3-Chloroperoxybenzoic acid(MCPBA) - ≥85% , CAS No.937-14-4

CAS: 937-14-4 Cat. No.: C106492 Molecular Weight: 172.57 Beilstein Registry Number: 608317 EC Number: 213-322-3

GRADE & PURITY ≥85%

Synonyms

M-Chloroperoxybenzoic acid | 3-Chloroperbenzoic acid | MCPBA | BRN 0608317 | NSC 97094 | UNII-G203D4H1RB | CCRIS 639 | NSC-97094 | MFCD00002127 | CHEBI:52091 | G203D4H1RB

Storage

Store at 2-8°C

Shipped In

Wet ice,FedEx DG Service

Overview

3-Chloroperbenzoic acid is a strong oxidizing agent mainly used for the epoxidation of alkenes and also in the Baeyer-Villiger oxidation of ketones to esters.

Specifications

Synonyms

M-Chloroperoxybenzoic acid | 3-Chloroperbenzoic acid | MCPBA | BRN 0608317 | NSC 97094 | UNII-G203D4H1RB | CCRIS 639 | NSC-97094 | MFCD00002127 | CHEBI:52091 | G203D4H1RB

Specifications & Purity

≥85%

Storage

Store at 2-8°C

Shipped In

Wet ice, FedEx DG Service

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥85%

Names and Identifiers

• Canonical Smiles: C1=CC(=CC(=C1)Cl)C(=O)OO
• IUPAC Name: 3-chlorobenzenecarboperoxoic acid
• InChIKey: NHQDETIJWKXCTC-UHFFFAOYSA-N
• INCHI: 1S/C7H5ClO3/c8-6-3-1-2-5(4-6)7(9)11-10/h1-4,10H
• Isomeric SMILES: C1=CC(=CC(=C1)Cl)C(=O)OO
• WGK Germany: 3
• UN Number: 3106
• Molecular Weight: 172.57
• Beilstein: 608317
• Reaxy-Rn: 608317
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=608317&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Class Benzene and substituted derivatives
      • Subclass Benzoic acids and derivatives
        • Level5 Halobenzoic acids and derivatives
          • Level6 3-halobenzoic acids and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Class: Benzene and substituted derivatives
• Subclass: Benzoic acids and derivatives
• Intermediate Tree Nodes: Halobenzoic acids and derivatives
• Direct Parent: 3-halobenzoic acids and derivatives
• Alternative Parents: Peroxybenzoic acids and derivatives Benzoyl derivatives Chlorobenzenes Aryl chlorides Peroxycarboxylic acids Organic hydroperoxides Carboxylic acid salts Peroxols Monocarboxylic acids and derivatives Organochlorides Organic salts Organic oxides Hydrocarbon derivatives
• Molecular Framework: Aromatic homomonocyclic compounds
• Substituents: 3-halobenzoic acid or derivatives - Peroxybenzoate - Benzoyl - Chlorobenzene - Halobenzene - Aryl chloride - Aryl halide - Peroxycarboxylic acid or derivatives - Peroxycarboxylic acid - Carboxylic acid salt - Hydroperoxide - Monocarboxylic acid or derivatives - Peroxol - Carboxylic acid derivative - Organic oxygen compound - Organohalogen compound - Organic salt - Hydrocarbon derivative - Organic oxide - Organochloride - Organooxygen compound - Aromatic homomonocyclic compound
• Description: This compound belongs to the class of organic compounds known as 3-halobenzoic acids and derivatives. These are benzoic acids or derivatives carrying a halogen atom at the 3-position of the benzene ring.
• External Descriptors: monochlorobenzenes - peroxy acid

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Mechanisms of Action

Chemical and Physical Properties

• Sensitivity: Heat sensitive
• Melt Point(°C): 69-71°C
• Molecular Weight: 172.560 g/mol
• XLogP3: 2.400
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 171.993 Da
• Monoisotopic Mass: 171.993 Da
• Topological Polar Surface Area: 46.500 Ų
• Heavy Atom Count: 11
• Formal Charge: 0
• Complexity: 149.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

References

1. Weiping Xu, Guochen Wang, Dong Chen, Wantai Yang, Yuhong Ma.  (2023)  Synchronously Improving Mechanical and Thermal Performances of Cured Epoxy Resins by Epoxidized Polyether Sulphones as Modifiers.  MACROMOLECULAR CHEMISTRY AND PHYSICS,      [PMID:] [10.1002/macp.202300351]

2. Yongxing Guo, Jinghua Zhao, Limin Wu, Wei Liu, Yi Li, Yonggang Yang.  (2023)  Control the structure of the polyacrylate/epoxy resin film through photopolymerisation.  LIQUID CRYSTALS,      [PMID:] [10.1080/02678292.2023.2290291]

3. Huahai Yu, Ying Piao, Yifan Zhang, Jiajia Xiang, Shiqun Shao, Jianbin Tang, Zhuxian Zhou, Youqing Shen.  (2023)  Cell-Selective Binding Zwitterionic Polymeric Micelles Boost the Delivery Efficiency of Antibiotics.  ACS Nano,      [PMID:37933869] [10.1021/acsnano.3c05181]

4. Lei Chen, Zekun Li, Yufeng Ma, Qianqian Shang, Yun Hu, Qin Huang, Meng Zhang, Puyou Jia, Yonghong Zhou.  (2023)  Tung Oil-Based Degradable Vitrimer for Reprocessable and Recyclable Vitrimer–MWCNT Composites with Self-Healing Ability Triggered by Multiple Stimuli.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.3c01681]

