Chlorodiisopropylphosphine - ≥85% , CAS No.40244-90-4

CAS: 40244-90-4 Cat. No.: C598444 Peso molecular: 152.6 Número EC: 629-426-0

GRADE & PURITY ≥85%

Synonyms

Chlorodiisopropylphosphine|40244-90-4|Diisopropylchlorophosphine|Phosphinous chloride, bis(1-methylethyl)-|chloro-di(propan-2-yl)phosphane|5FG5N54CYB|Chlorobis(isopropyl)phosphine|UNII-5FG5N54CYB|P,P-Bis(1-methylethyl)phosphinous chloride|Phosphinous chlo

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Descripción general

Chlorodiisopropylphosphine can be used:

• To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.

• As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.

• A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.

Specifications

Sinónimos

Chlorodiisopropylphosphine | 40244-90-4 | Diisopropylchlorophosphine | Phosphinous chloride, bis(1-methylethyl)- | chloro-di(propan-2-yl)phosphane | 5FG5N54CYB | Chlorobis(isopropyl)phosphine | UNII-5FG5N54CYB | P, P-Bis(1-methylethyl)phosphinous chloride | Phosphinous chlo

Especificaciones y pureza

≥85%

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥85%

Nombres e identificadores

• Sonrisas canónicas: CC(C)P(C(C)C)Cl
• IUPAC Name: chloro-di(propan-2-yl)phosphane
• InChIKey: JZPDBTOWHLZQFC-UHFFFAOYSA-N
• INCHI: 1S/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3
• Isómeros SMILES: CC(C)P(C(C)C)Cl
• WGK Alemania: 3
• Número ONU: 2924
• Grupo de embalaje: II
• Peso molecular: 152.6
• Reaxy-Rn: 1918497
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1918497&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organophosphorus compounds
    • Clase Alkylhalophosphines

• Kingdom: Organic compounds
• Superclass: Organophosphorus compounds
• Clase: Alkylhalophosphines
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Alkylhalophosphines
• Alternative Parents: Organopnictogen compounds Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Alkylhalophosphine - Organopnictogen compound - Hydrocarbon derivative - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as alkylhalophosphines. These are organophosphorus compounds with the general formula RPX2 or R2PX (R=alkyl, X=halogen).
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Sensibilidad: Heat,Air & Moisture sensitive.
• Índice de refracción: 1.475
• Punto de inflamación (°F): 39.2 °F
• Punto de inflamación (°C): 3°C
• Punto de ebullición (°C): 69 °C/33 mmHg
• Peso molecular: 152.600 g/mol
• XLogP3: 2.300
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 152.052 Da
• Monoisotopic Mass: 152.052 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 8
• Formal Charge: 0
• Complexity: 53.500
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1