Chloranil, Tetrachloro-1,4-benzoquinone
Chloranil, and the parent benzoquinone, are relatively mild oxidants (dehydrogenation reagents).
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Chloranil, and the parent benzoquinone, are relatively mild oxidants (dehydrogenation reagents).
Chloramine-T is a source of electrophilic chlorine. In water, chloramine-T is decomposed to yield hypochlorite, which acts as a disinfectant, and the sulfonamide moiety, which inhibits bacterial grow due to the similarity with para-aminobenzoic acid (a bacterial metabolite). Chloramine-T can ...
NHC-trihydroboranes are white solids that are stable to air, water, and even chromatography. However, 1,3-dimethylimidazol-2-ylidene borane is a surprisingly good hydride donor that is comparable to anionic reagents such as NaCNBH3. The reagent can be used for reductive amination procedures and ...
Diethylsilane
The use of chloramine-B as the oxidant and KI or NaBr as the halogen source enables a direct oxidative halogenation of terminal alkynes to provide synthetically valuable 1-iodoalkynes and 1-bromoalkynes in very good yields under mild reaction conditions.
Dextrans are polysaccharides with molecular weights starting at 1,000 Daltons, consisting of a linear backbone of α-linked D-glucopyranosyl units. Their unique structural properties and versatility make them essential in various biological and medical research applications.
Fluorescein isothiocyanate (FITC) is a green fluorescent dye widely used in biological labeling and imaging techniques. Polysaccharides are important biological macromolecules involved in various biological processes and functions. By labeling polysaccharides with FITC, their visualization and ...
DIBAL-H, Diisobutylaluminium hydride
Cerium (IV) ammonium nitrate ((NH4)2Ce(NO3)6) is a one-electron oxidizing agent that is used for oxidative addition reactions of electrophilic radicals to alkenes, enabling intermolecular and intramolecular carbon-carbon and carbon-heteroatom bond formation. CAN also oxidizes secondary alcohols ...