9-Phenanthrylmagnesium bromide - 0.5M in THF , CAS No.71112-64-6

CAS: 71112-64-6 Cat. No.: P465978 Fórmula: C₁₄H₉BrMg Peso molecular: 281.43 PubChem CID: 12396678

GRADE & PURITY 0.5M in THF

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Visão geral

Description

9-phenanthrylmagnesium bromide is a Grignard reagent. It can be prepared using magnesium turnings and 9-bromophenanthrene under anhydrous condition.9-Phenanthrylmagnesium bromide can be used as a reagent to prepare:9-alkyl and 9-arylthiophenanthrenes by reacting with alkyl or aryl thiol compounds.(S)-α-methylbenzyl 1-(9-phenanthryl)-2-naphthoate by treating with (S)- α -methylbenzyl methoxy-2-naphthoate.1-(9-Phenanthryl)-1-phenylethanol (carbinol) by reacting with acetophenone. The obtained carbinol undergoes dehydration reaction in the presence of acetic acid and sulfuric acid to afford 1-(9-phenanthryl)-1-phenylethene (PPE).

Specifications

Especificações e pureza

0.5M in THF

Condições de armazenamento de armazenamento

Store at 2-8°C,Argon charged

Enviado em

Wet ice

Este produto requer transporte de cadeia fria. Serviços terrestres e outros serviços econômicos não estão disponíveis.

Nomes e identificadores

Sorrisos canónicos

C1=CC=C2C(=C1)C=[C-]C3=CC=CC=C32.[Mg+2].[Br-]

IUPAC Name

magnesium;9H-phenanthren-9-ide;bromide

InChIKey

RQYSGLNTEAQBIV-UHFFFAOYSA-M

INCHI

1S/C14H9.BrH.Mg/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13;;/h1-9H;1H;/q-1;;+2/p-1

SMILES isoméricas

C1=CC=C2C(=C1)C=[C-]C3=CC=CC=C32.[Mg+2].[Br-]

PubChem CID

12396678

Número UN

2924

Peso molecular

281.43

Propriedades químicas e físicas

• Solubilidade: It reacts with water.
• Sensibilidade: Moisture sensitive; Air sensitive
• Ponto de inflamação (°F): Not applicable
• Ponto de inflamação (°C): Not applicable
• Ponto de ebulição (°C): 65℃ (lit.)

Perguntas frequentes

How should this product be stored?

Store at 2–8 °C under argon. It is supplied under an argon blanket; reseal under inert gas after each use.

How is this product shipped?

This product ships chilled on wet ice. Unpack on arrival and transfer it to the storage condition stated above.

What are the CAS number, molecular formula and molecular weight?

The CAS Number is 71112-64-6, the molecular formula is C14H9BrMg, and the molecular weight is 281.43 g/mol. InChIKey RQYSGLNTEAQBIV-UHFFFAOYSA-M.

What documentation is provided?

Available product documentation, including Certificates of Analysis (COA), Safety Data Sheets (SDS), and specification sheets, is shown in the product document area. Document availability and access follow the current site policy.