5. Meiying Ge, Guozheng Liang, Aijuan Gu.  (2023)  Structural design strategy of biobased propargyl ether-functionalized epoxy monomer to access low viscosity resin with excellent heat resistance and mechanical properties for advanced composite via VARTM.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2023.146269]

6. Xing Liu, Zhenhong Xiao, Xianyong Liu, Yuling Liu, Jianqing Zhao, Shumei Liu.  (2023)  Design and synthesis of epoxy prepolymer containing aromatic imide structures for thermoset with excellent thermal, mechanical and dielectric properties.  CHEMICAL ENGINEERING SCIENCE,      [PMID:] [10.1016/j.ces.2023.119149]

7. Jingjing Fan, Wei Liu, Lieshun Cai, Taoshan Jiang, Zhongkai Wang.  (2023)  Castor oil-based multi-functional monomers and their application in polyamide design.  INDUSTRIAL CROPS AND PRODUCTS,      [PMID:] [10.1016/j.indcrop.2023.117188]

8. Cijian Zhang, Shicong Song, Qi Cao, Jiahui Li, Qian Liu, Shouhai Zhang, Xigao Jian, Zhihuan Weng.  (2023)  Improving the comprehensive properties of chitosan-based thermal insulation aerogels by introducing a biobased epoxy thermoset to form an anisotropic honeycomb-layered structure.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:37391003] [10.1016/j.ijbiomac.2023.125616]

9. Yongxing Guo, Jinghua Zhao, Yi Li, Wei Liu, Yonggang Yang.  (2023)  Preparation and applications of the epoxy resin-based polymer- stabilised cholesteric liquid crystal films with microcracks at the surface.  LIQUID CRYSTALS,      [PMID:] [10.1080/02678292.2023.2227949]

10. Jiahui Li, Haiyang Zhao, Qi Cao, Wenguang Zeng, Jiangjiang Zhang, Yujie Guo, Yi Zhao, Xigao Jian, Zhihuan Weng.  (2023)  Synthesis of Cyano-Containing Epoxy Precursor from Vanillin for Engineering Multifaceted Performance-Enhancing Resins.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.2c06678]

11. Hongwei Gu, Qi Cao, Jiahui Li, Jing Zhao, Shouhai Zhang, Xigao Jian, Zhihuan Weng.  (2023)  Enhancing the comprehensive performance of bisphenol A epoxy resin via blending with a bio-based counterpart.  POLYMER,      [PMID:] [10.1016/j.polymer.2023.126038]

12. Sijia Ren, Jiachun Feng.  (2023)  Reconfigurable and Reprocessable Thermadapt Stress-Free Two-Way Shape Memory Polymers Based on a Dual Crosslinking Network with Outstanding Mechanical Properties.  Advanced Materials Technologies,  8  (14): (2300029).  [PMID:] [10.1002/admt.202300029]

13. Wei Chunxiang, Gao Tianyu, Xu Yu, Yang Wenjie, Dai Guangjian, Li Ruiting, Zhu San E., Yuen Richard K. K., Yang Wei, Lu Hongdian.  (2023)  Synthesis of Bio-based Epoxy Containing Phosphine Oxide as a Reactive Additive Toward Highly Toughened and Fire-retarded Epoxy Resins.  CHINESE JOURNAL OF POLYMER SCIENCE,  41  (11): (1733-1746).  [PMID:] [10.1007/s10118-023-2932-4]

14. Jianliang Jiang, Jingbo Shen, Xiao Yang, Dongqi Zhao, Yakai Feng.  (2023)  Epoxy-Functionalized POSS and Glass Fiber for Improving Thermal and Mechanical Properties of Epoxy Resins.  Applied Sciences-Basel,  13  (4): (2461).  [PMID:] [10.3390/app13042461]

15. Min Li, Fei Xing, Tianshu Li, Shaokai Wang, Yizhuo Gu, Wei Zhang, Yanjie Wang, Qinghui Li.  (2023)  Multiscale interfacial enhancement of surface grown carbon nanotubes carbon fiber composites.  POLYMER COMPOSITES,  44  (5): (2766-2777).  [PMID:] [10.1002/pc.27278]

16. Zhiqiang Feng, Xiaohong Liu, Jiaming Liu, Xi Chen, Bifang Chen, Liyan Liang.  (2023)  Liquid crystal epoxy composites based on functionalized boron nitride: Synthesis and thermal properties.  POLYMER ENGINEERING AND SCIENCE,  63  (3): (932-942).  [PMID:] [10.1002/pen.26255]

17. Yuhong Huang, Xiaowei Li, Linlin Chen, Guiling Luo, Duanjian Tao, Jing Sun, Zhenjiang Qiu, Yanhong Chao, Wenshuai Zhu.  (2022)  Synthesis of a magnetic crown ether ion imprinted polymer material for the selective adsorption of lithium.  NEW JOURNAL OF CHEMISTRY,  47  (6): (3134-3139).  [PMID:] [10.1039/D2NJ05377B]

18. Xiaoli Zhang, Yongxing Guo, Yi Li, Wei Liu, Hongkun Li, Yonggang Yang.  (2022)  Colorfully Patterned Epoxy Resin Films with a Cholesteric Structure Prepared through a Photopolymerization Approach.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.2c01432]

