2,6-Di-tert-butylpyridine - ≥97%(GC) , CAS No.585-48-8

CAS: 585-48-8 Cat. No.: D154612 Peso molecular: 191.32 Beilstein Registry Number: 125886 Número EC: 209-557-6

GRADE & PURITY ≥97%(GC)

Synonyms

J-507390 | OI9LF0H4MM | 2,6-Di-tert-butylpyridine, 96% | NSC175805 | NSC-175805 | Pyridine,6-di-tert-butyl- | A831919 | EINECS 209-557-6 | SCHEMBL42955 | 2,6-di-(tert-butyl)pyridine | 2,6-Di(tert-butyl)pyridine | 2,6-di-tert.-butylpyridine | DTXSID8020721

Storage

Store at 2-8°C,Argon charged,Desiccated

Shipped In

Wet ice

Specifications

Sinónimos

J-507390 | OI9LF0H4MM | 2, 6-Di-tert-butylpyridine, 96% | NSC175805 | NSC-175805 | Pyridine, 6-di-tert-butyl- | A831919 | EINECS 209-557-6 | SCHEMBL42955 | 2, 6-di-(tert-butyl)pyridine | 2, 6-Di(tert-butyl)pyridine | 2, 6-di-tert.-butylpyridine | DTXSID8020721

Especificaciones y pureza

≥97%(GC)

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged, Desiccated

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥97%(GC)

Nombres e identificadores

• Sonrisas canónicas: CC(C)(C)C1=NC(=CC=C1)C(C)(C)C
• IUPAC Name: 2,6-ditert-butylpyridine
• InChIKey: UWKQJZCTQGMHKD-UHFFFAOYSA-N
• INCHI: 1S/C13H21N/c1-12(2,3)10-8-7-9-11(14-10)13(4,5)6/h7-9H,1-6H3
• Isómeros SMILES: CC(C)(C)C1=NC(=CC=C1)C(C)(C)C
• WGK Alemania: 3
• Peso molecular: 191.32
• Beilstein: 125886
• Reaxy-Rn: 125886
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=125886&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organoheterocyclic compounds
    • Clase Pyridines and derivatives

• Kingdom: Organic compounds
• Superclass: Organoheterocyclic compounds
• Clase: Pyridines and derivatives
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Pyridines and derivatives
• Alternative Parents: Heteroaromatic compounds Azacyclic compounds Organopnictogen compounds Organonitrogen compounds Hydrocarbon derivatives
• Molecular Framework: Aromatic heteromonocyclic compounds
• Substituents: Pyridine - Heteroaromatic compound - Azacycle - Organic nitrogen compound - Organopnictogen compound - Hydrocarbon derivative - Organonitrogen compound - Aromatic heteromonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as pyridines and derivatives. These are compounds containing a pyridine ring, which is a six-member aromatic heterocycle which consists of one nitrogen atom and five carbon atoms.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Miscible with alcohol, acetone, and hexane. Immiscible with water.
• Sensibilidad: Moisture sensitive.；Air sensitive
• Índice de refracción: n20/D 1.473(lit.)
• Punto de inflamación (°F): 159.8 °F
• Punto de inflamación (°C): 71°C(lit.)
• Punto de ebullición (°C): 100-101°C/23 mmHg(lit.)
• Punto de fusión (°C): 2°C(lit.)
• Peso molecular: 191.310 g/mol
• XLogP3: 4.100
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 191.167 Da
• Monoisotopic Mass: 191.167 Da
• Topological Polar Surface Area: 12.900 Ų
• Heavy Atom Count: 14
• Formal Charge: 0
• Complexity: 162.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

Referencias

1. Ke Du, Zhizheng Sheng, He Li, Lou Gao, Tianlan Yan, Jiayu Yu, Di Pan, Zhichao Tan, Songhai Xie, Jing Ju, Yahong Zhang, Yi Tang.  (2023)  Ultrasmall Zeolite Subcrystal Catalyst Devoid of Intracrystalline Diffusion Limitation for Bulk Molecule Conversion.  ACS Applied Nano Materials,      [PMID:] [10.1021/acsanm.3c05122]

