Curpous oxide - ≥99% , CAS No.1317-39-1

CAS: 1317-39-1 Cat. No.: C108791 Molecular Weight: 143.09 EC Number: 215-270-7

GRADE & PURITY ≥99%

Synonyms

Dicopper Oxide

Storage

Argon charged,Room temperature

Shipped In

Normal

Overview

Copper(I)oxide is a weak base that can be used in nucleophilic substitution, decarboxylation, cyclocondensation, and 1,1-addition reactions. It can also be used to form carbenoid intermediates from diazo compounds and radicals from arenediazonium salts

Application：

Copper(I) oxide can be used as a catalyst to synthesize:
Ynones via solvent-free Sonogashira reaction；
N-Heteroaryl derivatives via cross-coupling of nitrogen heterocycles with halopyridines

Specifications

Synonyms

Dicopper Oxide

Specifications & Purity

≥99%

Storage

Argon charged, Room temperature

Shipped In

Normal

Purity

≥99%

Names and Identifiers

• WGK Germany: 3
• RTECS: GL8050000
• UN Number: 3077
• Molecular Weight: 143.09
• Reaxy-Rn: 16074385
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=16074385&ln=

Chemical and Physical Properties

• Solubility: It is insoluble in water and organic solvents
• Sensitivity: Air Sensitive；Moisture Sensitive
• Boil Point(°C): 1800℃
• Melt Point(°C): 1235°C

References

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72. Shi-Wei Fu, Jian Yang, Zong-Yan Zhao, Bao-Feng Shan, Jia-Xin Zhang, Jin Zhang, Qingju Liu, Jianyong Feng, Zhaosheng Li, Zhigang Zou.  (2024)  Band-Edge Electronic Structure on Photo(electro)catalytic Performance of ABO2 (A = Cu, Ag; B = Al, Ga, In): Elucidating the Role of Valence Electron States.  CHEMISTRY OF MATERIALS,      [PMID:] [10.1021/acs.chemmater.3c02898]

73. Wenyan Yan, Lin Zhou, Zisheng Luo, Shenghua Ding, Dong Li, Xingyu Lin.  (2024)  Cell-Membrane-Inspired Ultrathin Silica Nanochannels Coating for Long-Term Stable Photoelectrocatalysis with Enhanced Performance.  Advanced Science,      [PMID:39352301] [10.1002/advs.202407686]

74. Qi Wang, Xiangjian Liu, Jiawei Zhu, Heqing Jiang.  (2024)  Chlorine-oxidation-free dual hydrogen production by seawater electrolysis coupling formaldehyde oxidation.  ELECTROCHIMICA ACTA,      [PMID:] [10.1016/j.electacta.2024.144490]

75. Weiqian Cai, Youqun Wang, Linshan Xiong, Yingjie Zheng, Zhibin Zhang, Xiaohong Cao, Yunhai Liu.  (2025)  Construction of Au(Ag)/Cu2O-N integrated heterostructures for enhanced visible-light photocatalytic reduction of U(VI).  Journal of Environmental Chemical Engineering,      [PMID:] [10.1016/j.jece.2025.116250]

76. Chaofan Ma, Qun Yang, Huiyu Su, Huimin Yang, Xiaoxia Wang, Dawen Zeng.  (2024)  Cu-MOF-Derived C-Doped CuO/Cu2O Hollow Nano-Octahedrons for Room-Temperature NO2 Sensing at the ppb Level.  ACS Applied Nano Materials,      [PMID:] [10.1021/acsanm.3c05445]

77. Rui Yang, Xiaozhong Zheng, Hao Fu, Xinyue Cao, Yangguang Hu, Yiyin Huang.  (2024)  Dynamic Restructuring of Cu7S4/Cu for Efficient CO2 Electro-reduction to Formate.  ChemSusChem,      [PMID:38385812] [10.1002/cssc.202301771]

