Triisopropylsilyl Chloride( TIPSCl) - ≥95%(GC) , CAS No.13154-24-0

CAS: 13154-24-0 Cat. No.: T162257 Molecular Weight: 192.8 Beilstein Registry Number: 1737450 EC Number: 603-492-0 PubChem CID: 139400

GRADE & PURITY ≥95%(GC)

Synonyms

UN 2577 | AKOS006222739 | BP-21129 | Chloro triisopropylsilane | chloro- triisopropylsilane | tri(propan-2-yl)silyl chloride | BDBM50167968 | Q2453270 | chlortriisopropylsilane | triisopropyl silyl chloride | tri-isopropyl silyl chloride | S17950 | Silane

Storage

Room temperature,Argon charged

Shipped In

Normal

Overview

TIPS can replace alkynes for the preparation of silicon-based vinyl eneones from chromium carbene complexes.

Specifications

Synonyms

UN 2577 | AKOS006222739 | BP-21129 | Chloro triisopropylsilane | chloro- triisopropylsilane | tri(propan-2-yl)silyl chloride | BDBM50167968 | Q2453270 | chlortriisopropylsilane | triisopropyl silyl chloride | tri-isopropyl silyl chloride | S17950 | Silane

Specifications & Purity

≥95%(GC)

Storage

Room temperature, Argon charged

Shipped In

Normal

Purity

≥95%(GC)

Names and Identifiers

• Canonical Smiles: CC(C)[Si](C(C)C)(C(C)C)Cl
• IUPAC Name: chloro-tri(propan-2-yl)silane
• InChIKey: KQIADDMXRMTWHZ-UHFFFAOYSA-N
• INCHI: 1S/C9H21ClSi/c1-7(2)11(10,8(3)4)9(5)6/h7-9H,1-6H3
• Isomeric SMILES: CC(C)[Si](C(C)C)(C(C)C)Cl
• WGK Germany: 3
• PubChem CID: 139400
• Molecular Weight: 192.8
• Beilstein: 1737450
• Reaxy-Rn: 1737446

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Class Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Organoheterosilanes
          • Level6 Trialkylheterosilanes
            • Level7 Trialkylchlorosilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Class: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Organoheterosilanes - Trialkylheterosilanes
• Direct Parent: Trialkylchlorosilanes
• Alternative Parents: Silyl monohalides Organochlorosilanes Organic metalloid salts Alkylhalosilanes Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkylchlorosilane - Silyl monohalide - Organochlorosilane - Organic metalloid salt - Alkylhalosilane - Hydrocarbon derivative - Organic salt - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as trialkylchlorosilanes. These are organoheterosilanes, bearing a silicon atom linked to three alkyl groups and one chlorine atom.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Miscible with water.
• Sensitivity: Moisture sensitive
• Refractive Index: 1.4520 to 1.4540
• Flash Point(°F): 147.2 °F
• Flash Point(°C): 62°C
• Boil Point(°C): 96 °C/18 mmHg
• Molecular Weight: 192.800 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 192.11 Da
• Monoisotopic Mass: 192.11 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 11
• Formal Charge: 0
• Complexity: 97.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

References

1. Jinkang Dou, Minghui Xu, Bojun Tan, Hongchang Mo, Xianming Lu, Bozhou Wang, Ning Liu.  (2023)  Synthesis of Highly Stable and Reactive Nitrile N-Oxides and Their Application as Catalyst-Free Crosslinkers.  MACROMOLECULES,      [PMID:] [10.1021/acs.macromol.3c00360]

2. Lingxiao Ma, Xiuzhong Zhu, Wanbin Zhang, Haitao Zhang, Jianyong Wang, Jianbo Qu.  (2021)  Study on the preparation and performance comparison of side-chain hydroxyl-terminated polybutadiene derivatives with narrowly molecular weight distribution used for polyurethane.  POLYMER TESTING,      [PMID:] [10.1016/j.polymertesting.2021.107389]

3. Xiu-zhong Zhu, Xiao-dong Fan, Na Zhao, Xin Min, Jie Liu, Zi-chao Wang.  (2017)  Influence of mono-lithium based initiators with different steric volumes on 1,4 unit content of hydroxyl terminated polybutadiene using anionic polymerization.  RSC Advances,  7  (83): (52712-52718).  [PMID:] [10.1039/C7RA11117G]

4. You Zhang, Wenzhong Ma, Jing Zhong, Yu Qiao, Zihao Jiang, Ning Xu, Longgui Zhang.  (2026)  Controlling Mechanically Induced Luminescence in Polycaprolactone via Precision Circular Mechanophore Size Design.  POLYMER,      [PMID:] [10.1016/j.polymer.2026.129854]