19. Wei Liu, Mei Wu, Chuqing Ma, Cheng Liu, Xiaoying Zhang, Zhong Wang, Zhongkai Wang.  (2022)  Efficient Miniemulsion Polymerization of Plant Oil-Based Acrylate Monomer toward Waterborne Epoxy Resins.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.2c02403]

20. Bao Chunyang, Chen Jing, Wang Yan, Yang Tao, Xu Xiaoling, Zhang Qiang.  (2022)  Cellulose-based functional polycarbonates as degradable enzyme carriers.  CELLULOSE,  29  (16): (8769-8780).  [PMID:] [10.1007/s10570-022-04810-4]

21. Jinbao Xu, Weiguo Liang, Jie Zhang, Zhixian Dong, Caihong Lei.  (2022)  Synthesis of side-chain functional Poly(ε-caprolactone) via the versatile and robust organo-promoted esterification reaction.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2022.111526]

22. Yangyang Xiao, Haibo Tan, Haitao Huang, Jizhong Yu, Lanting Zeng, Yinyin Liao, Ping Wu, Ziyin Yang.  (2022)  Light synergistically promotes the tea green leafhopper infestation-induced accumulation of linalool oxides and their glucosides in tea (Camellia sinensis).  FOOD CHEMISTRY,      [PMID:35716497] [10.1016/j.foodchem.2022.133460]

23. Chao Ma, Zhenghong Guo, Zhengping Fang, Juan Li.  (2022)  Flame retardancy and chemical degradation of epoxy containing phenylphosphonate group under mild conditions.  COMPOSITES PART B-ENGINEERING,      [PMID:] [10.1016/j.compositesb.2022.109967]

24. Su Qiuping, Tang Zilun, He Jiajian, Gu Yuxin, Li Yong, Xie Jing, Wang Shaoshun, Lin Ruijun, Lin Xiaofeng, Lin Wenjing, Yi Guobin.  (2022)  Synthesis of a curing agent containing trifunctional epoxy groups for powder coatings and its curing reaction kinetics.  Journal of Coatings Technology and Research,  19  (3): (907-917).  [PMID:] [10.1007/s11998-021-00578-7]

25. Feng Zhiqiang, Liu Xiaohong, Zhang Wenchao, Zeng Juanjuan, Liu Jiaming, Chen Bifang, Lin Jiaming, Tan Liqin, Liang Liyan.  (2022)  Functionalized mesoporous silica liquid crystal epoxy resin composite: an ideal low-dielectric hydrophobic material.  JOURNAL OF MATERIALS SCIENCE,  57  (2): (1156-1173).  [PMID:] [10.1007/s10853-021-06672-w]

26. Di Ma, Qingyu Zong, Yuchen Du, Fangzhou Yu, Xuan Xiao, Rong Sun, Yuan Guo, Xinhua Wei, Youyong Yuan.  (2021)  Sequential enzyme-activated macrotheranostic probe for selective tumor mitochondria targeting.  Acta Biomaterialia,      [PMID:34371167] [10.1016/j.actbio.2021.08.002]

27. Yudi Feng, Ke Jin, Jia Guo, Changchun Wang.  (2021)  All-carbocycle hydrocarbon thermosets with high thermal stability and robust mechanical strength for low-k interlayer dielectrics.  Polymer Chemistry,  12  (33): (4812-4821).  [PMID:] [10.1039/D1PY00877C]

28. Chao Ma, Lijun Qian, Juan Li.  (2021)  Effect of functional groups of magnolol-based cyclic phosphonate on structure and properties of flame retardant epoxy resin.  POLYMER DEGRADATION AND STABILITY,      [PMID:] [10.1016/j.polymdegradstab.2021.109630]

29. Yanzi Ke, Xiangyu Yang, Qian Chen, Junqi Xue, Zhijian Song, Yuehong Zhang, Samy A. Madbouly, Ying Luo, Mei Li, Qingwen Wang, Chaoqun Zhang.  (2021)  Recyclable and Fluorescent Epoxy Polymer Networks from Cardanol Via Solvent-Free Epoxy-Thiol Chemistry.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.1c00284]

30. Xu Zhang, Guangping Sun, Heng Liu, Xuequan Zhang.  (2021)  Fabrication of porous polymer coating layers with selective wettability on filter papers via the breath figure method and their applications in oil/water separation.  RSC Advances,  11  (24): (14276-14284).  [PMID:35423976] [10.1039/D1RA01080H]

31. Xin Wang, Haoxin Niu, Wenwen Guo, Lei Song, Yuan Hu.  (2021)  Cardanol as a versatile platform for fabrication of bio-based flame-retardant epoxy thermosets as DGEBA substitutes.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2021.129738]

32. Wenwen Guo, Xin Wang, Jiali Huang, Wei Cai, Lei Song, Yuan Hu.  (2021)  Intrinsically anti-flammable and self-toughened phosphorylated cardanol-derived novolac epoxy thermosets.  INDUSTRIAL CROPS AND PRODUCTS,      [PMID:] [10.1016/j.indcrop.2021.113496]

33. Yu Qi, Zhihuan Weng, Yan Kou, Jiahui Li, Qi Cao, Jinyan Wang, Shouhai Zhang, Xigao Jian.  (2021)  Facile synthesis of bio-based tetra-functional epoxy resin and its potential application as high-performance composite resin matrix.  COMPOSITES PART B-ENGINEERING,      [PMID:] [10.1016/j.compositesb.2021.108749]