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83. Tao Chen, Chuan Ma, Ben Wang, Linlin Xu, Wu Yang, Lushi Sun.  (2024)  Kinetics and debromination studies on the pyrolysis of waste printed circuit boards with the addition of copper and copper oxides.  Journal of Cleaner Production,      [PMID:] [10.1016/j.jclepro.2024.141141]

84. Yao Tang, Chunyan Fan, Zehao Zang, Yahui Cheng, Lanlan Li, Xiaofei Yu, Xiaojing Yang, Zunming Lu, Xinghua Zhang, Hui Liu.  (2024)  Non-metallic surface-modified X-Cu (X = F, Cl, Br) metal catalysts for all-pH hydrogen evolution reaction with high performance.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:39681020] [10.1016/j.jcis.2024.12.078]

85. Anjie Wang, Anjun Huang, Heping Zhao, Yue Liu, Yuxia Luo, Dacheng Zhou, Zhiguo Song, Jianbei Qiu, Cherkasova Tatiana, Zhengwen Yang.  (2024)  Optical storage and encryption via efficient reversible luminescence modulation based on copper-doped borate glass.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.150648]

86. Wenjian Dong, Chunhua Ni, Xia Li, Liangmin Yu, Xuefeng Yan.  (2024)  Preparation and antifouling performance of tin-free self-polishing antifouling coatings based on side-chain suspended indole derivative structural resins.  MARINE POLLUTION BULLETIN,      [PMID:39278177] [10.1016/j.marpolbul.2024.116931]

87. Chuang Li, Lidong Dai, Haiying Hu, Meiling Hong.  (2024)  Pressure-induced structural phase transitions and metallization in cuprous oxide under different hydrostatic environments up to 25.3 GPa.  CHEMICAL PHYSICS,      [PMID:] [10.1016/j.chemphys.2024.112414]

88. Lu Zhao, Xing-Bo Chen, Xin-Ru Hu, Lei Chen, Shun Feng, Ai-Yong Zhang, Shu-Chuan Peng, Zhi-Xian Lin, Chu Jiang, Wei Da, Qi-Xin Wei.  (2024)  Refining metallic nano-copper by electron-rich black carbon for superior Fenton-like catalysis in water purification: The capacitive regulation of corrosive electron transfer.  JOURNAL OF HAZARDOUS MATERIALS,      [PMID:39067299] [10.1016/j.jhazmat.2024.135337]

89. Bo Cai, Chen-Guang Tao, Jian Yang, Zong-Yan Zhao.  (2024)  Revealing the lattice engineering of Delafossite in core–shell CuRhO2@CuGaO2 heterostructure for efficient visible light photocatalytic activity.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2024.159906]

90. Xin Ke, Bingqing Xie, Jingguo Zhang, Jianwei Wang, Weiying Li, Liqing Ban, Qiang Hu, Huijun He, Limin Wang, Zhong Wang.  (2024)  Study on the preparation of ascorbic acid reduced ultrafine copper powders in the presence of different protectants and the properties of copper powders based on methionine protection.  Nanoscale Advances,  6  (4): (1135-1144).  [PMID:38356627] [10.1039/D3NA01146A]

91. Sa Xiao, Lina Zhang, Lian Zhou, Hua Zhong, Mark L Brusseau, Yan Li, Yake Wang, Guansheng Liu, Juntao Zhang.  (2024)  The long-term effect of Fe3O4 in activating persulfate to degrade refractory organic contaminants for groundwater remediation.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.148801]

92. Kejing Wang, Yongjun Liu, Zhiwen Li, Nan Cui, Lei Sun, Wei Huang.  (2024)  Unraveling the roles of Cu0 and Cu+ in CuZnAl catalyst for CO hydrogenation to higher alcohols.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2024.07.240]

93. Qiong Wang, Yihang Zhang, Guangyi Tian, Zhiguang Guo.  (2025)  An Efficient Fog Collection Origami Janus Membrane for Rapid Directional Water Transport and Omnidirectional Fog Harvesting.  ACS Applied Materials & Interfaces,      [PMID:40637168] [10.1021/acsami.5c10459]

