Vanadium(III) chloride - ≥96% , CAS No.7718-98-1

CAS: 7718-98-1 Cat. No.: V498277 Molecular Weight: 157.30 EC Number: 231-744-6 PubChem CID: 62647

GRADE & PURITY ≥96%

Synonyms

Vanadium trichloride

Storage

Room temperature,Argon charged

Shipped In

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Overview

Vanadium(III) chloride is a crystalline solid with variable oxidation states. It is widely used as a catalyst in organic synthesis, polymerization processes, and redox batteries. It acts as a reducing agent. 

Application：

Vanadium chloride may be used as a reduction agent to determine nitrates and nitrites in water samples.It may be used in redox flow batteries. Vanadium trichloride catalyses Pinacol coupling reactions of benzaldehyde in water. it also acts as a mild and efficient catalyst for the chemoselective deprotection of acetonides

Specifications

Synonyms

Vanadium trichloride

Specifications & Purity

≥96%

Storage

Room temperature, Argon charged

Shipped In

FedEx DG Service

Purity

≥96%

Names and Identifiers

• Pubchem Sid: 488183594
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488183594
• Canonical Smiles: Cl[V](Cl)Cl
• IUPAC Name: trichlorovanadium
• InChIKey: HQYCOEXWFMFWLR-UHFFFAOYSA-K
• INCHI: 1S/3ClH.V/h3*1H;/q;;;+3/p-3
• Isomeric SMILES: Cl[V](Cl)Cl
• PubChem CID: 62647
• UN Number: 2475
• Packing Group: III
• Molecular Weight: 157.30

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Class Transition metal salts
      • Subclass Transition metal chlorides

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Class: Transition metal salts
• Subclass: Transition metal chlorides
• Intermediate Tree Nodes: Not available
• Direct Parent: Transition metal chlorides
• Alternative Parents: Inorganic chloride salts
• Molecular Framework: Not available
• Substituents: Transition metal chloride - Inorganic chloride salt - Inorganic salt
• Description: This compound belongs to the class of inorganic compounds known as transition metal chlorides. These are inorganic compounds in which the largest halogen atom is Chlorine, and the heaviest metal atom is a transition metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Soluble in tetrahydrofuran, alcohol, ether and hydrocarbons.
• Sensitivity: Sensitive to light and humidity
• Melt Point(°C): 250 °C
• Molecular Weight: 157.300 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 155.851 Da
• Monoisotopic Mass: 155.851 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 4
• Formal Charge: 0
• Complexity: 8.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

References

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63. Tao Wei, Mengting Wang, Yanyan Zhou, Xingtong Guo, Sijia Wang, Ye Liu, Cheng Sun, Qian Wang.  (2024)  V-MOF-derived V2O5 nanoparticles-modified carbon fiber cloth-based dendrite-free anode for high-performance lithium metal batteries.  CHINESE JOURNAL OF CHEMICAL ENGINEERING,      [PMID:] [10.1016/j.cjche.2024.02.014]

64. Qingyan Yuan, Yunjia Wu, Zelin Wu, Jian Zhang, Zeyu Zhao, Qing Yin, Jingbin Han.  (2025)  Unlocking the critical role of sulfur doping in NiVFe layered double hydroxide cathode with enhanced reaction kinetics for chloride ion batteries.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:40997570] [10.1016/j.jcis.2025.139065]

65. Hui Yang, Xiankun Su, Li Cai, Zhenchun Sun, Yechun Lin, Jing Yu, Likai Hao, Cui Liu.  (2022)  Glutathione assisting the waste tobacco leaf to synthesize versatile biomass-based carbon dots for simultaneous detection and efficient removal of mercury ions.  Journal of Environmental Chemical Engineering,      [PMID:] [10.1016/j.jece.2022.108718]

66. Hui Yang, Yunlong Wei, Xiufang Yan, Chao Nie, Zhenchun Sun, Likai Hao, Xiankun Su.  (2022)  High-Efficiency Utilization of Waste Tobacco Stems to Synthesize Novel Biomass-Based Carbon Dots for Precise Detection of Tetracycline Antibiotic Residues.  Nanomaterials,  12  (18): (3241).  [PMID:36145029] [10.3390/nano12183241]

67. Miaojing Pan, Wei Chen, Guangfu Qian, Tianqi Yu, Zhenglin Wang, Lin Luo, Shibin Yin.  (2022)  Carbon-encapsulated Co3V decorated Co2VO4 nanosheets for enhanced urea oxidation and hydrogen evolution reaction.  ELECTROCHIMICA ACTA,      [PMID:] [10.1016/j.electacta.2022.139882]

