Tiocianato de chumbo(II) - ≥98% , CAS No.592-87-0

CAS: 592-87-0 Cat. No.: L304085 Fórmula: Pb(SCN)₂ Peso molecular: 323.36 Número CE: 209-774-6

GRADE & PURITY ≥98%

Synonyms

Ácido isotiociânico, sal de chumbo(2+) | TIOCIANATO DE CHUMBO [MI] | SCHEMBL107555 | Isotiocianato de chumbo | SCHEMBL1274475 | HSDB 641 | EINECS 209-774-6 | SCHEMBL42006 | Ácido tiociânico, sal de chumbo(2+) | Tiocianato de chumbo (Pb(SCN)2) | Ditiociana

Storage

Temperatura ambiente, carregado com árgon, dessecado

Shipped In

Normal

Visão geral

Aplicação do produto：

O tiocianato de chumbo (II) pode ser usado: Para formar um complexo com o éter de coroa de lariat de Schiff-base, N, N′-bis (3- (salicilaldimino) benzil) -4,13-diaza-18-crown-6

Investigar as propriedades de complexação e fluorescência do calixareno com dois fluoróforos dansil enxertados num material de sílica mesoporosa de poros grandes.

Como reagente na 1,2-ditiocianação de alcinos na presença de (dicloroiodo)benzeno

Como precursor para sintetizar películas de perovskite para aplicações em células solares.

Specifications

Sinónimos

Ácido isotiociânico, sal de chumbo(2+) | TIOCIANATO DE CHUMBO [MI] | SCHEMBL107555 | Isotiocianato de chumbo | SCHEMBL1274475 | HSDB 641 | EINECS 209-774-6 | SCHEMBL42006 | Ácido tiociânico, sal de chumbo(2+) | Tiocianato de chumbo (Pb(SCN)2) | Ditiociana

Especificações e pureza

≥98%

Condições de armazenamento de armazenamento

Temperatura ambiente, carregado com árgon, dessecado

Enviado em

Normal

Pureza

≥98%

Nomes e identificadores

• Pubchem Sid: 488181397
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488181397
• Sorrisos canónicos: C(#N)[S-].C(#N)[S-].[Pb+2]
• IUPAC Name: lead(2+);dithiocyanate
• InChIKey: VRNINGUKUJWZTH-UHFFFAOYSA-L
• INCHI: 1S/2CHNS.Pb/c2*2-1-3;/h2*3H;/q;;+2/p-2
• SMILES isoméricas: C(#N)[S-].C(#N)[S-].[Pb+2]
• WGK Alemanha: 3
• Número UN: 2291
• Grupo de embalagem: III
• Peso molecular: 323.36
• Reaxy-Rn: 5423743
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=5423743&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organosulfur compounds
    • Classe Thiocyanates
      • Subclass Metal thiocyanates

• Kingdom: Organic compounds
• Superclass: Organosulfur compounds
• Classe: Thiocyanates
• Subclass: Metal thiocyanates
• Intermediate Tree Nodes: Not available
• Direct Parent: Metal thiocyanates
• Alternative Parents: Organopnictogen compounds Organonitrogen compounds Organic lead salts Hydrocarbon derivatives
• Molecular Framework: Not available
• Substituents: Metal thiocyanate - Organic nitrogen compound - Organopnictogen compound - Hydrocarbon derivative - Organic lead salt - Organic salt - Organonitrogen compound - Aliphatic acyclic compound
• Descrição: This compound belongs to the class of organic compounds known as metal thiocyanates. These are metal salts of thiocyanic acid.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propriedades químicas e físicas

• Solubilidade: cold water: soluble 200 part(lit.) water: soluble 50 part (boiling)(lit.)
• Sensibilidade: Hygroscopic
• Ponto de fusão (°C): 190 °C (dec.) (lit.)
• Peso molecular: 323.000 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 323.927 Da
• Monoisotopic Mass: 323.927 Da
• Topological Polar Surface Area: 49.600 Ų
• Heavy Atom Count: 7
• Formal Charge: 0
• Complexity: 31.300
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 3

XLogP3

Referências

1. Meidan Que, Boyue Zhang, Jin Chen, Hao Yuan, Qizhao Wu, Huayan Wang, Dongyun Gui, Bo Li.  (2023)  Dual Ions Passivating FAPbBr3 Perovskite Quantum Dot Films via a Vacuum Drying Method for Stable and Efficient Solar Cells with an Ultrahigh Open-Circuit Voltage of over 1.67 V.  ACS Applied Energy Materials,      [PMID:] [10.1021/acsaem.3c00009]

2. Li Hong, Zaiwei Wang, Jovana V. Milić, Claudia E. Avalos, Weihua Zhang, Dan Ren, Cheng Wang, Brian Carlsen, Yuhang Liu, Shaik Mohammed Zakeeruddin, Anders Hagfeldt, Ti Wang, Hongwei Han, Michael Graetzel.  (2022)  Thiocyanate-Mediated Dimensionality Transformation of Low-Dimensional Perovskites for Photovoltaics.  CHEMISTRY OF MATERIALS,      [PMID:] [10.1021/acs.chemmater.2c00760]

3. Meidan Que, Shenghui He, Lili Gao, Boyue Zhang, Yabo Wang, Jin Chen, Bo Li, Wei Huang, Peng Zhong.  (2024)  Dual-anchored configuration involving Pb(NO3)2 for effective and stable FAPbI3 quantum dot solar cells.  Journal of Materials Chemistry C,  12  (45): (18391-18400).  [PMID:] [10.1039/D4TC02697G]

4. Siyu Li, Feng Liu, Dayang Wang, Keke Huang, Wensheng Yang, Renguo Xie.  (2025)  Precise Control of Halogen Distribution in Monolayer Hybrid Perovskites through Mechanochemistry.  Journal of Physical Chemistry C,      [PMID:] [10.1021/acs.jpcc.4c08389]

5. Liu Jianbo, Zhang Meng, Sun Xiaoran, Xiang Linhu, Yang Xiangyu, Hu Xin, Wang Zhicheng, Hou Tian, Qin Jinzhao, Huang Yuelong, Abdi-Jalebi Mojtaba, Hao Xiaojing.  (2025)  Scalable Fabrication of Methylammonium-Free Wide-Bandgap Perovskite Solar Cells by Blade Coating in Ambient Air.  Nano-Micro Letters,  17  (1): (1-11).  [PMID:40591204] [10.1007/s40820-025-01838-6]

6. Yue Zhao, Shujie Jiao, Song Yang, Yiyin Nie, Yajie Han, Junjie He, Chenyang Tao, Dongbo Wang, Shiyong Gao, Jinzhong Wang, Liancheng Zhao.  (2024)  High-Performance All-Inorganic Perovskite Tandem Photodetectors With Bi2TeO6 Layer Enabled by Enhanced Dual Pyro-Phototronic Effect for Triple-Encryption Imaging Sensing System with Programmable Logic Gate.  ADVANCED MATERIALS,      [PMID:39648596] [10.1002/adma.202414649]

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