(Bromometil)ciclopropano - ≥97% , CAS No.7051-34-5

CAS: 7051-34-5 Cat. No.: B109676 Peso molecular: 135 Beilstein Registry Number: 605296 Número EC: 230-331-8

GRADE & PURITY ≥97%

Synonyms

(Bromomethyl)cyclopropane, 97% | cyclopropyl-methylbromide | cyclopropylmethyl-bromide | UNII-D8ZPP7X54B | (BROMO)(CYCLOPROPYL)METHANE | (bromomethyl) cyclopropane | 1-bromomethylcyclopropane | 1-bromomethyl-cyclopropane | bromocyclopropylmethane | bromom

Storage

Conservar a -20°C

Shipped In

Hielera + almohadillas de hielo

Descripción general

Se ha estudiado la reacción de acoplamiento del (bromometil)ciclopropano con bromuro de fenilmagnesio.

el (bromometil)ciclopropano se utiliza en la síntesis de 1,4-dienos mediante acoplamiento cruzado catalizado por hierro con reactivos de Grignard alquenilo. Se ha utilizado como bloque de construcción sintético para la introducción del grupo ciclopropilmetilo.

Specifications

Sinónimos

(Bromomethyl)cyclopropane, 97% | cyclopropyl-methylbromide | cyclopropylmethyl-bromide | UNII-D8ZPP7X54B | (BROMO)(CYCLOPROPYL)METHANE | (bromomethyl) cyclopropane | 1-bromomethylcyclopropane | 1-bromomethyl-cyclopropane | bromocyclopropylmethane | bromom

Especificaciones y pureza

≥97%

Condiciones de almacenamiento de almacenamiento

Conservar a -20°C

Enviado en

Hielera + almohadillas de hielo

Pureza

≥97%

Nombres e identificadores

• Sonrisas canónicas: C1CC1CBr
• IUPAC Name: bromomethylcyclopropane
• InChIKey: AEILLAXRDHDKDY-UHFFFAOYSA-N
• INCHI: 1S/C4H7Br/c5-3-4-1-2-4/h4H,1-3H2
• Isómeros SMILES: C1CC1CBr
• WGK Alemania: 3
• Número ONU: 1993
• Peso molecular: 135
• Beilstein: 605296
• Reaxy-Rn: 605296
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=605296&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organohalogen compounds
    • Clase Organobromides

• Kingdom: Organic compounds
• Superclass: Organohalogen compounds
• Clase: Organobromides
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Organobromides
• Alternative Parents: Hydrocarbon derivatives Alkyl bromides
• Molecular Framework: Aliphatic homomonocyclic compounds
• Substituents: Hydrocarbon derivative - Organobromide - Alkyl halide - Alkyl bromide - Aliphatic homomonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as organobromides. These are compounds containing a chemical bond between a carbon atom and a bromine atom.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Not miscible in water.
• Sensibilidad: Heat Sensitive
• Índice de refracción: 1.475-1.479
• Punto de inflamación (°F): 105.8 °F
• Punto de inflamación (°C): 41 °C
• Punto de ebullición (°C): 102-108°C
• Peso molecular: 135.000 g/mol
• XLogP3: 1.700
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 133.973 Da
• Monoisotopic Mass: 133.973 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 5
• Formal Charge: 0
• Complexity: 30.600
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

Referencias

1. Xin Bao, Chunhong Wang, Zhenyu Zhang, Qinghua Cao, Fei Liu, Jing Chen, Chuanzhi Zhang, Haining Na, Jin Zhu.  (2021)  Wet spinning to prepare filaments from three cellulose carbonated derivatives: Synthesis, characterization and filament properties.  Carbohydrate Polymer Technologies and Applications,      [PMID:] [10.1016/j.carpta.2021.100099]