Chloro(1-t-butylindenyl)palladium(II) dimer - ≥99.95% metals basis , CAS No.1779569-01-5

CAS: 1779569-01-5 Cat. No.: C293980 Peso molecular: 626.26 PubChem CID: 155885086

GRADE & PURITY ≥99.95% metals basis

Synonyms

Umicore CX200;(Pd tBu-Ind Cl)2, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer, [(η3-1-tert-Butylindenyl)(μ-Cl)Pd]2, CX200

Storage

Room temperature

Shipped In

Normal

Descripción general

Application

The following palladium dimer is a precatalyst scaffold for cross-coupling reactions originally reported by the Hazari research group. When used with an selected ligand, the precatalyst exhibits superior activity over a wide array of cross-coupling reactions and under a variety of conditions.

Product class
M-C, Homogeneous Catalysts, Hazari Catalyst, Indenyl Ligands

Reaction type
Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Suzuki-Miyaura Coupling Reaction

Chemical properties

Chemical formula

C26H30Cl2Pd2

Empirical formula

[Pd(1-tBu-Ind)Cl]2

Molecular weight

626.27

Metal

Pd

Theoretical metal content

34

Metal purity

99.95

Applications & references

Suzuki-Miyaura coupling reaction catalyzed by an in situ generated solution of [Pd(cinnamyl)Cl]2 and IPr and an in situ generated solution of our Pd-cat. and IPr.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

Suzuki-Miyaura coupling reaction of 2-chloro-4,6-dimethoxyprimidine and benzofuran-2-boronic acid catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

Suzuki-Miyaura coupling reaction of 2-chloro-1H-benzimidazole and 3-thiophene boronic acid catalyzed by an in situ precatalyst generated from Umicore our Pd-cat. and SPhos.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

Suzuki-Miyaura coupling reaction of 2-methoxy chlorobenzene and morpholine catalyzed by an in situ precatalyst generated from our Pd-cat. and RuPhos.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

Suzuki-Miyaura coupling reaction of 3-acetylpyridine and 3-chloropyridine catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

Suzuki-Miyaura coupling reaction of 4-chloroanisole and potassium isopropyltrifluoroboronate catalyzed by an in situ precatalyst generated from our Pd-cat. and P(tBu)3.

Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)

Hiyama-Denmark Reactions of 4-(trifluoromethyl)chlorobenzene and 4-(methoxy)phenyl silanolate catalyzed by in situ precatalysts generated from our Pd-cat. and different ligands.

Reference: Org. Lett. 2016, 18, 5784 (DOI: 10.1021/acs.orglett.6b02330)

Specifications

Sinónimos

Umicore CX200;(Pd tBu-Ind Cl)2, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer, [(η3-1-tert-Butylindenyl)(μ-Cl)Pd]2, CX200

Especificaciones y pureza

≥99.95% metals basis

Condiciones de almacenamiento de almacenamiento

Room temperature

Enviado en

Normal

Pureza

≥99.95% metals basis

Nombres e identificadores

• Sonrisas canónicas: CC(C)(C)C1[C-]=CC2=CC=CC=C12.CC(C)(C)C1[C-]=CC2=CC=CC=C12.Cl[Pd+].Cl[Pd+]
• IUPAC Name: 1-tert-butyl-1,2-dihydroinden-2-ide;chloropalladium(1+)
• InChIKey: QRXJPFMMPGIVGO-UHFFFAOYSA-L
• INCHI: 1S/2C13H15.2ClH.2Pd/c2*1-13(2,3)12-9-8-10-6-4-5-7-11(10)12;;;;/h2*4-8,12H,1-3H3;2*1H;;/q2*-1;;;2*+2/p-2
• WGK Alemania: 3
• PubChem CID: 155885086
• Peso molecular: 626.26

Propiedades químicas y físicas

• Punto de fusión (°C): 166 °C