34. Jiali Huang, Wenwen Guo, Xin Wang, Lei Song, Yuan Hu.  (2021)  Intrinsically flame retardant cardanol-based epoxy monomer for high-performance thermosets.  POLYMER DEGRADATION AND STABILITY,      [PMID:] [10.1016/j.polymdegradstab.2021.109519]

35. Gui-Nan Shen, Jing Li, Ying-Hua Jin, Hu-Nan Sun, Ying-Ying Hao, Mei-Hua Jin, Ren Liu, Wei-Long Li, Yong-Qing Zhang, Jia-Bin Yu, Nan-Nan Yu, Wei-Dong Wang, Li-Yun Yu, Ji-Su Kim, Taeho Kwon, Ying-Hao Han.  (2020)  The compound 2‑benzylthio‑5,8‑dimethoxynaphthalene‑1,4‑dione leads to apoptotic cell death by increasing the cellular reactive oxygen species levels in Ras‑mutated liver cancer cells.  Experimental and Therapeutic Medicine,  20  (5): (1-1).  [PMID:32968439] [10.3892/etm.2020.9209]

36. Guanyi Hou, Xinlei Zhou, Sai Li, Ruifeng Jiang, Zhiyu Zhang, Mengjie Dong, Jun Liu, Yonglai Lu, Wencai Wang, Liqun Zhang, Shihu Wang.  (2020)  Exploiting Synergistic Experimental and Computational Approaches to Design and Fabricate High-Performance Elastomer.  MACROMOLECULES,      [PMID:] [10.1021/acs.macromol.0c01285]

37. Lili Wang, Panpan Hao, Xiaomeng Chu, Yujuan Sun, Xuteng Xing, Shaojie Liu, Erjun Tang, Xiaodong Xu.  (2020)  Dual-functionalized block copolymer brush grafted on micron-sized polystyrene microsphere as recoverable sulfonic acid catalyst and nitroxide radical inhibitor for synthesis of MPEGMA.  Materials Today Communications,      [PMID:] [10.1016/j.mtcomm.2020.101231]

38. Xu Zhang, Guangping Sun, Xuequan Zhang.  (2020)  A novel thermoplastic shape memory polymer with solid-state plasticity derived from exchangeable hydrogen bonds.  RSC Advances,  10  (16): (9387-9395).  [PMID:35497231] [10.1039/D0RA00988A]

39. Weiqi Xie, Donglin Tang, Shumei Liu, Jianqing Zhao.  (2020)  Facile synthesis of bio-based phosphorus-containing epoxy resins with excellent flame resistance.  POLYMER TESTING,      [PMID:] [10.1016/j.polymertesting.2020.106466]

40. Jinghong Liu, Zhuojian He, Guohui Wu, Xiaoqing Zhang, Chen Zhao, Caihong Lei.  (2020)  Synthesis of a novel nonflammable eugenol-based phosphazene epoxy resin with unique burned intumescent char.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2020.124620]

41. Chen Danping, Wang Yang, Mo Mingming, Zhang Junjie, Zhang Yanfei, Xu Yuzhi, Liu Si-Yang, Chen Jun, Ma Yingjun, Zhang Li, Dai Zong, Cai Chun, Zou Xiaoyong.  (2019)  Polymerization retardation isothermal amplification (PRIA): a strategy enables sensitively quantify genome-wide 5-methylcytosine oxides rapidly on handy instruments with nanoscale sample input.  NUCLEIC ACIDS RESEARCH,  47  (19): (e119).  [PMID:31418020] [10.1093/nar/gkz704]

42. Xiao Jia, Huan-Nian Ye, Huilan Weng, Ning Huang, Yan Yu, Jin-Ping Xue.  (2019)  Small molecular target-based multifunctional upconversion nanocomposites for targeted and in-depth photodynamic and chemo-anticancer therapy.  Materials Science & Engineering C-Materials for Biological Applications,      [PMID:31499944] [10.1016/j.msec.2019.109849]

43. Jiangjun Zhou, Kaijie Xu, Mengjia Xie, Haifeng Wu, Zan Hua, Zhongkai Wang.  (2019)  Two Strategies to precisely tune the mechanical properties of plant oil-derived epoxy resins.  COMPOSITES PART B-ENGINEERING,      [PMID:] [10.1016/j.compositesb.2019.05.096]

44. Lu Dai, Xixi Wang, Zhiyang Bu, Bo-Geng Li, Suyun Jie.  (2018)  Facile access to carboxyl-terminated polybutadiene and polyethylene from cis-polybutadiene rubber.  JOURNAL OF APPLIED POLYMER SCIENCE,  136  (2): (46934).  [PMID:] [10.1002/app.46934]

45. Yang Jianzhou, Jiang Jiajia, Jiang Juncheng, Pan Xuhai, Pan Yong, Ni Lei.  (2018)  Thermal instability and kinetic analysis on m-chloroperbenzoic acid.  JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,  135  (4): (2309-2316).  [PMID:] [10.1007/s10973-018-7470-x]

46. Renxin Xu, Detian Meng, Huajun Sun, Jing Zhou, Shixin Cheng, Zheng Li.  (2018)  Synthesis and properties of cycloaliphatic epoxy resins containing imide and diphenyl sulfone.  HIGH PERFORMANCE POLYMERS,      [PMID:] [10.1177/0954008318774822]