2. Fa-Peng Wu, Yun-Peng Zhao, Zong-Pin Fu, Le-Le Qiu, Jian Xiao, Jian Li, Fang-Jing Liu, Jing-Pei Cao.  (2023)  Catalytic transfer hydrogenolysis mechanism of benzyl phenyl ether over NiCu/Al2O3 using isopropanol as hydrogen source.  FUEL PROCESSING TECHNOLOGY,      [PMID:] [10.1016/j.fuproc.2023.107874]

3. Wen-Hui Hu, Meng-Nan Liu, Qun-Xing Luo, Jianbo Zhang, Huiyong Chen, Long Xu, Ming Sun, Xiaoxun Ma, Qing-Qing Hao.  (2023)  Friedel-Crafts acylation of anisole with acetic anhydride over single- to multiple-layer MWW zeolites: Catalytic behavior and kinetic mechanism.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2023.143098]

4. Ying Lu, Jianna Yu, Wen Liu, Guoxing Jing, Wenshan Li, Wenjie Liu.  (2022)  Quantitative determination of major alkaloids in areca nut products by high-performance liquid chromatography coupled with ion mobility spectrometry.  JOURNAL OF SEPARATION SCIENCE,  45  (24): (4469-4477).  [PMID:36250424] [10.1002/jssc.202200361]

5. Jiansu Ran, Lujain Alfilfil, Jingwei Li, Ruixue Yangcheng, Zhaohui Liu, Qin Wang, Yuntong Cui, Tong Cao, Min Qiao, Kexin Yao, Daliang Zhang, Jianjian Wang.  (2022)  Tailoring interfacial microenvironment of palladium-zeolite catalysts for the efficient low-temperature hydrodeoxygenation of vanillin in water.  ChemCatChem,  14  (14): (e202200397).  [PMID:] [10.1002/cctc.202200397]

6. Linjie Guan, Chengming Huang, Dingmei Han, Binbin He, Linhua Zhu, Dedong He, Yi Mei, Yun Zu.  (2022)  HZSM-5 zeolite cross-linked with ultrathin siliceous layer for intensifying catalytic cracking and diffusion of n-butane.  FUEL,      [PMID:] [10.1016/j.fuel.2022.123252]

7. Linjie Guan, Chengming Huang, Dingmei Han, Linhua Zhu, Yi Mei, Dedong He, Yun Zu.  (2021)  Reaction pathways of n-butane cracking over the MFI, FER and TON zeolites: Influence of regional differences in Brønsted acid sites.  MICROPOROUS AND MESOPOROUS MATERIALS,      [PMID:] [10.1016/j.micromeso.2021.111605]

8. Weijian Lu, Jianwen Zhang, Shiqi Zhang, Chen Ji, Ying Wu, Huiyong Chen, Yanxiong Fang, Jinxiang Dong, Baoyu Liu.  (2021)  Synthesis of Linear Alkylbenzenes over Beta Zeolites with Enhanced Transport and Surface Activity.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.1c02815]

9. Wen Li, Kuncan Wang, Guowu Zhan, Jiale Huang, Qingbiao Li.  (2021)  Design and Synthesis of Bioinspired ZnZrOx&Bio-ZSM-5 Integrated Nanocatalysts to Boost CO2 Hydrogenation to Light Olefins.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.1c01384]

10. Yaqi Qu, Mengying He, Hualiang An, Xinqiang Zhao, Yanji Wang.  (2025)  A novel and efficient In2O3@RhPt catalyst for solvent-free transfer hydrogenation of TDC to HTDC: Catalytic performance and mechanism.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.161742]

11. Ben Liang, Meng-Nan Liu, Ning An, Fang Ren, Qun-Xing Luo, Huiyong Chen, Jun Hu, Xiaoxun Ma, Qing-Qing Hao.  (2024)  Achieving long-lived MWW zeolite catalyst for alkylation of benzene with 1-dodecene: Insights into confinement effect of surface cavities and underlying mechanism.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.151109]

