Chlorophyll a - Moligand™, ≥85%(HPLC) , CAS No.479-61-8

CAS: 479-61-8 Cat. No.: C109269 Peso molecular: 893.49 Beilstein Registry Number: 3586237 Número EC: 207-536-6

GRADE & PURITY Moligand™, ≥85%(HPLC)

Synonyms

Chlorophyll a, from spinach | CHLOROPHYLLA | magnesium;methyl (3R,21S,22S)-16-ethenyl-11-ethyl-12,17,21,26-tetramethyl-4-oxo-22-[3-oxo-3-[(E,7R,11R)-3,7,11,15-tetramethylhexadec-2-enoxy]propyl]-23,25-diaza-7,24-diazanidahexacyclo[18.2.1.15,8.110,13.115,18

Storage

Store at -20°C

Shipped In

Ice chest + Ice pads

Descripción general

Chlorophyll a is an important green or blue color pigment in most organisms, which is implicated in oxygenic photosynthesis. It functions as an antenna pigment in photosystems I and II.

Specifications

Sinónimos

Chlorophyll a, from spinach | CHLOROPHYLLA | magnesium;methyl (3R, 21S, 22S)-16-ethenyl-11-ethyl-12, 17, 21, 26-tetramethyl-4-oxo-22-[3-oxo-3-[(E, 7R, 11R)-3, 7, 11, 15-tetramethylhexadec-2-enoxy]propyl]-23, 25-diaza-7, 24-diazanidahexacyclo[18.2.1.15, 8.110, 13.115, 18

Especificaciones y pureza

Moligand™, ≥85%(HPLC)

Mecanismos bioquímicos y fisiológicos

Chlorophyll a binds to the protein molecules CP47 and CP43, forming the inner antenna of the reaction center of Photosystem II. In photosystem I, the binding sites of chlorophyll a includes the polypeptides spread across the membranes. Scarcity in formati

Condiciones de almacenamiento de almacenamiento

Store at -20°C

Enviado en

Ice chest + Ice pads

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Grado

Moligand™

Pureza

≥85%(HPLC)

Nombres e identificadores

• Sonrisas canónicas: CCC1=C(C2=NC1=CC3=C(C4=C([N-]3)C(=C5C(C(C(=N5)C=C6C(=C(C(=C2)[N-]6)C=C)C)C)CCC(=O)OCC=C(C)CCCC(C)CCCC(C)CCCC(C)C)C(C4=O)C(=O)OC)C)C.[Mg+2]
• IUPAC Name: magnesium;methyl (3R,21S,22S)-16-ethenyl-11-ethyl-12,17,21,26-tetramethyl-4-oxo-22-[3-oxo-3-[(E,7R,11R)-3,7,11,15-tetramethylhexadec-2-enoxy]propyl]-23,25-diaza-7,24-diazanidahexacyclo[18.2.1.15,8.110,13.115,18.02,6]hexacosa-1,5,8(26),9,11,13(25),14,16,18,20(23)-decaene-3-carboxylate
• InChIKey: ATNHDLDRLWWWCB-AENOIHSZSA-M
• INCHI: 1S/C55H73N4O5.Mg/c1-13-39-35(8)42-28-44-37(10)41(24-25-48(60)64-27-26-34(7)23-17-22-33(6)21-16-20-32(5)19-15-18-31(3)4)52(58-44)50-51(55(62)63-12)54(61)49-38(11)45(59-53(49)50)30-47-40(14-2)36(9)43(57-47)29-46(39)56-42;/h13,26,28-33,37,41,51H,1,14-25,27H2,2-12H3,(H-,56,57,58,59,61);/q-1;+2/p-1/b34-26+;/t32-,33-,37+,41+,51-;/m1./s1
• Isómeros SMILES: CCC1=C(C2=NC1=CC3=C(C4=C([N-]3)C(=C5[C@H]([C@@H](C(=N5)C=C6C(=C(C(=C2)[N-]6)C=C)C)C)CCC(=O)OC/C=C(\C)/CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C4=O)C(=O)OC)C)C.[Mg+2]
• WGK Alemania: 3
• RTECS: FW6420000
• Peso molecular: 893.49
• Beilstein: 3586237
• Reaxy-Rn: 28424939
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=28424939&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organoheterocyclic compounds
    • Clase Tetrapyrroles and derivatives
      • Subclass Chlorins