47. Huimin Zhao, Siyuan Li, Zixin Yang, Ying Peng, Xiaohui Chen, Jiang Zheng.  (2018)  Identification of Ketene-Reactive Intermediate of Erlotinib Possibly Responsible for Inactivation of P450 Enzymes.  DRUG METABOLISM AND DISPOSITION,  46  (4): (442-450).  [PMID:29352069] [10.1124/dmd.117.079327]

48. Dan Liu, Ting Qiao, Haiyan Liu, Xiaoling Wang, Zhi-guo Shi.  (2017)  A simple approach to prepare a sulfone-embedded stationary phase for HPLC.  JOURNAL OF SEPARATION SCIENCE,  41  (4): (877-885).  [PMID:29205869] [10.1002/jssc.201700751]

49. Liu Shaojie, Xing Yubin, Han Jiangze, Tang Erjun.  (2017)  Catalytic oxidation of cellulose with a novel amphiphilic nitroxide block copolymer as a recoverable catalyst.  CELLULOSE,  24  (9): (3635-3644).  [PMID:] [10.1007/s10570-017-1375-x]

50. Hongjun Yang, Aibin Sun, Chenqun Chai, Wenyan Huang, Xiaoqiang Xue, Jianhai Chen, Bibiao Jiang.  (2017)  Synthesis and post-functionalization of a degradable aliphatic polyester containing allyl pendent groups.  POLYMER,      [PMID:] [10.1016/j.polymer.2017.06.029]

51. Peng Zhong-chuan, Li Qian, Li Hua-yi, Hu You-liang.  (2017)  Layered nanoparticles modified by chain end functional PE and their nanocomposites with PE.  CHINESE JOURNAL OF POLYMER SCIENCE,  35  (7): (897-908).  [PMID:] [10.1007/s10118-017-1931-8]

52. Yuchen Feng, Suyun Jie, Bo-Geng Li.  (2017)  Synthesis of ethylene/vinyl ester copolymers with pendent linear branches via ring-opening metathesis polymerization of fatty acid-derived cyclooctenes.  JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,  55  (13): (2211-2220).  [PMID:] [10.1002/pola.28606]

53. Yukun Feng, Hui Wang, Qian Wang, Wenlin Huang, Ying Peng, Jiang Zheng.  (2017)  Chemical Interaction of Protein Cysteine Residues with Reactive Metabolites of Methyleugenol.  CHEMICAL RESEARCH IN TOXICOLOGY,      [PMID:28107620] [10.1021/acs.chemrestox.6b00290]

54. Qinzhuo Zhou, Anqi Wang, Lu Dai, Suyun Jie, Bo-Geng Li.  (2016)  Cleavable polybutadiene rubber: A versatile precursor to hydroxyl-terminated or multi-hydroxyl polybutadiene and polyethylene.  POLYMER,      [PMID:] [10.1016/j.polymer.2016.11.033]

55. Shaojie Liu, Huali Wang, Xiaomeng Chu.  (2016)  Nitroxide polymer brushes as efficient and recoverable catalysts for the selective oxidation of primary alcohols to aldehydes.  JOURNAL OF APPLIED POLYMER SCIENCE,  134  (1):   [PMID:] [10.1002/app.44365]

56. Wen-Qiang Zhang, Xiu-Li Wang, Gui-Cheng Liu, Li Chen, Yu-Zhong Wang.  (2016)  Thermal transition behaviors, solubility, and mechanical properties of wholly aromatic para-, meta-poly(ether-amide)s: effect on numbers of para-aryl ether linkages.  RSC Advances,  6  (87): (84284-84293).  [PMID:] [10.1039/C6RA11163G]

57. Jie Chen, Xiaoying Li, Yigang Wang, Ke Li, Jinrui Huang, Jianchun Jiang, Xiaoan Nie.  (2016)  Synthesis and application of a novel environmental plasticizer based on cardanol for poly(vinyl chloride).  Journal of the Taiwan Institute of Chemical Engineers,      [PMID:] [10.1016/j.jtice.2016.05.025]

58. Huina Yao, Ying Peng, Jiang Zheng.  (2016)  Identification of glutathione and related cysteine conjugates derived from reactive metabolites of methyleugenol in rats.  CHEMICO-BIOLOGICAL INTERACTIONS,      [PMID:27154494] [10.1016/j.cbi.2016.05.006]

59. Chao Li, Jinyue Dai, Xiaoqing Liu, Yanhua Jiang, Songqi Ma, Jin Zhu.  (2016)  Green Synthesis of a Bio-Based Epoxy Curing Agent from Isosorbide in Aqueous Condition and Shape Memory Properties Investigation of the Cured Resin.  MACROMOLECULAR CHEMISTRY AND PHYSICS,  217  (13): (1439-1447).  [PMID:] [10.1002/macp.201600055]

60. Ben Dong, Mei Yang, Shusheng Ge, Yi Cao, Baoyan Li, Yun Lu.  (2016)  Synthesis and photoluminescence modulating of polypyrrole fluorescent nano-spheres/dots.  RSC Advances,  6  (28): (23737-23745).  [PMID:] [10.1039/C6RA01468B]

61. Meina Chi, Ying Peng, Jiang Zheng.  (2015)  Characterization of glutathione conjugates derived from reactive metabolites of bakuchiol.  CHEMICO-BIOLOGICAL INTERACTIONS,      [PMID:26712081] [10.1016/j.cbi.2015.12.009]

