Allyltrimethoxysilane - ≥97%(GC) , CAS No.2551-83-9

CAS: 2551-83-9 Cat. No.: A151275 Molecular Weight: 162.26 Beilstein Registry Number: 2350750 EC Number: 219-855-8

GRADE & PURITY ≥97%(GC)

Synonyms

A901416 | Allyltrimethoxysilane, 95% | SCHEMBL93295 | J-016033 | FT-0694825 | FS-4958 | LFRDHGNFBLIJIY-UHFFFAOYSA-N | Silane, trimethoxy-2-propenyl- | MFCD00053865 | AKOS008901195 | Silane, allyltrimethoxy- | Allyltrimethoxysilane, >=98%, deposition grade

Storage

Argon charged,Room temperature

Shipped In

Normal

Overview

Allyltrimethoxysilane is an allylating reagent that can be used for the allylation of carbonyl compounds such as aldehydes, ketones, and imines. Homoallylic alcohols and amines are obtained via the C-C bond forming reaction.It can also be used to synthesize homoallylic α-branched amines from aromatic and aliphatic aldehyde hydrazones, and ketone hydrazones.

Specifications

Synonyms

A901416 | Allyltrimethoxysilane, 95% | SCHEMBL93295 | J-016033 | FT-0694825 | FS-4958 | LFRDHGNFBLIJIY-UHFFFAOYSA-N | Silane, trimethoxy-2-propenyl- | MFCD00053865 | AKOS008901195 | Silane, allyltrimethoxy- | Allyltrimethoxysilane, >=98%, deposition grade

Specifications & Purity

≥97%(GC)

Storage

Argon charged, Room temperature

Shipped In

Normal

Purity

≥97%(GC)

Names and Identifiers

• Pubchem Sid: 488185156
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488185156
• Canonical Smiles: CO[Si](CC=C)(OC)OC
• IUPAC Name: trimethoxy(prop-2-enyl)silane
• InChIKey: LFRDHGNFBLIJIY-UHFFFAOYSA-N
• INCHI: 1S/C6H14O3Si/c1-5-6-10(7-2,8-3)9-4/h5H,1,6H2,2-4H3
• Isomeric SMILES: CO[Si](CC=C)(OC)OC
• WGK Germany: 3
• UN Number: 1993
• Packing Group: III
• Molecular Weight: 162.26
• Beilstein: 2350750
• Reaxy-Rn: 2350745
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=2350745&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Class Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Alkoxysilanes
          • Level6 Trialkoxysilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Class: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Alkoxysilanes
• Direct Parent: Trialkoxysilanes
• Alternative Parents: Silyl ethers Organoheterosilanes Organic metalloid salts Organooxygen compounds Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkoxysilane - Silyl ether - Organoheterosilane - Organic metalloid salt - Organic oxygen compound - Hydrocarbon derivative - Organic salt - Organooxygen compound - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as trialkoxysilanes. These are organosilicon compounds with the general formula RO[Si](R')(OR'')OR''' (R-R''' = aliphatic organyl group).
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Moisture sensitive
• Refractive Index: 1.405
• Flash Point(°F): 114.8 °F
• Flash Point(°C): 31°C
• Boil Point(°C): 136°C
• Molecular Weight: 162.260 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 162.071 Da
• Monoisotopic Mass: 162.071 Da
• Topological Polar Surface Area: 27.700 Ų
• Heavy Atom Count: 10
• Formal Charge: 0
• Complexity: 92.900
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

References

1. Bo Wang, Jianhua Sha, Shuaishuai Chen, Weiyan Yin, Yude Li, Qinyan Yue, Haiyan Yu, Shiping Xu.  (2023)  Enhanced adsorption-photocatalysis synergy and stability of polypropylene photocatalytic floating ball benefitted from click chemistry connection.  JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,      [PMID:] [10.1016/j.jphotochem.2023.114883]