[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium - ≥99.9% metals basis , CAS No.72287-26-4

CAS: 72287-26-4 Cat. No.: D294617 Peso molecular: 731.7 Número EC: 615-748-9

GRADE & PURITY ≥99.9% metals basis

Synonyms

Umicore CX93 | Pd(dppf)Cl2

Storage

Room temperature,Argon charged

Shipped In

Normal

Descripción general

A catalyst for Suzuki and Stille couplings

Catalyst for C-C and C-N coupling reaction.

Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:

· Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity. 

· Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives. 

· Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

Product class

M-P, Homogeneous Catalysts, Bidentate Ligands, Ferrocenyl Ligands - Achiral

Reaction type

Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, C-H Activation, Carbonylation, Negishi Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, Oxidation

Chemical properties

Chemical formula

C34H28Cl2FeP2Pd

Empirical formula

[Pd(dppf)Cl2]

Molecular weight

731.71

Metal

Pd

Theoretical metal content

14

Physical state

crystalline

Color

red

Metal purity

99.95

Applications & references

Reductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.

Reference: Org. Proc. Res. Dev. 2007, 11, 39. (DOI: 10.1021/op060193w), Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246)

High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl bromides.

Reference: J. Org. Chem. 2010, 75, 6998. (DOI: 10.1021/jo101433g)

Specifications

Sinónimos

Umicore CX93 | Pd(dppf)Cl2

Especificaciones y pureza

≥99.9% metals basis

Condiciones de almacenamiento de almacenamiento

Room temperature, Argon charged

Enviado en

Normal

Pureza

≥99.9% metals basis

Nombres e identificadores

• WGK Alemania: 3
• Peso molecular: 731.7

Propiedades químicas y físicas

• Solubilidad: Soluble in dichloromethane.
• Sensibilidad: Air & Moisture sensitive.
• Punto de fusión (°C): 275-280°C

Referencias

1. Fei Zhang, Zhe Li, Yaoming Liu, Binsheng Yang, Hui Qiao, Jie Chai, Guangming Wen, Bin Liu.  (2020)  Rational construction of AIEgens with wide color tunability and their specific lipid droplet imaging applications.  Journal of Materials Chemistry B,  8  (41): (9533-9543).  [PMID:33000854] [10.1039/D0TB01806F]

2. Fei Zhang, Yaoming Liu, Binsheng Yang, Guangming Wen, Bin Liu.  (2020)  Near-infrared AIEgens for lipid droplets imaging in corpus adiposum or trachea of Locusta migratoria and its application in photodynamic therapy.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2020.128589]

3. Zhiyuan Zeng, Tianqun Zhao, Yi Gong, Zhiqiang Yu.  (2024)  Synthesis, curing kinetics and properties of novel aromatic multifunctional epoxy resin.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2024.113375]

4. Shu-Yan Wei, Jia Chen, Shen-Yin Hou, Bo Sun, Jing Ren, Xin-Hui Wang, Lei Geng, Zhi-Ming Zhang, Hua-Qing Yin.  (2025)  Sensitive and Anti-Interference Al3+ Sensing with a Luminescent Eu-MOF.  INORGANIC CHEMISTRY,      [PMID:40878983] [10.1021/acs.inorgchem.5c02902]

5. Duoyang Fan, Ruyan Xie, Xiaohui Liu, Haohan Li, Ziheng Luo, Yanbing Li, Fei Chen, Wenbin Zeng.  (2024)  A peptide-based pH-sensitive antibacterial hydrogel for healing drug-resistant biofilm-infected diabetic wounds.  Journal of Materials Chemistry B,      [PMID:38746970] [10.1039/D4TB00594E]

6. Chen Pu, Shan Guogang, Nie Qingli, Yan Yuting, Zhang Pengfei, Zhao Zujin, Feng Hai-Tao, Tang Ben Zhong.  (2024)  Two-color emissive AIEgens with anti-Kasha property for dual-organelle imaging and phototherapy.  Science China-Chemistry,      [PMID:] [10.1007/s11426-023-1903-1]

7. Cheung-Hin Hung, Ka Hin Chan, Wai-Po Kong, Ruo-Lan Du, Kang Ding, Zhiguang Liang, Yong Wang, Kwok-Yin Wong.  (2025)  A Water-Soluble Aggregation-Induced Emission Photosensitizer with Intrinsic Antibacterial Activity as an Antiplanktonic and Antibiofilm Therapeutic Agent.  JOURNAL OF MEDICINAL CHEMISTRY,      [PMID:40186565] [10.1021/acs.jmedchem.5c00403]

8. Yuan Zhong, Maliang Tao, Quanzhi Yang, Meiwei Mou, Binbin Wei, Jianglin Wang, Bo Situ, Sijie Chen.  (2025)  Fast Screening of Urinary Tract Infections Using a Nitrite-Responsive Smartphone Fluorescent Sensor.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2025.137869]

9. Meili Yang, Zuzhe Kang, Xinpei Zhong, Sirui Bai, Dong-En Wang, Qin Tu, Sheng Chen, Jinyi Wang, Mao-Sen Yuan.  (2025)  Visualizing GSH-ONOO− Redox and Tracking Lesion-Remedy of Acute Kidney Oxidative Injury Based on a Dual-Site Chemosensor.  Advanced Healthcare Materials,      [PMID:40424091] [10.1002/adhm.202500907]

10. Minghao Zhai, Wanan Cai, Jingtao An, Chunli Ma, Tingting Zhou, Haijun Niu, Wen Wang.  (2025)  Polyamides containing triazine fused by triphenelamine with D-A block for improving performance of efficient and stable electrochromic/electrofluorochromic bifunctional device in display and camouflage.  Materials Today Chemistry,      [PMID:] [10.1016/j.mtchem.2025.103228]

11. Guangsen Tian, Shouzheng Li, Shaojia Song, Hongxi Zhao, Linfeng Zhang, Huadong Wu, Ye Luo, Jianding Li, Jia Guo, Qun Yi.  (2025)  Donor–acceptor engineering in conjugated polymer photocatalysts: thieno[3, 2-b]thiophene-dibenzothiophene sulfone copolymers for noble-metal-free visible-light hydrogen evolution.  Journal of Materials Chemistry A,      [PMID:] [10.1039/D5TA05975E]