(2R,2'R,3R,3'R)-4,4'-Di(anthracen-9-yl)-3,3'-di-tert-butyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole - ≥97%,≥99%(ee) , CAS No.1884680-45-8

CAS: 1884680-45-8 Cat. No.: R282059 Peso molecular: 738.83 PubChem CID: 138991737

Synonyms

(2R,2R’,3R,3R’)-WingPhos

Storage

Store at 2-8°C

Shipped In

Wet ice

Descripción general

(2R,2R′,3R,3R′)-WingPhos is a P-chiral biphosphorus ligand for Rh-catalyzed asymmetric hydrogenations as well as Rh-catalyzed asymmetric addition of aryl boroxines to ketones.

Specifications

Sinónimos

(2R, 2R’, 3R, 3R’)-WingPhos

Especificaciones y pureza

≥97%, ≥99%(ee)

Información jurídica

Sold in collaboration with Zejun for research purposes only. Patents ZL201310020371.1, CN 201610056390.

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Nombres e identificadores

• Sonrisas canónicas: CC(C)(C)P1C(OC2=CC=CC(=C21)C3=C4C=CC=CC4=CC5=CC=CC=C53)C6OC7=CC=CC(=C7P6C(C)(C)C)C8=C9C=CC=CC9=CC1=CC=CC=C18
• IUPAC Name: (2R)-4-anthracen-9-yl-2-[(2R)-4-anthracen-9-yl-3-tert-butyl-2H-1,3-benzoxaphosphol-2-yl]-3-tert-butyl-2H-1,3-benzoxaphosphole
• InChIKey: HDNWNMANFZGXKV-KHNZDHPSSA-N
• INCHI: 1S/C50H44O2P2/c1-49(2,3)53-45-39(43-35-21-11-7-17-31(35)29-32-18-8-12-22-36(32)43)25-15-27-41(45)51-47(53)48-52-42-28-16-26-40(46(42)54(48)50(4,5)6)44-37-23-13-9-19-33(37)30-34-20-10-14-24-38(34)44/h7-30,47-48H,1-6H3/t47-,48-,53?,54?/m1/s1
• PubChem CID: 138991737
• Peso molecular: 738.83

Propiedades químicas y físicas

• Sensibilidad: air sensitive