2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution - 1.0M in THF , CAS No.898838-07-8

CAS: 898838-07-8 Cat. No.: T466154 Peso molecular: 242.40

GRADE & PURITY 1.0M in THF

Synonyms

DTXSID30635642 | 2,2,6,6-tetramethylpiperidinylmagnesium chloride lithium chloride | lithium magnesium 2,2,6,6-tetramethylpiperidin-1-ide dichloride | JHBZAAACZVPPRQ-UHFFFAOYSA-L | TMPMgCl·LiCl

Storage

Store at 2-8°C,Protected from light,Argon charged

Shipped In

Wet ice

Descripción general

Description

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.Selective Deprotonations using Knochel-Hauser-Base

Specifications

Sinónimos

DTXSID30635642 | 2, 2, 6, 6-tetramethylpiperidinylmagnesium chloride lithium chloride | lithium magnesium 2, 2, 6, 6-tetramethylpiperidin-1-ide dichloride | JHBZAAACZVPPRQ-UHFFFAOYSA-L | TMPMgCl·LiCl

Especificaciones y pureza

1.0M in THF

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Protected from light, Argon charged

Enviado en

Wet ice

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Nombres e identificadores

• Sonrisas canónicas: [Li+].CC1(CCCC([N-]1)(C)C)C.[Mg+2].[Cl-].[Cl-]
• IUPAC Name: lithium;magnesium;2,2,6,6-tetramethylpiperidin-1-ide;dichloride
• InChIKey: JHBZAAACZVPPRQ-UHFFFAOYSA-L
• INCHI: 1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
• Isómeros SMILES: [Li+].CC1(CCCC([N-]1)(C)C)C.[Mg+2].[Cl-].[Cl-]
• Número ONU: UN 2924
• Grupo de embalaje: II
• Peso molecular: 242.40

Propiedades químicas y físicas

• Sensibilidad: moisture＆light＆air sensitive