Borane dimethyl sulfide complex - 9.8M in Dimethylthioamidine , CAS No.13292-87-0

CAS: 13292-87-0 Cat. No.: B431899 Peso molecular: 75.97 Beilstein Registry Number: 3663489 Número EC: 236-313-6

GRADE & PURITY 9.8M in Dimethylthioamidine

Synonyms

MCQRPQCQMGVWIQ-UHFFFAOYSA-N | Dimethyl sulphide borane | Dimethyl sulfide borane | borane methylsulphide | boron dimethyl sulfide | FT-0652013 | Borane dimethyl sulfide complex 2.0 M in THF | UNII-93TWS7F2GX | (Dimethyl sulfide)trihydroboron | (Methylthio

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Descripción general

Borane dimethyl sulfide complex (BMS) is a commonly used reagent and a mediator for hydroboration reaction for the preparation of organoborane compounds, which are utilized as key intermediates in organic synthesis. BMS is also employed as a reducing agent for the reduction of various functional groups such as aldehydes, ketones, epoxides, esters, and carboxylic acids to corresponding alcohols.

Application

Borane-dimethyl sulfide (BH 3 Me 2 S) can be used as a reagent: For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate. For the conversion of ozonides to alcohols. In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C 3 -symmetric tripodal hydroxyamide as a ligand. For the hydroboration reduction and other applications. With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.

Other Notes

10.0-10.2 M as BH 3 . May contain excess methyl sulfide.

Specifications

Sinónimos

MCQRPQCQMGVWIQ-UHFFFAOYSA-N | Dimethyl sulphide borane | Dimethyl sulfide borane | borane methylsulphide | boron dimethyl sulfide | FT-0652013 | Borane dimethyl sulfide complex 2.0 M in THF | UNII-93TWS7F2GX | (Dimethyl sulfide)trihydroboron | (Methylthio

Especificaciones y pureza

9.8M in Dimethylthioamidine

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Nombres e identificadores

• Sonrisas canónicas: [B].CSC
• InChIKey: MCQRPQCQMGVWIQ-UHFFFAOYSA-N
• INCHI: 1S/C2H6S.B/c1-3-2;/h1-2H3
• Isómeros SMILES: [B].CSC
• WGK Alemania: 3
• Peso molecular: 75.97
• Beilstein: 3663489
• Reaxy-Rn: 14759666
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=14759666&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic salts
    • Clase Organic metal salts
      • Subclass Organic metalloid salts

• Kingdom: Organic compounds
• Superclass: Organic salts
• Clase: Organic metal salts
• Subclass: Organic metalloid salts
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic metalloid salts
• Alternative Parents: Sulfenyl compounds Dialkylthioethers Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Organic metalloid salt - Dialkylthioether - Sulfenyl compound - Thioether - Hydrocarbon derivative - Organosulfur compound - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as organic metalloid salts. These are organic salt compounds containing a metalloid atom in its ionic form.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Punto de inflamación (°F): -31 °F
• Punto de inflamación (°C): -35 °C
• Peso molecular: 72.950 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 73.0283 Da
• Monoisotopic Mass: 73.0283 Da
• Topological Polar Surface Area: 25.300 Ų
• Heavy Atom Count: 4
• Formal Charge: 0
• Complexity: 2.800
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

Referencias

1. Shibin Wu, Keru Song, Jianwen Wang, Siyu Huang, Fengyue Shi, Guangdong Zhao.  (2023)  Microstructure and phase evolution behavior of SiZrBC ceramic precursors synthesized via sol–gel method.  JOURNAL OF SOLID STATE CHEMISTRY,      [PMID:] [10.1016/j.jssc.2023.123910]

2. Hui-Ling Duan, Xu Deng, Jun Wang, Li Fan, Yu-Cheng Yang, Zhi-Qi Zhang.  (2020)  Ethanolamine- and amine-functionalized porous cyclodextrin polymers for efficient removal of anionic dyes from water.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2020.109762]

3. Yuang Li, Yingli Zhu, Gangtao Luo, Pingan Chen, Mengke Qiao, Fu Chen, Xiangcheng Li.  (2025)  Fe-induced stacking faults engineering for breakthrough broadband absorption in SiBCN ceramics.  JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,      [PMID:] [10.1016/j.jmst.2025.08.063]

4. Bijie Wang, Yujie Song, Xiao Zhang, Ke Chen, Ming Liu, Xiao Hu, Liu He, Qing Huang.  (2021)  Polymer derived SiBCN(O) ceramics with tunable element content.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2021.12.246]

5. Bijie Wang, Ke Chen, Tianhao Li, Xun Sun, Ming Liu, Lingwei Yang, Xiao (Matthew) Hu, Jian Xu, Liu He, Qing Huang, Linbin Jiang, Yujie Song.  (2021)  High-Temperature Resistant Polyborosilazanes with Tailored Structures.  Polymers,  13  (3): (467).  [PMID:33535636] [10.3390/polym13030467]

6. Chunjia Luo, Yin Wang, Xi Hu, Yaofeng Wu, Yi Wang, Min Chao, Luke Yan.  (2024)  High temperature stable amorphous SiBCN microwave absorption ceramics derived from one-pot synthesis of single-source precursors.  MATERIALS RESEARCH BULLETIN,      [PMID:] [10.1016/j.materresbull.2024.112718]

7. Xi Hu, Geqing Zhang, Haodong He, Chunjia Luo, Min Chao, Guodong Sun, Luke Yan.  (2025)  Microwave absorption ceramics pyrolyzed from poly(dimethylsilylene)diacetylene-modified hyperbranched polyborosilazane.  JOURNAL OF THE AMERICAN CERAMIC SOCIETY,      [PMID:] [10.1111/jace.20586]