1,700+ technical articles by Aladdin Scientific's scientists on reagent selection, reaction mechanisms, assay design and formulation. New every week.
The reaction of tert-butyl peroxybenzoate (TBPB) and ammonia/amines provides the corresponding primary, secondary, and tertiary amides under catalyst- and solvent-free conditions in excellent yields. TBPB is an efficient and highly chemoselective benzoylating reagent for aliphatic amines in the ...
In recent years, the global demand for lithium salts has surged significantly, primarily driven by the rapid expansion of the lithium-ion battery (LIB) market, particularly for the automotive industry. Among the key lithium compounds traded globally, lithium carbonate (Li2CO3) and lithium ...
Lithium batteries stand as one of the paramount electrochemical energy storage systems in contemporary use. Their exceptional energy density and sizable storage capacity have propelled their swift adoption in portable electronics and diverse industrial applications, culminating in their ...
The quest for innovative and effective techniques to produce sulfonyl fluorides is of significant interest due to their extensive applications across various fields. Sulfur(VI) fluoride exchange (SuFEx) click chemistry has recently gained prominence as one of the leading methods in this domain. ...
The use of tert-butyl nitrite as the co-catalyst in a 2-azaadamantane-N-oxyl(AZADO)- and 9-azanoradamantane-N-oxyl(nor-AZADO)-catalyzed efficient aerobic oxidation of primary alcohols in MeCN instead of the previously reported AcOH provides the corresponding aldehydes selectively. The addition ...
Plant genetic transformation technology, also called plant transgenic technology, is a key technique in modern biotechnology. It can improve plant genetic characteristics by introducing foreign genes into the plant genome. This article focuses on agrobacterium mediated method the efficiency and ...
Various aromatic, aliphatic and conjugated alcohols were transformed into the corresponding carboxylic acids and ketones in good yields with aq 70% t-BuOOH in the presence of catalytic amounts of bismuth(III) oxide. This method possesses does not involve cumbersome work-up, exhibits ...
A range of unsymmetrical ketones has been prepared in good yields from aldehydes in one simple synthetic operation by addition of organolithium compounds followed by an oxidation using N-tert-butylphenylsulfinimidoyl chloride.
1,4-Cyclohexadiene can act as hydrogen atom donor due to aromatization as driving force.