62. Fu Yang, Shuying Gao, Cuirong Xiong, Haiqing Wang, Jin Chen, Yan Kong.  (2015)  Coordination of manganese porphyrins on amino-functionalized MCM-41 for heterogeneous catalysis of naphthalene hydroxylation.  CHINESE JOURNAL OF CATALYSIS,      [PMID:] [10.1016/S1872-2067(15)60836-1]

63. Qinzhuo Zhou, Suyun Jie, Bo-Geng Li.  (2015)  Facile synthesis of novel HTPBs and EHTPBs with high cis-1,4 content and extremely low glass transition temperature.  POLYMER,      [PMID:] [10.1016/j.polymer.2015.04.078]

64. Xiaoqian Ge, Liang Dong, Lining Sun, Zhengmei Song, Ruoyan Wei, Liyi Shi, Haige Chen.  (2015)  New nanoplatforms based on UCNPs linking with polyhedral oligomeric silsesquioxane (POSS) for multimodal bioimaging.  Nanoscale,  7  (16): (7206-7215).  [PMID:25811398] [10.1039/C5NR00950B]

65. Qinzhuo Zhou, Suyun Jie, Bo-Geng Li.  (2014)  Preparation of Hydroxyl-Terminated Polybutadiene with High Cis-1,4 Content.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/ie503652g]

66. Ying-Ying Zhang, Xing-Hong Zhang, Ren-Jian Wei, Bin-Yang Du, Zhi-Qiang Fan, Guo-Rong Qi.  (2014)  Synthesis of fully alternating polycarbonate with low Tg from carbon dioxide and bio-based fatty acid.  RSC Advances,  4  (68): (36183-36188).  [PMID:] [10.1039/C4RA06157H]

67. Yang Meng, Junfeng Chu, Jiajia Xue, Chaohao Liu, Zhen Wang, Liqun Zhang.  (2014)  Design and synthesis of non-crystallizable, low-Tg polysiloxane elastomers with functional epoxy groups through anionic copolymerization and subsequent epoxidation.  RSC Advances,  4  (59): (31249-31260).  [PMID:] [10.1039/C4RA02293A]

68. Jie Zhao, Hongjuan Li, Kui Yang, Shiguo Sun, Aiping Lu, Yongqian Xu.  (2014)  A specific and rapid “on-off” acenaphthenequinone-based probe for HOCl detection and imaging in living cells.  NEW JOURNAL OF CHEMISTRY,  38  (8): (3371-3374).  [PMID:] [10.1039/C4NJ00470A]

69. Ma SongQi, Liu XiaoQing, Jiang YanHua, Fan LiBo, Feng JianXiang, Zhu Jin.  (2013)  Synthesis and properties of phosphorus-containing bio-based epoxy resin from itaconic acid.  Science China-Chemistry,  57  (3): (379-388).  [PMID:] [10.1007/s11426-013-5025-3]

70. Yan Zhang, Jinhong Li, Zhengzhen Du, Meidong Lang.  (2013)  Synthesis and pH-responsive assembly of methoxy poly(ethylene glycol)-b-poly(ε-caprolactone) with pendant carboxyl groups.  JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,  52  (2): (188-199).  [PMID:] [10.1002/pola.26987]

71. Chang-Di Chen, Wen-Bing Sheng, Guo-Jun Shi, Can-Cheng Guo.  (2012)  Substituent-induced regioselective hydroxylation of the aromatic C–H bond on naphthalene with metachloroperbenzoic acid catalyzed by F20TPPMnCl.  JOURNAL OF PHYSICAL ORGANIC CHEMISTRY,  26  (1): (23-29).  [PMID:] [10.1002/poc.3012]

72. Beitao Liu, Jiahui Li, Cijian Zhang, Yibo Wang, Xigao Jian, Zhihuan Weng.  (2024)  “Polymer to polymer” recycling and body-temperature triggered shape memory of a carvone-based epoxy thermoset system achieved using a thiol-Michael covalent adaptable network.  Journal of Materials Chemistry A,      [PMID:] [10.1039/D4TA03378G]

73. Nianzhao Gao, Yang Lu, Jicheng Li, Feiyang Zhao, Minghui Ru, Shujun Zhao, Shuangfei Xiang, Feiya Fu, Hongyan Diao, Xiangdong Liu.  (2024)  A fully degradable epoxy resin based on a nontoxic triphenol derived from diphenolic acid and eugenol.  Polymer Chemistry,      [PMID:] [10.1039/D4PY00599F]

74. Xiujie Quan, Zhixin Lin, Conglin Chen, Tao Ma, Yang Zhang.  (2024)  A sustainable rapeseed oil-based bio-additive designed for hard asphalt binders: Performance, environmental, and economic assessment.  FUEL,      [PMID:] [10.1016/j.fuel.2024.132191]

75. Yulu Yang, Xianhui Zhang, Yao Yang, Pengfei Gao, Wuzhe Fan, Tao Zheng, Weihu Yang, Yu Tang, Kaiyong Cai.  (2024)  A two-pronged approach to inhibit ferroptosis of MSCs caused by the iron overload in postmenopausal osteoporosis and promote osseointegration of titanium implant.  Bioactive Materials,      [PMID:39161794] [10.1016/j.bioactmat.2024.07.024]

