2-Propanol-d₈ - ≥99.5 atom% D , CAS No.22739-76-0

CAS: 22739-76-0 Cat. No.: P432348 Fórmula: CD₃CD(OD)CD₃ Peso molecular: 68.14 Beilstein Registry Number: 1816231 Número CE: 245-189-2

GRADE & PURITY ≥99.5 atom% D

Synonyms

AKOS015903465 | D99058 | EINECS 245-189-2 | 1,1,1,2,3,3,3-heptadeuterio-2-deuteriooxypropane | 2-Propan-1,1,1,2,3,3,3-d7-ol-d | Propan-1,1,1,2,3,3,3-d7-2-ol-d | (O,1,1,1,2,3,3,3-2H8)Propan-2-ol | J-014836 | A935653 | MFCD00044341 | 2-Propanol-d8 | 2-Propa

Storage

Room temperature,Argon charged

Shipped In

Normal

Visão geral

2-Propanol-d 8 (Isopropanol-d 8 ) is a deuterated derivative of isopropanol. Generation and decay of correlated radical pairs (SCRP) during the reduction of acetone(D 6 ) in 2-propanol(D 8 ) have been studied by Fourier transform-electron paramagnetic resonance (FT-EPR) spectroscopy. It participates as solvent during the evaluation of triplet decay constants, triplet lifetime and photoreduction rate constants of benzophenone.

Application

2-Propanol-d 8 may be used in the preparation of 2-iodopropane-d 7 .

Specifications

Sinónimos

AKOS015903465 | D99058 | EINECS 245-189-2 | 1,1,1,2,3,3,3-heptadeuterio-2-deuteriooxypropane | 2-Propan-1,1,1,2,3,3,3-d7-ol-d | Propan-1,1,1,2,3,3,3-d7-2-ol-d | (O,1,1,1,2,3,3,3-2H8)Propan-2-ol | J-014836 | A935653 | MFCD00044341 | 2-Propanol-d8 | 2-Propa

Especificações e pureza

≥99.5 atom% D

Condições de armazenamento de armazenamento

Room temperature,Argon charged

Enviado em

Normal

Pureza

≥99.5 atom% D

Nomes e identificadores

• Sorrisos canónicos: CC(C)O
• IUPAC Name: 1,1,1,2,3,3,3-heptadeuterio-2-deuteriooxypropane
• InChIKey: KFZMGEQAYNKOFK-PIODKIDGSA-N
• INCHI: 1S/C3H8O/c1-3(2)4/h3-4H,1-2H3/i1D3,2D3,3D,4D
• SMILES isoméricas: [2H]C([2H])([2H])C([2H])(C([2H])([2H])[2H])O[2H]
• WGK Alemanha: 3
• Peso molecular: 68.14
• Beilstein: 1816231
• Reaxy-Rn: 635639
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=635639&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic oxygen compounds
    • Classe Organooxygen compounds
      • Subclass Alcohols and polyols

• Kingdom: Organic compounds
• Superclass: Organic oxygen compounds
• Classe: Organooxygen compounds
• Subclass: Alcohols and polyols
• Intermediate Tree Nodes: Not available
• Direct Parent: Secondary alcohols
• Alternative Parents: Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Secondary alcohol - Hydrocarbon derivative - Aliphatic acyclic compound
• Descrição: This compound belongs to the class of organic compounds known as secondary alcohols. These are compounds containing a secondary alcohol functional group, with the general structure HOC(R)(R') (R,R'=alkyl, aryl).
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propriedades químicas e físicas

• Sensibilidade: heat sensitive
• Índice de refração: 1.3728
• Ponto de inflamação (°F): 53.6 °F
• Ponto de inflamação (°C): 12 °C
• Ponto de ebulição (°C): 82°C
• Ponto de fusão (°C): -89.5°C
• Peso molecular: 68.140 g/mol
• XLogP3: 0.300
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 68.1077 Da
• Monoisotopic Mass: 68.1077 Da
• Topological Polar Surface Area: 20.200 Ų
• Heavy Atom Count: 4
• Formal Charge: 0
• Complexity: 10.800
• Isotope Atom Count: 8
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

Referências

1. Wang Tianjiao, Xin Yu, Chen Bingfeng, Zhang Bin, Luan Sen, Dong Minghua, Wu Yuxuan, Cheng Xiaomeng, Liu Ye, Liu Huizhen, Han Buxing.  (2024)  Selective hydrodeoxygenation of α, β-unsaturated carbonyl compounds to alkenes.  Nature Communications,  15  (1): (1-10).  [PMID:38461211] [10.1038/s41467-024-46383-9]