants on the removal of nitrobenzene by Fe(II) sorbed on goethite.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:31176923] [10.1016/j.jcis.2019.05.095]

93. Lai Shanshan, Guo Jiahong, Li Xin, Yu Xiaoxiao, Lai Guosong.  (2025)  Dual DNA recycling amplification-assisted CRISPR/Cas12a cleavage for dual-channel ratiometric fluorescence biosensing of kanamycin antibiotic.  ANALYTICAL AND BIOANALYTICAL CHEMISTRY,      [PMID:40183844] [10.1007/s00216-025-05858-4]

94. Liyang Wang, Junying He, Hanzhong Feng, Qian Li, Meirong Song, Haoran Gou, Yongxing He, Kui Zhu.  (2025)  Antifungal Effects of the Phloroglucinol Derivative DPPG Against Pathogenic Aspergillus fumigatus.  Antibiotics-Basel,  14  (5): (499).  [PMID:40426565] [10.3390/antibiotics14050499]

95. Xinna Hu, Tao Ma, Haibo Pan, Shiguo Chen, Donghong Liu.  (2025)  Direct assembly of tannic acid-based metal-phenolic networks at the oil-water Interface for emulsion stabilization.  FOOD RESEARCH INTERNATIONAL,      [PMID:40467213] [10.1016/j.foodres.2025.116625]

96. Yin Yun-Dong, Zhang Yu-Wei, Song Xi-Tong, Hu Jun, Chen Yu-Heng, Lai Wen-Chuan, Li Ya-Fei, Gu Zhi-Yuan.  (2025)  Native globular ferritin nanopore sensor.  Nature Communications,  16  (1): (1-12).  [PMID:40481000] [10.1038/s41467-025-60322-2]

97. Yifeng Lan, Rujia Deng, Yuan Zhang, Yingwen Xu, Yingqi Ma, Lulu Liu, Qi Wang, Rui Gao, Keming Yun, Jieping Lv, Zhiwen Wei.  (2025)  Truncated aptamer-based fluorescent logic gate detection platform and systems toxicology study for Methamphetamine/Amphetamine.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2025.139195]

98. Kang Shaoyang, Ding Sheng, Lyu Donghao, Gao Rui, Peng Sirui, Liu Jing, Zhang Chuangnian, Feng Zujian, Huang Pingsheng, Kong Deling, Wang Weiwei.  (2025)  A Microgel-Stabilized, Light-Controlled Artificial Energy Supply Module for Efficient Biosynthesis.  Regenerative Biomaterials,      [PMID:41669165] [10.1093/rb/rbaf106]

99. Hongling Bu, Hanjie Chen, Chengshuai Liu, Hui Tong, Yanfu Wei, Meiqing Chen, Ziming Xu, Jianbo Chen, Peng Yuan.  (2025)  Clay Mineral Structure Dictates Arsenic(III) Oxidative Fate: Mechanistic Insights from Contrasting 1:1 and 2:1 Phyllosilicates.  JOURNAL OF HAZARDOUS MATERIALS,      [PMID:41349308] [10.1016/j.jhazmat.2025.140665]

100. Huang Junyun, Liu Boying, Yuan Sijia, Zhou Haiyun, Bao Jian, Tu Yong, Wang Zunyao, Wang Weixia.  (2025)  The pH-Dependent Toxic Effects of Benzophenone-3 on Aquatic Organisms.  BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY,  116  (1): (9).  [PMID:41400706] [10.1007/s00128-025-04167-x]

101. Yunqi Xiao, Shanyu Zhang, Xinmeng Gao, Tian Li, Hanhan Zhang, Panke Zhang, Shuo Huang.  (2026)  Nanopore profiling and structure determination of oligosaccharides by fragmentation.  Science Advances,  12  (1):   [PMID:41477834] [10.1126/sciadv.aea8462]

102. Xiong Liu, Guangxia Feng, Yuan Ping, Zhiping Zhang, Li Kong.  (2026)  Inhaled engineered apoptotic neutrophil-derived nanovesicles enhance macrophage efferocytosis for attenuating lung inflammation.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2026.173072]

103. Bowen Sun, Ying Wang, Jaslyn Ru Ting Chen, Manli Guo, Emily Xi Tan, Lam Bang Thanh Nguyen, Wanzong Wang, Hao Feng, In Yee Phang, Yan Lv, Jianhua Li, Xing Yi Ling, Qi-Zhi Zhong.  (2026)  Surface engineering of SERS nanocomposites via metal–phenolic networks for stable sensing.  COMPOSITES COMMUNICATIONS,      [PMID:] [10.1016/j.coco.2026.102753]

104. Yahui Xie, Yun Liu, Haibo Zhao, Xuemin Kang, Haiteng Tao, Bin Yu, Bo Cui.  (2026)  Gelatin/starch hydrogel tissue adhesive loaded with EGCG-Zr complex with antibacterial, antioxidant, and immunomodulatory properties for advanced wound healing.  Biomaterials Advances,      [PMID:41690128] [10.1016/j.bioadv.2026.214769]

105. Jingwen Xu, Xu Hu, Zongyan Li, Junhan Li, Zhida Gao, Zhi-Yong Wu, Yan-Yan Song.  (2026)  Development of a Paper-Based SERS Platform for On-Site Separation and Detection of Mercury Species in Aqueous Environments.  ANALYTICAL CHEMISTRY,      [PMID:41666277] [10.1021/acs.analchem.5c06628]

106. Wanlei Ren, Junqi Zhao, Xujuan Lv, Sha Qiu, Yujia Ren, Xuxin Yan, Shuai Qin, Daoqing Fan, Juan Wang, Xueji Zhang.  (2026)  Colorimetric sensor arrays for the analysis of active ingredients in licorice based on the efficient catalysis of oxidase-like manganese-nanozymes.  TALANTA,      [PMID:] [10.1016/j.talanta.2026.129570]