(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) - ≥97% , CAS No.361346-80-7

CAS: 361346-80-7 Cat. No.: B120935 Peso molecular: 573.6 Número EC: 632-216-1 PubChem CID: 10120770

GRADE & PURITY ≥97%

Synonyms

B2314 | (R)-AMAC | (1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) | (1R,2R)-N,N-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) | (E)-3-[[(1R,2R)-2-[[(E)-2-Acetyl-3-oxidobut-2-enylide

Storage

Argon charged,Room temperature

Shipped In

Normal

Descripción general

Catalyst used for the enantioselective reduction of ketones, hetero Diels-Alder reaction, carbonylene reaction, 1,3-dipolar cycloaddition · Schiff base-cobalt complex catalyst for asymmetric borohydride reduction of carbonyl compounds Catalyst for: Enantioselective borohydride reduction Stereoselective preparation of aryl alcohols via asymmetric reduction of aryl ketones with borohydride Stereoselective borohydride reduction of diketones to diols Stereoselective preparation of optically active deuterated primary alcohols via enantioselective borodeuteride reduction of aldehydes Stereoselective preparation of β-hydroxy esters via dynamic kinetic resolution of alkylketo esters with enantioselective borohydride reduction Chemoselective, diastereoselective, and enantioselective borohydride reduction of 1,3-diketones Asymmetric synthesis of diarylhydroxypropanones by stereoselective reduction of alkyldiaryldiketones

Specifications

Sinónimos

B2314 | (R)-AMAC | (1R, 2R)-N, N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1, 2-dimesitylethylenediaminato Cobalt(II) | (1R, 2R)-N, N-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1, 2-DIMESITYLETHYLENEDIAMINATO COBALT(II) | (E)-3-[[(1R, 2R)-2-[[(E)-2-Acetyl-3-oxidobut-2-enylide

Especificaciones y pureza

≥97%

Condiciones de almacenamiento de almacenamiento

Argon charged, Room temperature

Enviado en

Normal

Pureza

≥97%

Nombres e identificadores

• Sonrisas canónicas: CC1=CC(=C(C(=C1)C)C(C(C2=C(C=C(C=C2C)C)C)N=CC(=C(C)[O-])C(=O)C)N=CC(=C(C)[O-])C(=O)C)C.[Co+2]
• IUPAC Name: (E)-3-[[(1R,2R)-2-[[(E)-2-acetyl-3-oxidobut-2-enylidene]amino]-1,2-bis(2,4,6-trimethylphenyl)ethyl]iminomethyl]-4-oxopent-2-en-2-olate;cobalt(2+)
• InChIKey: PHCQQLMRNZRDJA-SGIDGJHMSA-L
• INCHI: 1S/C32H40N2O4.Co/c1-17-11-19(3)29(20(4)12-17)31(33-15-27(23(7)35)24(8)36)32(34-16-28(25(9)37)26(10)38)30-21(5)13-18(2)14-22(30)6;/h11-16,31-32,35,37H,1-10H3;/q;+2/p-2/b27-23+,28-25+,33-15?,34-16?;/t31-,32-;/m1./s1
• Isómeros SMILES: CC1=CC(=C(C(=C1)C)[C@@H](N=C/C(=C(\[O-])/C)/C(=O)C)[C@H](N=C/C(=C(\[O-])/C)/C(=O)C)C2=C(C=C(C=C2C)C)C)C.[Co+2]
• WGK Alemania: 2
• PubChem CID: 10120770
• Peso molecular: 573.6

Propiedades químicas y físicas

• Sensibilidad: Air Sensitive
• Rotación específica [α]: [α]/D 291°, c = 0.1 in chloroform
• Punto de fusión (°C): 246-250°C