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· · COA & SDS Disponible para cada producto · Same-day shipping on in-stock items Bis(norbornadiene)rhodium(I) tetrafluoroborate - ≥27.5% , CAS No.36620-11-8
Synonyms
Chiralyst P374 | A874315 | MFCD00671775 | B2091 | DTXSID30448239 | ZWPWNBFOFVFMPP-UHFFFAOYSA-N | AKOS025295231 | bicyclo[2.2.1]hepta-2,5-diene;rhodium;tetrafluoroborate | [rh(nbd)2]bf4 | Bis[eta-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate | BP-12226
Storage
Argon charged,Room temperature
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Why this grade ≥27.5% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.
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Storage & shipping Argon charged,Room temperature Ships Normal Check lot-specific COA for exact specifications.
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Quality documents SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.
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Literature proof Cited in 0 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.
Descripción general Application
Precatalysts for Asymmetric and Cross-Coupling Catalysis
Bis(norbornadiene)rhodium(I) tetrafluoroborate can be used as a catalyst for the synthesis of:
• Lactones via the 1,4-addition of arylboronic acids to butenolide.
• Chiral β-aryl-substituted ketones and esters.
• β-aryloxycarboxylic esters from β-aryloxy-α,γ-unsaturated esters.
Product class
M-C, Homogeneous Catalysts, Diene/Dienyl Ligands
Reaction type
Hydrogenation, Asymmetric Reactions, CH-Activation, Asymmetric Hydrogenation, Isomerization
Chemical properties
Theoretical metal content
Specifications Sinónimos
Chiralyst P374 | A874315 | MFCD00671775 | B2091 | DTXSID30448239 | ZWPWNBFOFVFMPP-UHFFFAOYSA-N | AKOS025295231 | bicyclo[2.2.1]hepta-2, 5-diene;rhodium;tetrafluoroborate | [rh(nbd)2]bf4 | Bis[eta-(2, 5-norbornadiene)]rhodium(I) Tetrafluoroborate | BP-12226
Especificaciones y pureza
≥27.5%
Condiciones de almacenamiento de almacenamiento
Argon charged, Room temperature
Nombres e identificadores Sonrisas canónicas [B-](F)(F)(F)F.C1C2C=CC1C=C2.C1C2C=CC1C=C2.[Rh] IUPAC Name bicyclo[2.2.1]hepta-2,5-diene;rhodium;tetrafluoroborate InChIKey ZWPWNBFOFVFMPP-UHFFFAOYSA-N INCHI 1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1; Isómeros SMILES [B-](F)(F)(F)F.C1C2C=CC1C=C2.C1C2C=CC1C=C2.[Rh] WGK Alemania 3 PubChem CID 10915722 Número ONU 1759 Peso molecular 373.99
Documentation 📋 Safety Data Sheet (SDS) Comprehensive hazard, handling, storage, and regulatory compliance document.
Download SDS → ✅ Certificate of Analysis (COA) Lot-specific quality data. Enter your lot number to retrieve the exact COA.
Look up COA → 📊 Datasheet Quick-reference summary of product specifications and applications.
View datasheet → 🔬 Specification Sheet Full quality attributes and acceptance criteria for this grade.
View spec sheet →
Advanced Data Taxonomic Classification Kingdom Organic compounds Superclass Hydrocarbons Clase Polycyclic hydrocarbons Subclass Not available Intermediate Tree Nodes Not available Direct Parent Polycyclic hydrocarbons Alternative Parents Organic transition metal salts Organic metalloid salts Unsaturated aliphatic hydrocarbons Olefins Hydrocarbon derivatives Organic anions Molecular Framework Not available Substituents Polycyclic hydrocarbon - Organic metalloid salt - Organic transition metal salt - Unsaturated aliphatic hydrocarbon - Unsaturated hydrocarbon - Hydrocarbon derivative - Olefin - Organic anion - Aliphatic homopolycyclic compound Descripción This compound belongs to the class of organic compounds known as polycyclic hydrocarbons. These are polycyclic organic compounds made up only of carbon and hydrogen atoms. External Descriptors Not available Data sources 1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.
Estructura 3D Certificados (CoA, COO, BSE/TSE y tabla de análisis) Propiedades químicas y físicas Sensibilidad Air Sensitive；Moisture sensitive Punto de fusión (°C) 136.9-139.9 °C Peso molecular 373.990 g/mol XLogP3 Hydrogen Bond Donor Count 0 Hydrogen Bond Acceptor Count 5 Rotatable Bond Count 0 Exact Mass 374.034 Da Monoisotopic Mass 374.034 Da Topological Polar Surface Area 0.000 Ų Heavy Atom Count 20 Formal Charge -1 Complexity 122.000 Isotope Atom Count 0 Defined Atom Stereocenter Count 0 Undefined Atom Stereocenter Count 0 Defined Bond Stereocenter Count 0 Undefined Bond Stereocenter Count 0 The total count of all stereochemical bonds 0 Covalently-Bonded Unit Count 4
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