12. Long Zhang, Linjie Guan, Jiashu Liu, Song Song, Ye Tian, Xingang Li.  (2025)  Efficient Brønsted Acid Sites Accessibility of ZSM-5 Nanosheets Promoting One-Step Lactide Synthesis.  ChemCatChem,      [PMID:] [10.1002/cctc.202402094]

13. Fa-Peng Wu, Le-Le Qiu, Yun-Peng Zhao, Zong-Pin Fu, Jing Liang, Jian Xiao, Jian Li, Fang-Jing Liu, Jing-Pei Cao.  (2024)  Self-hydrogen transfer hydrogenolysis of β-O-4 bonds in lignin model compounds over NiCu/Al2O3 catalyst.  FUEL,      [PMID:] [10.1016/j.fuel.2024.132094]

14. Yu Qiao, Wenzhong Ma, You Zhang, Tiansheng Gao, Haicun Yang, Zheng Cao, Jing Zhong.  (2024)  Ultra-high stretchability and shape fixation rate shape memory polyurethanes based on cyclic polytetrahydrofuran molecular rings.  POLYMER,      [PMID:] [10.1016/j.polymer.2024.127578]

15. Yanjuan Yang, Yuhuan Li, Liang Deng, Shangzhi Xie, Chuang Gao, Zixu Yang, Jing Xu.  (2025)  The critical role of crystal phases of LaPO4 in controlling the acidic sites for the production of 5-hydroxymethylfurfural from glucose.  GREEN CHEMISTRY,      [PMID:] [10.1039/D5GC01931A]

16. Lei Xia, Fang-Jing Liu, Meng-Jie Wang, Han-Bing Zhang, Jing Zhang, Yao Lu, Le-Le Qiu, Xian-Yong Wei, Yun-Peng Zhao.  (2025)  Alkali-enhanced oxygen vacancies driven high catalytic performance of Pd/WO3 for selective hydrogenation of phenol to cyclohexanone.  Molecular Catalysis,      [PMID:] [10.1016/j.mcat.2025.115371]

17. Jiayu Yu, Ke Du, Di Pan, He Li, Ling Ding, Wei Chen, Yahong Zhang, Yi Tang.  (2025)  Distinguishing and unraveling classical and non-classical pathways in MFI zeolite crystallization: insights into their contributions and impact on the final product.  Inorganic Chemistry Frontiers,      [PMID:] [10.1039/D5QI00224A]

18. Zong-Pin Fu, Qi-Jie Zhou, Yun-Peng Zhao, Yu-Fa Wu, Fang-Jing Liu, Mei Zhong, Jian Li, Jing Liang, Jing-Pei Cao.  (2025)  Electron-rich Cuδ+-O-Con+ boosts active site reconfiguration to trigger multi-pathway C-O bond hydrogenolysis activation in lignin.  JOURNAL OF CATALYSIS,      [PMID:] [10.1016/j.jcat.2025.116529]

19. Zong-Pin Fu, Yun-Peng Zhao, Yu-Fa Wu, Qi-Jie Zhou, Shu-Ting Hu, Le-Le Qiu, Fang-Jing Liu, Mei Zhong, Jing Liang, Jing-Pei Cao.  (2026)  Interfacial oxygen vacancies and Cu-Ni bimetallic sites synergistically enhance the catalytic hydroconversion of soluble portion from lignite thermal dissolution.  JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,      [PMID:] [10.1016/j.jaap.2026.107623]

20. Xiuqing Zheng, Jianna Yu, Mengting Huang, Jiaxu Liu, Jiaxing Li, Peixuan Huang, Lu Cheng, Binwang Yang, Haoran Huang, Zhuyue Peng, Wenjie Liu.  (2026)  Fourier Deconvolution Multiplexing Boosts Ion Throughput in Pinhole-Interfaced GC-IMS/MS for Synchronous Peak Identification.  ANALYTICAL CHEMISTRY,      [PMID:] [10.1021/acs.analchem.6c00104]