• Kingdom: Organic compounds
• Superclass: Organoheterocyclic compounds
• Clase: Tetrapyrroles and derivatives
• Subclass: Chlorins
• Intermediate Tree Nodes: Not available
• Direct Parent: Chlorins
• Alternative Parents: Metallotetrapyrroles Phorbines Diterpenoids Aryl alkyl ketones Fatty acid esters Substituted pyrroles 1,3-dicarbonyl compounds Dicarboxylic acids and derivatives Methyl esters Heteroaromatic compounds Azacyclic compounds Organic zwitterions Organic salts Organic oxides Hydrocarbon derivatives Organonitrogen compounds
• Molecular Framework: Aromatic heteropolycyclic compounds
• Substituents: Chlorin - Metallotetrapyrrole skeleton - Phorbine skeleton - Diterpenoid - Aryl ketone - Aryl alkyl ketone - Fatty acid ester - Dicarboxylic acid or derivatives - Substituted pyrrole - 1,3-dicarbonyl compound - Fatty acyl - Heteroaromatic compound - Methyl ester - Pyrrole - Carboxylic acid ester - Ketone - Azacycle - Carboxylic acid derivative - Organooxygen compound - Organonitrogen compound - Hydrocarbon derivative - Organic salt - Organic oxide - Organic oxygen compound - Organic nitrogen compound - Organic zwitterion - Carbonyl group - Aromatic heteropolycyclic compound
• Descripción: This compound belongs to the class of organic compounds known as chlorins. These are large heterocyclic aromatic ring systems consisting, at the core, of three pyrroles and one pyrroline coupled through four methine linkages.
• External Descriptors: methyl ester - chlorophyll

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Soluble in ethanol (10 μg/ml), acetone, benzene, ether, and chloroform. Insoluble in water.
• Sensibilidad: Light sensitive.Air sensitive.
• Punto de fusión (°C): 150-153°C
• Peso molecular: 893.500 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 22
• Exact Mass: 892.535 Da
• Monoisotopic Mass: 892.535 Da
• Topological Polar Surface Area: 96.400 Ų
• Heavy Atom Count: 65
• Formal Charge: 0
• Complexity: 2130.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 5
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 1
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 1
• Covalently-Bonded Unit Count: 2

XLogP3

Referencias

1. Bicheng Liu, Liangming Wu, Zoujun Peng, Sihao Wu, Ping Qiu.  (2021)  Monitoring of parathion methyl using a colorimetric gold nanoparticle-based acetylcholinesterase assay.  SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,      [PMID:34865979] [10.1016/j.saa.2021.120665]

2. Zi-Ling Li, Xiao-Run Qi, Yi-Heng Xu, Jia-Qi Zhao, Gui-Fu Zuo, Man-Man Wang.  (2025)  Highly efficient and convenient QuEChERS using ZIF-67 derived magnetic nanoporous carbon for determination of carbamate pesticides in various vegetable and fruit samples.  FOOD CHEMISTRY,      [PMID:39848044] [10.1016/j.foodchem.2025.142904]

3. Xiaokang Zhang, Dengke Ren, Yanhui Wei, Hongchao Ma.  (2025)  Red Light, Green chemistry: on-site nitrite detection in pre-processed vegetables using diazotization-active carbon dots and smartphone-enabled dual-mode fluorometric/colorimetric readout.  ANALYTICA CHIMICA ACTA,      [PMID:41093511] [10.1016/j.aca.2025.344643]

4. Jingwen Li, Hui Yu, Lijuan Wang, Qing Ma, Dongkun Zhao, Baocheng Xu, Xinjing Dou, Lili Liu.  (2025)  Impact of packaging film colour on phytosterol photooxidation in safflower seed oil.  LWT-FOOD SCIENCE AND TECHNOLOGY,      [PMID:] [10.1016/j.lwt.2025.117818]