Indium(III) bromide - ≥99.9% metals basis , CAS No.13465-09-3

CAS: 13465-09-3 Cat. No.: I302449 Molecular Weight: 354.53 EC Number: 236-692-8 PubChem CID: 26046

GRADE & PURITY ≥99.9% metals basis

Synonyms

Q4096881 | AKOS040765860 | Indium tribromide | DTXSID5065485 | Indium(III) bromide, 99% | EINECS 236-692-8 | tribromoindium | Indium (III) bromide | InBr3 | Indium bromide (InBr3) | UNII-0099V88160 | Indium(III) bromide, anhydrous | Indium(III) bromide, 9

Storage

Room temperature,Argon charged,Desiccated

Shipped In

Normal

Overview

Indium(III) bromide is used in organic synthesis as a water tolerant Lewis acid.It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones. It is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells."

Specifications

Synonyms

Q4096881 | AKOS040765860 | Indium tribromide | DTXSID5065485 | Indium(III) bromide, 99% | EINECS 236-692-8 | tribromoindium | Indium (III) bromide | InBr3 | Indium bromide (InBr3) | UNII-0099V88160 | Indium(III) bromide, anhydrous | Indium(III) bromide, 9

Specifications & Purity

≥99.9% metals basis

Storage

Room temperature, Argon charged, Desiccated

Shipped In

Normal

Purity

≥99.9% metals basis

Names and Identifiers

• Canonical Smiles: Br[In](Br)Br
• IUPAC Name: tribromoindigane
• InChIKey: JKNHZOAONLKYQL-UHFFFAOYSA-K
• INCHI: 1S/3BrH.In/h3*1H;/q;;;+3/p-3
• Isomeric SMILES: Br[In](Br)Br
• WGK Germany: 3
• PubChem CID: 26046
• Molecular Weight: 354.53

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Class Post-transition metal salts
      • Subclass Post-transition metal bromides

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Class: Post-transition metal salts
• Subclass: Post-transition metal bromides
• Intermediate Tree Nodes: Not available
• Direct Parent: Post-transition metal bromides
• Alternative Parents: Inorganic salts
• Molecular Framework: Not available
• Substituents: Post-transition metal bromide - Inorganic salt
• Description: This compound belongs to the class of inorganic compounds known as post-transition metal bromides. These are inorganic compounds in which the largest halogen atom is Bromine, and the heaviest metal atom a post-transition metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Soluble in water.
• Sensitivity: Moisture sensitive
• Boil Point(°C): 656°C (Lit.)
• Melt Point(°C): 436 °C (lit.)
• Molecular Weight: 354.530 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 353.657 Da
• Monoisotopic Mass: 351.659 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 4
• Formal Charge: 0
• Complexity: 8.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

References

1. Dong-Yang Li, Yan-Bing Shang, Qi Liu, Hua-Wu Zhang, Xin-Yue Zhang, Cheng-Yang Yue, Xiao-Wu Lei.  (2023)  0D hybrid indium halide as a highly efficient X-ray scintillation and ultra-sensitive fluorescent probe.  Materials Horizons,  10  (11): (5004-5015).  [PMID:37642515] [10.1039/D3MH00536D]

2. Keqiang Chen, Zixin Gu, Zhiqing Wang, Mengyu Guan, Xiu Tan, Wanqing Xu, Xinyu Ji, Weiqi Lu, Yueli Liu, Guogang Li.  (2023)  Surface polarization-induced emission and stability enhancement of CsPbX3 nanocrystals.  Chemical Science,  14  (33): (8914-8923).  [PMID:37621427] [10.1039/D3SC02109B]

3. An Hou, Liubing Fan, Yan Xiong, Jiawei Lin, Kunjie Liu, Mingyue Chen, Zhongnan Guo, Jing Zhao, Quanlin Liu.  (2023)  Zero-Dimensional Halides with ns2 Electron (Sb3+) Activation to Generate Broad Photoluminescence.  INORGANIC CHEMISTRY,      [PMID:37478468] [10.1021/acs.inorgchem.3c01726]

4. Hui Wang, Chao Wang, Yanan Wang, Mengjiao Sun, Guangjiu Zhao.  (2023)  Efficient White Light Emission of 0D Lead-Free Indium-Based Halide Perovskite and the Intermediate State Promotion Mechanism of the Nonadiabatic Transition to Self-Trapped Exciton via Antimony(III) Cation Doping.  Journal of Physical Chemistry C,      [PMID:] [10.1021/acs.jpcc.3c01988]

