Chromium chloride - ≥99.9% metals basis, powder , CAS No.10049-05-5

CAS: 10049-05-5 Cat. No.: C113686 Peso molecular: 122.9 Número EC: 233-163-3 PubChem CID: 51073530

GRADE & PURITY ≥99.9% metals basis, powder

Synonyms

Chromium(II) chloride | Chromium dichloride | Chromous chloride

Storage

Argon charged,Room temperature

Shipped In

Normal

Descripción general

Mediates the condensation of the aldehydes with trisubstituted chloroalkenes.Used in the synthesis of a highly active precatalyst for ethylene oligimerization. Used to make bis(indenyl)chromium dimer and related products. Used with iodoform and tetraethyl ethylenediamine to convert terminal olefins into trans-iodocyclopropanes in excellent yields. The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties.

Specifications

Sinónimos

Chromium(II) chloride | Chromium dichloride | Chromous chloride

Especificaciones y pureza

≥99.9% metals basis, powder

Condiciones de almacenamiento de almacenamiento

Argon charged, Room temperature

Enviado en

Normal

Pureza

≥99.9% metals basis

Nombres e identificadores

• Pubchem Sid: 504771021
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504771021
• WGK Alemania: 3
• RTECS: GB5250000
• PubChem CID: 51073530
• Peso molecular: 122.9

Propiedades químicas y físicas

• Solubilidad: Soluble in water. Insoluble in alcohol and ether
• Sensibilidad: Air and Moisture Sensitive
• Punto de ebullición (°C): 1300°C
• Punto de fusión (°C): 824°C

Referencias

1. Jing Xu, Juan Yang, Zhongteng Wang, Pei Li, Jian Lan, Risheng Yu, Jie Li, Lu Li, Wei Liu, Junlang Chen, Shangshen Feng, Liang Chen.  (2023)  Quantitative mixed-valence state identification of metal ions based on fluorescence response of graphene quantum dots.  MATERIALS & DESIGN,      [PMID:] [10.1016/j.matdes.2023.112465]

2. Pu Li, Chen Luo, Xiaoxiao Chen, Chaobiao Huang.  (2023)  A novel “off-on” ratiometric fluorescent aptasensor for adenosine detection based on FRET between quantum dots and graphene oxide.  SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,      [PMID:37866265] [10.1016/j.saa.2023.123557]

3. Xinlei Zhang, Peng Liu, Yuchi Zhang, Bohan Li, Yan Xu.  (2023)  Sequential on–off–on detection of Fe2+ and enantiomeric L-lysine with logic gate operation based on fluorescent carbon dots derived from a zinc–amine complex.  NEW JOURNAL OF CHEMISTRY,  47  (41): (19202-19209).  [PMID:] [10.1039/D3NJ04046A]

4. Jianbang Ge, Biwu Cai, Fei Zhu, Yang Gao, Xinrui Wang, Qianjin Chen, Mingyong Wang, Shuqiang Jiao.  (2023)  Natural Convection in Molten Salt Electrochemistry.  JOURNAL OF PHYSICAL CHEMISTRY B,      [PMID:37781882] [10.1021/acs.jpcb.3c03938]

5. Cheng Huang, Kun Li, Hong Zhang, Wenwen Zhang, Yanlin Sun, Shujie Xing, Ying Shao, Jing Zhu, Yalan Chen, Long Chen.  (2023)  Chitosan immobilized Chinese gallotannin: A potential adsorbent to enrich the rare metals Ge (Ⅳ), Ga (Ⅲ), and In (Ⅲ).  Journal of Environmental Chemical Engineering,      [PMID:] [10.1016/j.jece.2023.110816]

6. Qing Zhang, Chunrong Zhang, Nan Li, Zhao Dai.  (2023)  Optical Visualization of Cadmium Ion Using a Label-Free Nucleic Acid Aptamer for Recognition.  ANALYTICAL LETTERS,      [PMID:] [10.1080/00032719.2023.2235623]

7. Yi Liu, Shuangjiang Li, Xiaojian Yu, Ying Chen, Xiaoning Tang, Tianding Hu, Lan Shi, Manoj Pudukudy, Shaoyun Shan, Yunfei Zhi.  (2023)  Cellulose nanofibers (CNF) supported (Salen)Cr(III) composite as an efficient heterogeneous catalyst for CO2 cycloaddition.  Molecular Catalysis,      [PMID:] [10.1016/j.mcat.2023.113344]