76. Ruoyu Li, Wenfeng Li, Yungshan Teng, Runze Li, Siyi Kong, Xin Chen, Haotian Luo, Danying Chen, Yuqing Guo, Yangqiao Qing, Hio Cheng leong, Bingyan Guo, Meihan Chen, Zixin Pan, Shushuo Zheng, Yihong Deng, Yang Cao, Chen Zhou, Xuenong Zou, Weicai Wang.  (2025)  Ameliorating macrophage pyroptosis via ANXA1/NLRP3/Caspase-1/GSDMD pathway：Ac2-26/OGP-loaded intelligent hydrogel enhances bone healing in diabetic periodontitis.  Biofabrication,      [PMID:39773706] [10.1088/1758-5090/ada737]

77. Jing Chen, Deqi Yang, Guoqi Zhu, Ru Zhang, Bingfang Wang, Zhiqiang Chang, Jing Dai, Wenjuan Wu, Menahem Y. Rotenberg, Yin Fang.  (2024)  Automated and ultrasensitive point-of-care glycoprotein detection using boronate-affinity enhanced organic electrochemical transistor patch.  BIOSENSORS & BIOELECTRONICS,      [PMID:38554574] [10.1016/j.bios.2024.116229]

78. Zhang Jinbo, Jiang Lihang, Liu Shaofeng, Shen Junhao, Braunstein Pierre, Shen Yong, Kang Xiaohui, Li Zhibo.  (2024)  Bifunctional and recyclable polyesters by chemoselective ring-opening polymerization of a δ-lactone derived from CO2 and butadiene.  Nature Communications,  15  (1): (1-12).  [PMID:39379349] [10.1038/s41467-024-52090-2]

79. Meiying Ge, Jia-Tao Miao, Guozheng Liang, Aijuan Gu.  (2024)  Biobased epoxy resin with ultrahigh glass transition temperature over 400 °C by post-crosslinking strategy.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.148993]

80. Qianqian Fan, Jiahui Li, Qi Cao, Chengwen Gu, Qian Liu, Xigao Jian, Zhihuan Weng.  (2024)  Bio-based liquid crystal epoxy resins: Toughening and strengthening of conventional epoxy resins with strategically extended spacer layers.  COMPOSITES COMMUNICATIONS,      [PMID:] [10.1016/j.coco.2024.102068]

81. Wei Du, Henan Wei, Tiankuan Zhu, Shiping Zhang.  (2024)  Combination of ring-opening polymerization and “click” chemistry towards functionalization of polycaprolactone with sulfobetaine groups.  POLYMER,      [PMID:] [10.1016/j.polymer.2024.126721]

82. Xie Tianyu, Hu Wenbo, You Lin, Wang Xin.  (2024)  Design, synthesis and biological evaluation of thienopyridine derivatives as c-Met kinase inhibitors.  MOLECULAR DIVERSITY,      [PMID:39356364] [10.1007/s11030-024-10998-3]

83. Yunxia Yuan, Bingqing Chi, Jiajia Fan, Ying Wang, Gan Luo, Xiaoyan Gao.  (2025)  Enhancing the Accuracy of Identification and Relative Quantification of Unsaturated Fatty Acids in Serum via a Stable Isotope-Labeled Double Derivatization Strategy.  ANALYTICAL CHEMISTRY,      [PMID:40019293] [10.1021/acs.analchem.4c06375]

84. Langlang Dai, Yuehong Zhang, Fei Ma, Tuo Ji, Lei Zhang, Bin Lyu.  (2025)  Eugenol-Based Epoxy Materials with High Biobased Carbon Content and Their Structure–Property Relationships.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.4c03649]

85. Yang Yang, Yifan Li, Qinhui Xie, Bo Jiang, Junbo Li, Yunfei Xie, Wei Ji.  (2024)  Evaluating the Kinetics and Molecular Mechanism for Biomimetic Metabolic Activation of PAHs by Surface-Enhanced Raman Scattering Spectroscopy.  ANALYTICAL CHEMISTRY,      [PMID:38869249] [10.1021/acs.analchem.4c01437]

86. Huiting Lin, Yichang Ma, Xiaocan Wang, Guiqin Yi, Aimei Zhu, Qinglin Liu, Qiugen Zhang.  (2024)  Highly-conductive proton exchange membrane of sulfonated poly(biphenyl alkylene) copolymers for H2/O2 fuel cell with 2.62 W cm-2 power density.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2024.122479]

87. Xiujie Quan, Xiyin Liu, Conglin Chen, Tao Ma, Xing Wang, Yang Zhang.  (2024)  Improving thermal cracking and fatigue cracking performance of hard asphalt binders with bio-renewable additives.  CONSTRUCTION AND BUILDING MATERIALS,      [PMID:] [10.1016/j.conbuildmat.2024.139305]

88. Zitong Jiang, Shaohu Huo, Lei Qiao, Paiyu Lin, Ling Fu, Yaling Wu, Wenhong Li, Chenrong Bian, Yaoyao Li, Nan Li, Haiyan Cheng, Xuan Nie, Shenggang Ding.  (2024)  Inhalable mucin-permeable nanomicelles deliver antibiotics for effective treatment of chronic pneumonia.  Journal of Materials Chemistry B,      [PMID:39109448] [10.1039/D3TB02970K]

89. Weiping Xu, Dan Zhao, Xiaoqing Jiang, Dong Chen, Wantai Yang, Yuhong Ma.  (2025)  Modification of epoxy resins with different molecular weight poly(aryl ether sulfone) as effective toughening agents.  POLYMER,      [PMID:] [10.1016/j.polymer.2025.128324]

