(4S)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-5,5-dimethyl-4-(1-methylethyl)-oxazole - ≥97% , CAS No.1152313-76-2

CAS: 1152313-76-2 Cat. No.: S468593 Peso molecular: 401.48 Número EC: 694-359-6 PubChem CID: 71310816

GRADE & PURITY ≥97%

Synonyms

(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-5,5-dimethyl-4,5-dihydrooxazole | (4S)-2-[2-(Diphenylphosphanyl)phenyl]-5,5-dimethyl-4-(propan-2-yl)-4,5-dihydro-1,3-oxazole | DTXSID10746341 | Oxazole, 2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-5,5-dimeth

Storage

Room temperature

Descripción general

Description

Use of 5,5-(Dimethyl)-i-Pr-PHOX as a Practical Equivalent to t-Bu-PHOX in Asymmetric CatalysisDesign, Synthesis, and Applications of Potential Substitutes of t-Bu-Phosphinooxazoline in Pd-Catalyzed Asymmetric Transformations and Their Use for the Improvement of the Enantioselectivity in the Pd-Catalyzed Allylation Reaction of Fluorinated Allyl Enol Carbonates(S)-5,5-(Dimethyl)-i-Pr-PHOX is a phosphinooxazoline ligand (PHOX), belongs to the class of non-C2symmetric chiral ligand.It can be used in:The enantioselective Pd-catalyzed allylation reactions.The synthesis of (R)-2-phenyl-2,5-dihydrofuran by the enantioselective Heck reaction between 2,3-dihydrofuran and phenyl triflate.The allylation reaction of fluorinated allyl enol carbonates and fluorinated silyl enol ethers to prepare allylated tert α-fluoroketones.

Specifications

Sinónimos

(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-5, 5-dimethyl-4, 5-dihydrooxazole | (4S)-2-[2-(Diphenylphosphanyl)phenyl]-5, 5-dimethyl-4-(propan-2-yl)-4, 5-dihydro-1, 3-oxazole | DTXSID10746341 | Oxazole, 2-[2-(diphenylphosphino)phenyl]-4, 5-dihydro-5, 5-dimeth

Especificaciones y pureza

≥97%

Condiciones de almacenamiento de almacenamiento

Room temperature

Pureza

≥97%

Nombres e identificadores

• Sonrisas canónicas: CC(C)C1C(OC(=N1)C2=CC=CC=C2P(C3=CC=CC=C3)C4=CC=CC=C4)(C)C
• IUPAC Name: [2-[(4S)-5,5-dimethyl-4-propan-2-yl-4H-1,3-oxazol-2-yl]phenyl]-diphenylphosphane
• InChIKey: JGUZEKBWCGNHHN-DEOSSOPVSA-N
• INCHI: 1S/C26H28NOP/c1-19(2)24-26(3,4)28-25(27-24)22-17-11-12-18-23(22)29(20-13-7-5-8-14-20)21-15-9-6-10-16-21/h5-19,24H,1-4H3/t24-/m0/s1
• Isómeros SMILES: CC(C)[C@H]1C(OC(=N1)C2=CC=CC=C2P(C3=CC=CC=C3)C4=CC=CC=C4)(C)C
• WGK Alemania: 3
• PubChem CID: 71310816
• Peso molecular: 401.48