94. Kai Zhu, Zihan Lin, Xinyi Bai, Fangfang Chang, Qing Zhang, Xiaolei Wang, Zhengyu Bai.  (2025)  Enhanced Electrocatalytic Conversion of CO2 to C2+ Products via Intermediate Stabilized Cu+/Cu0 Interface Catalysts.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.5c03662]

95. Yaju Zhou, Jingyi Zhou, Weiwei Zhang, Jianglei Fan, Shen Wu, Xiuqing Li, Shizhong Wei.  (2025)  Improvement the thermal stability and mechanical properties of ODS cu alloy by forming composite oxide dispersion.  MATERIALS CHARACTERIZATION,      [PMID:] [10.1016/j.matchar.2025.115552]

96. Yushan He, Jun Zan, Zihui He, Xinna Bai, Cijun Shuai, Hao Pan.  (2024)  A Photochemically Active Cu2O Nanoparticle Endows Scaffolds with Good Antibacterial Performance by Efficiently Generating Reactive Oxygen Species.  Nanomaterials,  14  (5): (452).  [PMID:38470782] [10.3390/nano14050452]

97. Zhen Chen, Guiqiu Li, Xinlong Zheng, Yuhao Liu, Jun Dai, Bo Huang, Meng Xia, Lulu Yan, Qi Chen, Yijun Shen, Dong Wang, Meng Li, Wei Xiao, Xinlong Tian, Juanxiu Xiao.  (2024)  Facile synthesis of advanced BaTiO3/CuPbSbS3 heterostructure photocatalyst with enhanced piezo-photocatalytic degradation performance.  Nano Energy,      [PMID:] [10.1016/j.nanoen.2024.109463]

98. Yue Junyi, Zhang Simeng, Wang Xingyu, Fu Jiamin, Xu Yang, Weng Suting, Zhu Ye, Zhao Changtai, Zheng Matthew, Wang Yueyue, Zhu Xiangzhen, Wu Han, Wang Guanzhi, Xia Yu, Cao Mengyan, Jing Qihang, Wang Xuefeng, Xia Wei, Liang Jianwen, Sun Xueliang, Li Xiaona.  (2025)  Universal superionic conduction via solid dissociation of salts in van der Waals materials.  Nature Energy,  10  (10): (1237-1250).  [PMID:] [10.1038/s41560-025-01853-2]

99. Dai Zechuan, Chen Yanxu, Zhang Huaikun, Cheng Mingyu, Zhang Bocheng, Feng Pingyi, Feng Yafei, Zhang Genqiang.  (2025)  Surface engineering on bulk Cu2O for efficient electrosynthesis of urea.  Nature Communications,  16  (1): (1-13).  [PMID:40188148] [10.1038/s41467-025-57708-7]

100. Xinru Huang, Hang Yang, Yi Wei, Haonan Ju, Wei Wang, Dong Tu, Guogang Li.  (2025)  Dynamic and Static Stress Sensing Based on Mechanical Quenching Phenomenon From CaZnOS:Cu+.  Laser & Photonics Reviews,      [PMID:] [10.1002/lpor.202402010]

101. Chen Wang, Yunpeng Zou, Xiaohui Wu, Xiangling Zhang, Wenjiao Sang, Tao Zhou, Mingjie Huang.  (2025)  Citrate-ball milled Cu-Fe oxides activate O2 triggering selective non-radical mechanism: A boosted strategy coupling oxygen vacancies with surface carboxyl.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.164580]

102. Jinghao Lu, Lili Yang, Chuanhui Zhang, Haijie Cao, Xingyun Li, Lianying Zhang, Chang Long, Xiu Song Zhao.  (2025)  Revealing the relationship between Cu valence and product selectivity in CO2 electrolysis.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:40517497] [10.1016/j.jcis.2025.138189]