68. Hongchao Shi, Huihui Wang, Xia Cui, Ziang Gao, Jiao Jia, Haifeng Xu.  (2024)  Highly conductive titanium nitride core sterically reinforced nickel-vanadium layered double hydroxides for supercapacitors.  JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,      [PMID:] [10.1016/j.jpcs.2024.112099]

69. Yuanjie Wei, Jing Liang, Xinyu Zhang, Hehe Ren, Xinzhan Du, Qiang Fu, Wei Wu.  (2025)  Metal oxides/sulfides/walnut septum biochar-based printed electrode for high area/volumetric energy density flexible asymmetric supercapacitors.  Journal of Energy Storage,      [PMID:] [10.1016/j.est.2025.116267]

70. Li Suiqin, Wang Shibin, Wang Yuhang, He Jiahui, Li Kai, Gerken James B., Stahl Shannon S., Zhong Xing, Wang Jianguo.  (2025)  Synergistic enhancement of electrochemical alcohol oxidation by combining NiV-layered double hydroxide with an aminoxyl radical.  Nature Communications,  16  (1): (1-14).  [PMID:39747151] [10.1038/s41467-024-55616-w]

71. Jingyan Duan, Xinru Zhao, Zhongge Luo, Huachuan Sun, Mingpeng Chen, Qingjie Lu, Boxue Wang, Bin Xiao, Tong Zhou, Dequan Li, Hao Cui, Tianwei He, Qingju Liu.  (2025)  Enhancing water dissociation kinetics via vanadium-doped nickel oxide/ruthenium heterostructures for efficient hydrogen production at ampere-level current density.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2025.126271]

72. Chen Peng, Wang Yan, Cai Wangfeng.  (2025)  Directly anchored vanadium-based flower-like composite on nickel foam: enhancing surface area and stability for improved supercapacitor performance.  IONICS,      [PMID:] [10.1007/s11581-025-06296-z]

73. Liu Yu-Kun, Pang Yu-Chen, Li Chao-Qun, Zhang Xiao-Yue, Hu Xue-Chun, Chen Wei, Yu Xue-Bin, Xia Guang-Lin.  (2025)  Amorphous VB2 nanoparticles for stable hydrogen storage of 2LiBH4–MgH2.  RARE METALS,      [PMID:] [10.1007/s12598-025-03327-6]

74. ZiHan Yang, ZhongKe Luo, Chao Wang.  (2025)  Preparation of NiCoFeMnCrV high entropy alloy and its efficient electrocatalytic performance in water splitting.  JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,      [PMID:] [10.1016/j.jpcs.2025.112846]

75. Wu Han, Fu Zhanzhao, Chang Jiangwei, Hu Zhiang, Li Jian, Wang Siyang, Yu Jingkun, Yong Xue, Waterhouse Geoffrey I. N., Tang Zhiyong, Chang Junbiao, Lu Siyu.  (2025)  Engineering high-density microcrystalline boundary with V-doped RuO2 for high-performance oxygen evolution in acid.  Nature Communications,  16  (1): (1-12).  [PMID:40368887] [10.1038/s41467-025-59472-0]

76. Zheheng Jiang, Wei Liu, Muzammil Hussain, Hao Sun, Yun Kuang, Yaping Li, Wen Liu, Daojin Zhou, Xiaoming Sun.  (2025)  Ir–Co3S4/CoOxHy Heterojunction Enables Efficient Alkaline Oxygen Evolution through Binuclear Ir–Co Active Sites.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.5c00603]

77. Jing Wei, Jianxin Fu, Abdul Qayum.  (2025)  In-Situ Combustion Derived Micbirneyite-Photoanode Films for Enhanced Photoelectrochemical Water Splitting Efficiency.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2025.138773]

78. Liu Yang, Jiaqi Nie, Jiqing Zhang, Haihui Wu, Xiaohui Guan, Song Han, Liwen Wang, Penggang Yin, Tao Zou, Hongfan Huang.  (2025)  Electron structure regulation via Co, in, Zn, and V in-situ substitution for high-quality cathode design of aqueous zinc-ion batteries.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:] [10.1016/j.jcis.2025.139323]

79. Wendi Wang, Jianxin Wang, Danfeng He, Xin Huang, Yutong Yang, Xi Chen, Lijie Zhao, Hong Pan, Jun Zhang.  (2025)  Thiophene bridged Ni-V units in bimetallic hydroxides electrodes to improve the cycling stability of supercapacitor.  JOURNAL OF ALLOYS AND COMPOUNDS,      [PMID:] [10.1016/j.jallcom.2025.184957]

80. Qingqing Liu, Liyun Cao, Koji Kajiyoshi, Dewei Chu, Yijun Liu, Yong Zhao, Jianfeng Huang, Liangliang Feng.  (2025)  Heterogeneous VN/MoP Nanoparticles Embedded in a Nitrogen-Doped Carbon Framework Achieve Efficient Electrocatalytic Hydrogen Evolution.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.5c08556]

