Borane dimethyl sulfide complex solution - 1.0 M in 2-methyltetrahydrofuran , CAS No.13292-87-0

CAS: 13292-87-0 Cat. No.: B431896 Peso molecular: 75.97 Beilstein Registry Number: 3663489 Número EC: 236-313-6

GRADE & PURITY 1.0 M in 2-methyltetrahydrofuran

Synonyms

MCQRPQCQMGVWIQ-UHFFFAOYSA-N | Dimethyl sulphide borane | Dimethyl sulfide borane | borane methylsulphide | boron dimethyl sulfide | FT-0652013 | Borane dimethyl sulfide complex 2.0 M in THF | UNII-93TWS7F2GX | (Dimethyl sulfide)trihydroboron | (Methylthio

Storage

Store at 2-8°C

Shipped In

Wet ice

Descripción general

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Find details here .

Application

Commonly used in hydroboration of olefins and as a reductant of carbonyls. 2-Me-THF has shown potential as an environmentally friendly solvent compared to commonly used solvents; e.g. dichloromethane and THF. Reactant used as a regioselective reducing agent Reactant involved in: Hydroboration / oxidation Synthesis of cage compounds For an alternative to Tetrahydrofuran and Dichloromethane, please see: An alternative to Tetrahydrofuran and Dichloromethane 2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Specifications

Sinónimos

MCQRPQCQMGVWIQ-UHFFFAOYSA-N | Dimethyl sulphide borane | Dimethyl sulfide borane | borane methylsulphide | boron dimethyl sulfide | FT-0652013 | Borane dimethyl sulfide complex 2.0 M in THF | UNII-93TWS7F2GX | (Dimethyl sulfide)trihydroboron | (Methylthio

Especificaciones y pureza

1.0 M in 2-methyltetrahydrofuran

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Nombres e identificadores

• Sonrisas canónicas: [B].CSC
• InChIKey: MCQRPQCQMGVWIQ-UHFFFAOYSA-N
• INCHI: 1S/C2H6S.B/c1-3-2;/h1-2H3
• Isómeros SMILES: [B].CSC
• WGK Alemania: 3
• Peso molecular: 75.97
• Beilstein: 3663489
• Reaxy-Rn: 14759666
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=14759666&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic salts
    • Clase Organic metal salts
      • Subclass Organic metalloid salts

• Kingdom: Organic compounds
• Superclass: Organic salts
• Clase: Organic metal salts
• Subclass: Organic metalloid salts
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic metalloid salts
• Alternative Parents: Sulfenyl compounds Dialkylthioethers Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Organic metalloid salt - Dialkylthioether - Sulfenyl compound - Thioether - Hydrocarbon derivative - Organosulfur compound - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as organic metalloid salts. These are organic salt compounds containing a metalloid atom in its ionic form.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Punto de inflamación (°F): -31 °F
• Punto de inflamación (°C): -35 °C
• Peso molecular: 72.950 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 73.0283 Da
• Monoisotopic Mass: 73.0283 Da
• Topological Polar Surface Area: 25.300 Ų
• Heavy Atom Count: 4
• Formal Charge: 0
• Complexity: 2.800
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

Referencias

1. Shibin Wu, Keru Song, Jianwen Wang, Siyu Huang, Fengyue Shi, Guangdong Zhao.  (2023)  Microstructure and phase evolution behavior of SiZrBC ceramic precursors synthesized via sol–gel method.  JOURNAL OF SOLID STATE CHEMISTRY,      [PMID:] [10.1016/j.jssc.2023.123910]

2. Bijie Wang, Yujie Song, Xiao Zhang, Ke Chen, Ming Liu, Xiao Hu, Liu He, Qing Huang.  (2021)  Polymer derived SiBCN(O) ceramics with tunable element content.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2021.12.246]

3. Bijie Wang, Ke Chen, Tianhao Li, Xun Sun, Ming Liu, Lingwei Yang, Xiao (Matthew) Hu, Jian Xu, Liu He, Qing Huang, Linbin Jiang, Yujie Song.  (2021)  High-Temperature Resistant Polyborosilazanes with Tailored Structures.  Polymers,  13  (3): (467).  [PMID:33535636] [10.3390/polym13030467]

4. Hui-Ling Duan, Xu Deng, Jun Wang, Li Fan, Yu-Cheng Yang, Zhi-Qi Zhang.  (2020)  Ethanolamine- and amine-functionalized porous cyclodextrin polymers for efficient removal of anionic dyes from water.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2020.109762]

5. Chunjia Luo, Yin Wang, Xi Hu, Yaofeng Wu, Yi Wang, Min Chao, Luke Yan.  (2024)  High temperature stable amorphous SiBCN microwave absorption ceramics derived from one-pot synthesis of single-source precursors.  MATERIALS RESEARCH BULLETIN,      [PMID:] [10.1016/j.materresbull.2024.112718]

6. Yuang Li, Yingli Zhu, Gangtao Luo, Pingan Chen, Mengke Qiao, Fu Chen, Xiangcheng Li.  (2025)  Fe-induced stacking faults engineering for breakthrough broadband absorption in SiBCN ceramics.  JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,      [PMID:] [10.1016/j.jmst.2025.08.063]

7. Xi Hu, Geqing Zhang, Haodong He, Chunjia Luo, Min Chao, Guodong Sun, Luke Yan.  (2025)  Microwave absorption ceramics pyrolyzed from poly(dimethylsilylene)diacetylene-modified hyperbranched polyborosilazane.  JOURNAL OF THE AMERICAN CERAMIC SOCIETY,      [PMID:] [10.1111/jace.20586]