103. Jinyun Liu, Jiamin Liu, Ting Zhou, Xiaofei Huang, Yajun Zhu, Haojun Xu, Tianli Han.  (2025)  High-Performance Magnesium/Lithium Hybrid-Ion Battery Using NiS2 Nanosheet-Coated Cu2S Cubes as a Cathode Material.  ACS Applied Materials & Interfaces,      [PMID:40526110] [10.1021/acsami.5c06737]

104. Meng Wu, Junhao Li, Yougui Yang, Ling He, Kunpeng Shi, Cang Zhang, Qi Wang, Yong Yang, Chunjian Wang, Dacheng Zhou, Jianbei Qiu.  (2025)  Cu+ doping for tuning optical and nonlinear optical properties of multinary sulfide quantum dot glass.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2025.11.023]

105. Jiawei Lu, Liyuan Chai, Xiaobo Min, Yong Ke, Yun Li, Yunyan Wang, Xin Wang, Yiming Liu, Cong Peng.  (2025)  Lowering melting temperatures of high zinc slag derived from co-smelting of primary ores and secondary resources: Regulation method and mechanisms.  JOURNAL OF ALLOYS AND COMPOUNDS,      [PMID:] [10.1016/j.jallcom.2025.185594]

106. Yinying Wang, Qu Zhang, Tao Wang, Yafen Zheng, Dongling Wu.  (2025)  Construction of Cu2O@CuO Sea-Urchin-Like Heterojunction Materials for Enhancing Zinc Storage.  Small,      [PMID:41392776] [10.1002/smll.202513050]

107. Shida Gong, Xinguang Wu, Shiying Li, Yajun Ding, Zhongliang Xiao.  (2025)  Hollow Cu2O/CuO nanocomposites via hydrothermal synthesis toward enhancing the thermal decomposition of energetic molecular perovskite.  CHEMICAL PHYSICS LETTERS,      [PMID:] [10.1016/j.cplett.2025.142506]

108. Xinxian Dai, Lei Jiang, Jiyong Zheng, Tao Yuan, Hui Huang, Xiaolin Lu.  (2026)  Safer Solutions for Sea: Montipora capricornis Coral Responses to Naturally-Derived Versus Copper-Based Antifouling Agents.  ENVIRONMENTAL POLLUTION,      [PMID:41506610] [10.1016/j.envpol.2026.127635]

109. Jiawei Lu, Liyuan Chai, Xiaobo Min, Yunyan Wang, Hui Xu, Yun Li, Yong Ke, Cong Peng.  (2026)  Kinetics and Mechanisms of Microscale Interfacial Reactions and Structural Evolution during ZnO Dissolution in Multicomponent Oxide Melts.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2026.01.311]

110. Zijun Yi, Long Zhang, Asif Al Jaman, Hui Li, Fang Ding, Yingjie Cai, Xuehong Ren.  (2026)  Environmentally friendly Cu2SnS3 absorber with titanium (IV) cation regulation enabling power conversion efficiency over 6 % in photovoltaic applications.  JOURNAL OF ALLOYS AND COMPOUNDS,      [PMID:] [10.1016/j.jallcom.2026.186689]

111. Jinzhe Liang, Xianliu Luo, Ya-Qian Shi, Liang-Mei Yang, Caiying Li, Lixian Huang, Yuzhen Ma, Yong Huang, Shulin Zhao.  (2026)  H2S-Activable BiFeO3–x Nanocatalysts for Ferroptosis-Driven Cancer Immunotherapy.  ACS Nano,      [PMID:41622764] [10.1021/acsnano.5c18008]

112. Shu Yuan, Lizhen Wu, Rongyi Wang, Rui Xue, Fangyuan Li, Huiyuan Li, Guiru Zhang, Peng Shen, Zhiming Bao, Congfan Zhao, Qing Wang, Jiewei Yin, Liuxuan Luo, Shuiyun Shen, Liang An, Xiaohui Yan, Junliang Zhang.  (2026)  Breaking the transport limit of the rib-channel flow field to enable amp-level CO2 electrolysis and high-purity CO output.  Joule,      [PMID:] [10.1016/j.joule.2026.102357]