5. Fan Chen, Xiao-Jun Wang, Xuehu Zhang, Changhua Zhang.  (2023)  Near room temperature synthesis of Cs2InCl5-xBrx·H2O (x = 0–5) perovskites with tunable yellow to red emissions.  JOURNAL OF LUMINESCENCE,      [PMID:] [10.1016/j.jlumin.2023.119938]

6. Fei Zhang, Xinzhen Ji, Wenqing Liang, Ying Li, Zhuangzhuang Ma, Meng Wang, Yue Wang, Di Wu, Xu Chen, Dongwen Yang, Xinjian Li, Chongxin Shan, Zhifeng Shi.  (2021)  Room-temperature synthesis of blue-emissive zero-dimensional cesium indium halide quantum dots for temperature-stable down-conversion white light-emitting diodes with a half-lifetime of 186 h.  Materials Horizons,  8  (12): (3432-3442).  [PMID:34700333] [10.1039/D1MH01370J]

7. Hang Ruan, Zhongnan Guo, Jiawei Lin, Kunjie Liu, Lingling Guo, Xin Chen, Jing Zhao, Quanlin Liu, Wenxia Yuan.  (2021)  Structure and Optical Properties of Hybrid-Layered-Double Perovskites (C8H20N2)2AgMBr8 (M = In, Sb, and Bi).  INORGANIC CHEMISTRY,      [PMID:34523334] [10.1021/acs.inorgchem.1c01669]

8. Jinyuan Zhang, Huaimin Gu.  (2020)  Growth of InZnP/ZnS core/shell quantum dots with wide-range and refined tunable photoluminescence wavelengths.  DALTON TRANSACTIONS,  49  (18): (6119-6126).  [PMID:32323683] [10.1039/D0DT00575D]

9. Da Chen, Shiqiang Hao, Guojun Zhou, Chenkai Deng, Quanlin Liu, Shulan Ma, Christopher Wolverton, Jing Zhao, Zhiguo Xia.  (2019)  Lead-Free Broadband Orange-Emitting Zero-Dimensional Hybrid (PMA)3InBr6 with Direct Band Gap.  INORGANIC CHEMISTRY,      [PMID:31652051] [10.1021/acs.inorgchem.9b02669]

10. Chunqing Hou, Xiaoting Liu, Zisheng Wang, Fan Yu, Bowen Jin, Yang Yang, Yilong Song, Qingfeng Dong.  (2024)  Designing guanidine-based lead-free hybrid indium perovskites with highly efficient intrinsic broadband emissions.  Journal of Materials Chemistry C,  12  (20): (7426-7434).  [PMID:] [10.1039/D4TC00482E]

11. Kai-Zheng Song, Jin-Zhao Huang, Meng-Xin Li, Feng-Lei Jiang.  (2024)  Full Color Al-Doped InP Quantum Dots with High Brightness via Gram-Scale One-Pot Synthesis for White Light-Emitting Diodes.  ACS Applied Materials & Interfaces,      [PMID:39726272] [10.1021/acsami.4c16513]

12. Naiwei Wei, Hong Zhu, Danni Yan, Shuai Yang, Lili Xu, Shengli Zhang, Yuhui Dong, Yousheng Zou, Haibo Zeng.  (2024)  Reactivity-matched synthesis of monodisperse Ag(In,Ga)S2 QDs with efficient luminescence.  Nanoscale,  16  (28): (13654-13662).  [PMID:38963285] [10.1039/D4NR00804A]

13. Huan Tian, Feng-Lei Jiang.  (2026)  Stabilizing CsPbBr3 Nanocrystals by Cotreatment with Inorganic and Organic Ligands.  ACS Applied Nano Materials,      [PMID:] [10.1021/acsanm.5c05019]

14. Bo Wang, Jingrui Zhang, Liangyi Gu, Jiahong Li, Jian Wang, Limin Zhang, Yuxiao Wu, Xiaoshuang Li.  (2026)  Regulating A-Site Alloying of Cs2-xRbxInBr5·H2O Perovskites for NIR LED Applications.  ACS Applied Optical Materials,      [PMID:] [10.1021/acsaom.5c00678]