Pentylmagnesium bromide solution - 2.0M in diethyl ether , CAS No.693-25-4

CAS: 693-25-4 Cat. No.: P466408 Fórmula: C₅H₁₁BrMg Peso molecular: 175.35 Número EC: 211-747-9 PubChem CID: 101838

GRADE & PURITY 2.0M in diethyl ether

Synonyms

amyl magnesium bromide | Amylmagnesium bromide | amyl-magnesium bromide | n-Pentyl magnesium bromide | ZXWGTPYWPZGZPT-UHFFFAOYSA-M | AKOS015902926 | Bromopentylmagnesium | pentylmagnesiumbromide | DTXSID20883478 | Pentylmagnesium bromide, 1.0 M in THF | P

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Descripción general

Description

Pentylmagnesium bromide solution is a Grignard reagent that can be used in the preparation of:Alkanes via Ni or Cu-catalyzed cross-coupling reaction with alkyl fluorides.Hydroxypiperidinones via the addition-cyclization-deprotection process of aldimines.It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine , and surface alkylation of H-terminated Si (111), by Si-C bond formation.

Specifications

Sinónimos

amyl magnesium bromide | Amylmagnesium bromide | amyl-magnesium bromide | n-Pentyl magnesium bromide | ZXWGTPYWPZGZPT-UHFFFAOYSA-M | AKOS015902926 | Bromopentylmagnesium | pentylmagnesiumbromide | DTXSID20883478 | Pentylmagnesium bromide, 1.0 M in THF | P

Especificaciones y pureza

2.0M in diethyl ether

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C,Argon charged

Enviado en

Wet ice

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Nombres e identificadores

Pubchem Sid

508813546

Sonrisas canónicas

CCCC[CH2-].[Mg+2].[Br-]

IUPAC Name

magnesium;pentane;bromide

InChIKey

XWCQLLDGXBLGMD-UHFFFAOYSA-M

INCHI

1S/C5H11.BrH.Mg/c1-3-5-4-2;;/h1,3-5H2,2H3;1H;/q-1;;+2/p-1

Isómeros SMILES

CCCC[CH2-].[Mg+2].[Br-]

WGK Alemania

1

PubChem CID

101838

Peso molecular

175.35

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic salts
    • Clase Organic metal salts
      • Subclass Organic metal halides

• Kingdom: Organic compounds
• Superclass: Organic salts
• Clase: Organic metal salts
• Subclass: Organic metal halides
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic metal halides
• Alternative Parents: Organic metal bromide salts Organic bromide salts Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Organic metal halide - Organic metal bromide salt - Hydrocarbon derivative - Organic bromide salt - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as organic metal halides. These are organic compounds containing metals and halogens. Some are ionic while others are covalently bonded.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Sensibilidad: Air & Moisture sensitive
• Punto de inflamación (°F): -40 °C
• Punto de inflamación (°C): -40°C
• Peso molecular: 175.350 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 173.989 Da
• Monoisotopic Mass: 173.989 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 7
• Formal Charge: 0
• Complexity: 17.600
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 3

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