90. Pengzhi Bi, Xiuzhong Zhu, Li Tian, Jinbang Han, Wanbin Zhang, Tong Wang.  (2024)  Preparation and Performance Study of HTPB-g-(PNIPAM/PEG) Thermoresponsive Polymer Brush.  Polymers,  16  (9): (1248).  [PMID:38732717] [10.3390/polym16091248]

91. Guan-Long Wu, Yu Li, Ji-Xin Zhu, Yuan Hu, Zhou Gui, Xin Wang.  (2025)  Sustainably sourced epoxy thermal management composites with simultaneously improved thermal conductivity, dielectric properties and fire safety.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.161023]

92. Tao Li, Mingzu Zhang, Jinlin He, Peihong Ni.  (2024)  Synthesis and Characterization of Graft Copolymers with Poly(ε-caprolactone) Side Chain Using Hydroxylated Poly(β-myrcene-co-α-methyl styrene).  MOLECULES,  29  (10): (2363).  [PMID:38792224] [10.3390/molecules29102363]

93. Zhiyuan Zeng, Tianqun Zhao, Yi Gong, Zhiqiang Yu.  (2024)  Synthesis, curing kinetics and properties of novel aromatic multifunctional epoxy resin.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2024.113375]

94. Fei Wu, Fengqing Chen, Zhenghong Guo, Hangtian Hu, Lina Liu.  (2025)  Bio-based eugenol flame retardant for simultaneously enhancing fire safety and mechanical performance of epoxy resin.  Materials Today Communications,      [PMID:] [10.1016/j.mtcomm.2025.113511]

95. Huan Liu, Shihong Cheng, Yadong Yang, Chunlin Wang, Shijiang Zhu, Fuchun Zhao.  (2022)  Strong Hydrophobic and Ultraviolet Reflective Film from Fluorinated Polyisoprene with Microphase Separation via Thiol–Epoxy Click Chemistry.  MACROMOLECULAR CHEMISTRY AND PHYSICS,  223  (18): (2200100).  [PMID:] [10.1002/macp.202200100]

96. Jun Deng, Xiaoqing Liu, Chao Li, Yanhua Jiang, Jin Zhu.  (2015)  Synthesis and properties of a bio-based epoxy resin from 2,5-furandicarboxylic acid (FDCA).  RSC Advances,  5  (21): (15930-15939).  [PMID:] [10.1039/C5RA00242G]

97. Kun Xu, Yanan Zou, Chuanchuan Lin, Liangshuai Zhang, Meijun Tan, Meng Li, Jing Wu, Xuan Li, Ye He, Peng Liu, Ke Li, Kaiyong Cai.  (2024)  Cascade catalysis nanozyme for interfacial functionalization in combating implant infections associated with diabetes via sonodynamic therapy and adaptive immune activation.  BIOMATERIALS,      [PMID:38850718] [10.1016/j.biomaterials.2024.122649]

98. Yan Zhao, Bolei Wei, Mi Wu, Huiliang Zhang, Jinrong Yao, Xin Chen, Zhengzhong Shao.  (2019)  Preparation and characterization of antibacterial poly(lactic acid) nanocomposites with N-halamine modified silica.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:31751749] [10.1016/j.ijbiomac.2019.11.125]

99. Wenjing Yu, Kaiju Sun, Liying Zhang, Xilin Wan, Changbao Chen, Rui Su, Yifei Liu, Hongfeng Wang, Hongmei Yang.  (2020)  Investigation of the Effects of Squalene and Squalene Epoxides on the Homeostasis of Coenzyme Q10 in Rats by UPLC-Orbitrap MS.  CHEMISTRY & BIODIVERSITY,  17  (8): (e2000243).  [PMID:32472636] [10.1002/cbdv.202000243]

100. Yongjing Liu, Dongting Huang, Lirong Chen, Huixin You, Hua Li, Wei Xu.  (2025)  Boric acid-functional Zn-organic framework as dispersive solid-phase extraction adsorbent combined with deep eutectic solvent for efficient purification of scutellarin.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2025.133344]

101. Kaiguo Xia, Guang Chen, Bingbing Hou, Zhe Wang, Yaqi Zhu, Yuexian Xu, Shanfu Zhang, Qiang Xuan, Yezi You, Zongyao Hao.  (2025)  Trimethylamine N-Oxide–Derived Zwitterion Coating for Polyurethane Ureteral Stents Prevents Encrustation Formation.  Acta Biomaterialia,      [PMID:40318742] [10.1016/j.actbio.2025.04.058]

102. Jingman Xie, Kangle Yan, Hailong Wang, Shuo Geng, Yan Gao, Wangmao Tian, Chengcheng Hu, Liang Yuan.  (2025)  Oxidation of Polydithioacetals towards Enhanced Interchain Interactions and Oxidative Stability.  Polymer Chemistry,      [PMID:] [10.1039/D5PY00359H]

103. Junbo Zang, Jiahui Qi, Jiaxu Zhang, Hao Liu, Chunhong Zhang, Chengyue Zhang, Runtian Wu, Xiaochao Xu, Lei Shang.  (2026)  High-strength, flame-retardant, dielectric Si-functionalized biomass hybrid crosslinked non-isocyanate polyurethane-epoxy for general-purpose adhesive.  POLYMER DEGRADATION AND STABILITY,      [PMID:] [10.1016/j.polymdegradstab.2026.111997]