2-Trimethylsilyl-1,3-dithiane - ≥95% , CAS No.13411-42-2

CAS: 13411-42-2 Cat. No.: T162340 Peso molecular: 192.41 Beilstein Registry Number: 1616460 Número EC: 236-504-4 PubChem CID: 83413

GRADE & PURITY ≥95%

Synonyms

(1,3-dithiane-2-yl)trimethyl silane | FT-0660841 | 2-amino-5-isobutyl-1,3,4-thiadiazole | EINECS 236-504-4 | (1,3-dithian-2-yl)trimethylsilane | 2-trimethylsily-1,3-dithiane | FS-5760 | J-006486 | MFCD00006655 | 2-(trimethysilyl)-1,3-dithiane | AKOS015840

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Descripción general

2-(Trimethylsilyl)-1,3-dithiane participates in Lewis base-catalyzed 1,3-dithiane addition to electrophiles such as carbonyl compounds and N-substituted aldimines. It undergoes novel diazo transfer reaction with tosyl azide in hexamethylphosphoramide-THF to yield 2-diazo-1,3-dithiane, which on decomposition yields formal carbene adducts. It is a versatile acyl anion equivalen

Specifications

Sinónimos

(1, 3-dithiane-2-yl)trimethyl silane | FT-0660841 | 2-amino-5-isobutyl-1, 3, 4-thiadiazole | EINECS 236-504-4 | (1, 3-dithian-2-yl)trimethylsilane | 2-trimethylsily-1, 3-dithiane | FS-5760 | J-006486 | MFCD00006655 | 2-(trimethysilyl)-1, 3-dithiane | AKOS015840

Especificaciones y pureza

≥95%

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥95%

Nombres e identificadores

• Sonrisas canónicas: C[Si](C)(C)C1SCCCS1
• IUPAC Name: 1,3-dithian-2-yl(trimethyl)silane
• InChIKey: BTTUMVHWIAXYPJ-UHFFFAOYSA-N
• INCHI: 1S/C7H16S2Si/c1-10(2,3)7-8-5-4-6-9-7/h7H,4-6H2,1-3H3
• Isómeros SMILES: C[Si](C)(C)C1SCCCS1
• WGK Alemania: 3
• PubChem CID: 83413
• Peso molecular: 192.41
• Beilstein: 1616460
• Reaxy-Rn: 1616463

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organoheterocyclic compounds
    • Clase Dithianes

• Kingdom: Organic compounds
• Superclass: Organoheterocyclic compounds
• Clase: Dithianes
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Dithianes
• Alternative Parents: Trialkylsilanes Organic metalloid salts Dialkylthioethers Hydrocarbon derivatives
• Molecular Framework: Aliphatic heteromonocyclic compounds
• Substituents: 1,3-dithiane - Trialkylsilane - Organic metalloid salt - Dialkylthioether - Thioether - Hydrocarbon derivative - Organic salt - Organosilicon compound - Alkylsilane - Aliphatic heteromonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as dithianes. These are compounds containing a dithiane moiety, which is composed of a cyclohexane core structure wherein two methylene units are replaced by sulfur centres.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Sensibilidad: Moisture sensitive
• Índice de refracción: 1.53
• Punto de inflamación (°F): 204.8 °F
• Punto de inflamación (°C): 96°C(lit.)
• Punto de ebullición (°C): 77°C/2mmHg(lit.)
• Peso molecular: 192.400 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 192.046 Da
• Monoisotopic Mass: 192.046 Da
• Topological Polar Surface Area: 50.600 Ų
• Heavy Atom Count: 10
• Formal Charge: 0
• Complexity: 103.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3