81. Jianzhang Wang, Yingxia Wu, Jian Zhang, Shengli Wang, Hongliang Wang.  (2025)  A Traveling Multi-Analyte Chemosensor Based on Wet-Chemical Colorimetry for Shipboard Seawater Analysis.  Applied Sciences-Basel,  15  (24): (12861).  [PMID:] [10.3390/app152412861]

82. Wenxuan Zheng, Lin Gao, Mingsong Fan, Zhiyu Dou, Lili Cui, E. Jin.  (2025)  Dandelion-like V–CoP nanoarchitectures derived from MOFs: boosting the HER via enhanced water dissociation at industrial current densities.  Inorganic Chemistry Frontiers,      [PMID:] [10.1039/D5QI01758K]

83. Qiudi Mao, Zhishan Li, Qiangli Lv, Haoran Guo, Qiming Sun, Hua Wang, Kongzhai Li.  (2025)  Fe3 + -preactivated nickel-vanadium layered double hydroxide for boosting oxygen evolution reaction.  JOURNAL OF ALLOYS AND COMPOUNDS,      [PMID:] [10.1016/j.jallcom.2025.185820]

84. Naixin Zhai, Zihao Wang, Zhenzhi Cheng, Zhihao Xu, Keke Guo, Weiping Zhou, Fei Gao, Guangsheng Luo, Guangbin Ji.  (2025)  Simultaneous Manipulation of Multidimensional Heterojunctions and Dielectric Gene Engineering for Broadband Microwave Absorption.  ADVANCED FUNCTIONAL MATERIALS,  35  (33): (2502480).  [PMID:] [10.1002/adfm.202502480]

85. Li-Qian Cheng, Yi Gong, Jiangyun Ding, Jingye Pan, Kai Chen, Xuxia Hao, Yu Dai, Min Jiang, Xinyuan Xie, Fan Yang, Ruiping Liu.  (2026)  Synergistic V/F Co-doping and Mn2+-Trapping separator for long-life LiMn0.8Fe0.2PO4 cathodes.  JOURNAL OF POWER SOURCES,      [PMID:] [10.1016/j.jpowsour.2026.239431]

86. Yifan Li, Hongshun Zheng, Tong Zhou, Hao Cui, Haigang Dong, Dongxia Yang, Ke Wang, Weijie Zhan, Boxue Wang, Yun Chen, Jize Li, Yuetong Cao, Zhikun Wang, Yumin Zhang, Jin Zhang, Qingju Liu.  (2026)  Zn single-atom loaded TiO2 derived from Ti-MOF for high hydrogen evolution activity under visible light.  Materials Today Energy,      [PMID:] [10.1016/j.mtener.2026.102225]

87. Ke Hu, Jiawei Shi, Yongsheng Yan, Ting Tang, Weiwei Cai, Hongying Hou.  (2026)  Surface neutralization-driven phosphate reconstruction enables high-efficiency oxygen evolution on NiV-LDH nanosheet arrays.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2026.166297]

88. Liang Yin, Tiantian Ma, Zibo Zhu, Zhanao Yao, Songlin Yu, Yi Li, Chengbo Li, Nian Ran, Wei Zhou, Jianjun Liu.  (2026)  Decoding active sites in high-entropy catalysts via attention-enhanced model.  Science Advances,  12  (7):   [PMID:41686899] [10.1126/sciadv.aea1170]

89. Wenzhuo Zhang, Linna Wang, Xiang Li, Yunling Ji, Guisheng Xu, Yikang Cao, Shufen Wang, Jian Li.  (2026)  Inhibiting Ru over-oxidation in RuO2 via vanadium doping for efficient oxygen evolution reaction toward acid and alkaline water electrolysis.  FUEL,      [PMID:] [10.1016/j.fuel.2026.139167]

90. Jianbin Yang, Jiaguang Zheng, Changhai Wu, Haoran Shen, Deyu Tang, Chao Su, Panpan Zhou.  (2026)  Nano-sized TiVH catalysts unlocking high-performance hydrogen storage in magnesium hydride.  FUEL,      [PMID:] [10.1016/j.fuel.2026.139308]

91. Jian Gu, Wentian Cui, Hongzhi Cheng, Didi Cao, Jian Yang, Junyang Jin, Lin Zhao, Hongkang Wei, Meiling Yu, Zhipeng Xie, Chang-an Wang.  (2026)  Preparation and formation mechanism of high-performance novel (TiHfVNb)C medium-entropy submicron particles and ceramics.  JOURNAL OF ALLOYS AND COMPOUNDS,      [PMID:] [10.1016/j.jallcom.2026.187164]