Allyltributylstannane - ≥97% , CAS No.24850-33-7

CAS: 24850-33-7 Cat. No.: A118613 Peso molecular: 331.12 Beilstein Registry Number: 3588340 Número EC: 246-494-3

GRADE & PURITY ≥97%

Synonyms

allyl tributylstannane | Allyltributyltin | allyl-tributyltin | DTXSID50179553 | tributyl(1-allyl)stannane | allyltri-n-butyl tin | AMY18348 | MFCD00215511 | tributyl(prop-2-enyl)stannane | ALLYLTRIBUTYLSTANNANE [MI] | tributyl (prop-2-en-1-yl)stannane |

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Descripción general

Aldehyde allylation reagent, the catalyst of this reaction is chiral Lewis acid and Ytterbium(III) trifluoromethanesulfonate. Catalyzed by tetrakis(triphenylphosphine)palladium (0) (product number 216666), it reacts with iodoquinone 4 and allyl acetate. Used in the efficient allylation reaction of aldehydes and trichloro-1,3,5-triazene to produce high allyl alcohol.

Specifications

Sinónimos

allyl tributylstannane | Allyltributyltin | allyl-tributyltin | DTXSID50179553 | tributyl(1-allyl)stannane | allyltri-n-butyl tin | AMY18348 | MFCD00215511 | tributyl(prop-2-enyl)stannane | ALLYLTRIBUTYLSTANNANE [MI] | tributyl (prop-2-en-1-yl)stannane |

Especificaciones y pureza

≥97%

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged

Enviado en

Wet ice

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Pureza

≥97%

Nombres e identificadores

• Pubchem Sid: 488186634
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488186634
• Sonrisas canónicas: CCCC[Sn](CCCC)(CCCC)CC=C
• IUPAC Name: tributyl(prop-2-enyl)stannane
• InChIKey: YLGRTLMDMVAFNI-UHFFFAOYSA-N
• INCHI: 1S/3C4H9.C3H5.Sn/c3*1-3-4-2;1-3-2;/h3*1,3-4H2,2H3;3H,1-2H2
• Isómeros SMILES: CCCC[Sn](CCCC)(CCCC)CC=C
• WGK Alemania: 3
• Peso molecular: 331.12
• Beilstein: 3588340
• Reaxy-Rn: 3588340
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=3588340&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Clase Organo-post-transition metal compounds
      • Subclass Organotin compounds
        • Level5 Tetraorganotin compounds
          • Level6 Tetraalkyltins

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Clase: Organo-post-transition metal compounds
• Subclass: Organotin compounds
• Intermediate Tree Nodes: Tetraorganotin compounds
• Direct Parent: Tetraalkyltins
• Alternative Parents: Metal allyls Organic salts Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Tetraalkyltin - Metal allyl - Hydrocarbon derivative - Organic salt - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as tetraalkyltins. These are tetraorganotin compounds where the tin atom is linked to exactly four alkyl groups.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Immiscible with water.
• Sensibilidad: Air sensitive
• Índice de refracción: 1.486
• Punto de inflamación (°F): 217.4 °F
• Punto de inflamación (°C): 103 °C
• Punto de ebullición (°C): 100-102℃
• Peso molecular: 331.120 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 11
• Exact Mass: 332.153 Da
• Monoisotopic Mass: 332.153 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 16
• Formal Charge: 0
• Complexity: 141.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

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