Palladium(II) chloride (PdCl2) reacts with unsubstituted or alkyl-substituted cyclic ketones in the CO atmosphere to afford acyclic diesters and acyclic chloro-substituted monoesters. PdCl2 reacts with N,N-dimethylallylamine in methanol to afford di-μ-chloro-bis(2-methoxy-3-N,N-dimethylaminopropyl)dipalladium(II). Palladium dichloride, acetate and acetylacetonate in the [bmim][BF4] or [bmim][PF6] (where[bmim]+ = 1-butyl-3-methylimidazolium cation) ionic liquids have been employed for the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.
Palladium catalysts and precursor used as an oxidizing agent and as a source of Pd(0) complexes. Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1
Product class
PGM Solids, Chlorides
Reaction type
Cross Coupling Reactions with Arenes, CH-Activation, Carbonylation, Mizoroki Heck Coupling Reaction, Oxidation
Chemical properties
Theoretical metal content
Applications & references
Efficient oxidative carboxylation of benzylic C-H bonds via nondirected C(sp³)-H activation forming substituted 2-phenylacetic acid esters and derivatives starting from inexpensive, commercially available starting materials.
Reference: J. Am. Chem. Soc. 2012, 134, 9902 (DOI: 10.1021/ja3036459)
Efficient Palladium catalyzed hydroformylation of aryl and enol trifluoromethanesulfonates providing α,β-unsaturated aldehydes.
Reference: Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246)
Palladium catalyzed intermolecular decarboxylative coupling in the presence of reactive C-H groups.
Reference: J. Org. Chem. 2010, 75, 1550. (DOI: 10.1021/jo9022793)
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