≥98% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.
Store at 2-8°C,Argon charged Ships Wet ice Check lot-specific COA for exact specifications.
SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.
Cited in 0 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.
P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)) is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N and C-O bond formation reactions, and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases. It has been proposed as an active catalyst for use in Stille reactions of aryl halides (bromides and chlorides).
P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)3) may be used as catalyst in the following studies: . Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides. . Stille cross-couplings reactions of aryl chloride. . Synthesis of chloropeptin I, via Stille cross-coupling reaction. . Heck reaction. . Negishi cross-coupling reactions.
| Pubchem Sid | 504771807 |
|---|---|
| Pubchem Sid Url | https://pubchem.ncbi.nlm.nih.gov/substance/504771807 |
| Sonrisas canónicas | CC(C)(C)P(C(C)(C)C)C(C)(C)C.C1=CC=C([C-]=C1)C2=CC=CC=C2N.Cl[Pd+] |
| IUPAC Name | chloropalladium(1+);2-phenylaniline;tritert-butylphosphane |
| InChIKey | DZNFQIYYEXFFGV-UHFFFAOYSA-M |
| INCHI | 1S/C12H10N.C12H27P.ClH.Pd/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-6,8-9H,13H2;1-9H3;1H;/q-1;;;+2/p-1 |
| Isómeros SMILES | CC(C)(C)P(C(C)(C)C)C(C)(C)C.C1=CC=C([C-]=C1)C2=CC=CC=C2N.Cl[Pd+] |
| WGK Alemania | 3 |
| PubChem CID | 60201440 |
| Peso molecular | 512.41 |
| Reaxy-Rn | 22750896 |
Comprehensive hazard, handling, storage, and regulatory compliance document.
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| Lot Number | Certificate Type | Fecha | Articulo |
|---|---|---|---|
 F2418351 | Certificate of Analysis | Jun 12, 2024 | C153833 |
| F2418352 | Certificate of Analysis | Jun 12, 2024 | C153833 |
| F2418353 | Certificate of Analysis | Jun 12, 2024 | C153833 |
| F2418354 | Certificate of Analysis | Jun 12, 2024 | C153833 |
| F2418355 | Certificate of Analysis | Jun 12, 2024 | C153833 |
| F2418356 | Certificate of Analysis | Jun 12, 2024 | C153833 |
| J2530112 | Certificate of Analysis | Jun 12, 2024 | C153833 |
| Sensibilidad | Air and moisture sensitive |
|---|---|
| Punto de fusión (°C) | 167-170°C |
![Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) - ≥98% CAS No(1375325-71-5) by Aladdin Scientific](https://www.aladdinsci.com/media/catalog/product/cache/207e23213cf636ccdef205098cf3c8a3/C/1/C153833.jpg)