8. Fanghao Xu, Shixiang Ma, Hongwu Tian, Zhen Xing, Chunjiang Zhao, Quan Feng, Xiande Zhao, Daming Dong.  (2023)  Detection of chromium in different valence states in water and soil using laser-induced breakdown spectroscopy combined with an ion enrichment chip.  JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY,  38  (7): (1442-1449).  [PMID:] [10.1039/D3JA00095H]

9. Weijun Wu, Jie Mao, Yifei Lu, Sui Wang.  (2023)  A Facile Dual-Emission Ratiometric Carbon-Dot Fluorescent Probe and Its Application in Portable Chemical Sensors and Water Quality Analysis.  ChemistrySelect,  8  (17): (e202300345).  [PMID:] [10.1002/slct.202300345]

10. Pu Li, Chen Luo, Xiaoxiao Chen, Chaobiao Huang.  (2022)  An off–on fluorescence aptasensor for trace thrombin detection based on FRET between CdS QDs and AuNPs.  RSC Advances,  12  (55): (35763-35769).  [PMID:36545096] [10.1039/D2RA06891E]

11. Hui Yang, Xiankun Su, Li Cai, Zhenchun Sun, Yechun Lin, Jing Yu, Likai Hao, Cui Liu.  (2022)  Glutathione assisting the waste tobacco leaf to synthesize versatile biomass-based carbon dots for simultaneous detection and efficient removal of mercury ions.  Journal of Environmental Chemical Engineering,      [PMID:] [10.1016/j.jece.2022.108718]

12. Hui Yang, Yunlong Wei, Xiufang Yan, Chao Nie, Zhenchun Sun, Likai Hao, Xiankun Su.  (2022)  High-Efficiency Utilization of Waste Tobacco Stems to Synthesize Novel Biomass-Based Carbon Dots for Precise Detection of Tetracycline Antibiotic Residues.  Nanomaterials,  12  (18): (3241).  [PMID:36145029] [10.3390/nano12183241]

13. Kehan Xu, Long Li, Zuohua Huang, Zhenbang Tian, Hui Li.  (2022)  Efficient adsorption of heavy metals from wastewater on nanocomposite beads prepared by chitosan and paper sludge.  SCIENCE OF THE TOTAL ENVIRONMENT,      [PMID:35850330] [10.1016/j.scitotenv.2022.157399]

14. Yuan-Yuan Tang, Jing-Shuai Chen, Xing-Pei Liu, Chang-Jie Mao, Bao-Kang Jin.  (2022)  An ultrasensitive photoelectrochemical aptasensor based on ZnIn2S4/CdSe heterojunction for the detection of microcystine-LR.  MICROCHEMICAL JOURNAL,      [PMID:] [10.1016/j.microc.2022.107773]

15. Pu Li, Xiaoxiao Chen, Gaojun Wu, Zhe Wang, Chaobiao Huang.  (2022)  Ascorbic Acid Sensor Based on CdS QDs@PDA Fluorescence Resonance Energy Transfer.  MOLECULES,  27  (7): (2097).  [PMID:35408497] [10.3390/molecules27072097]

16. Liu Yi, Chen Ying, Zhi Yunfei, Yu Xiaojian, Wang Pengfei, Wang Shouhong, Shan Shaoyun.  (2022)  SalenCr Catalyst Immobilized on Amino-Functionalized Cellulose for the Copolymerization of SO2 with Cyclohexene Oxide.  CATALYSIS LETTERS,  153  (1): (248-259).  [PMID:] [10.1007/s10562-022-03940-5]

17. Jun Yao, Li Wang, Hongyan Zhou, Zhuang Xie, Xiang Zeng, Chaohui Liu.  (2021)  Cuprous oxide coated silver/graphitic carbon nitride/cadmium sulfide nanocomposite heterostructure: Specific recognition of carcinoembryonic antigen through sandwich-type mechanism.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:35257935] [10.1016/j.jcis.2021.11.103]

18. Mengzi Liu, Yanyan Wei, Muhammad Salam, Xiaobing Yuan, Bingsheng Liu, Qiang He, Xuebin Hu, Hong Li, Yixin He.  (2021)  Potassium supplement enhanced cadmium removal in a Microcystis aeruginosa photobioreactor: Evidence from actual and simulated wastewater.  JOURNAL OF HAZARDOUS MATERIALS,      [PMID:34802826] [10.1016/j.jhazmat.2021.127719]

19. Lingfeng Qin, Bo Feng, Qi Luo, Zihang Zeng, Peng Zhang, Xiaosheng Ye, Taiping Qing.  (2021)  Copper ion and G-quadruplex-mediated fluorescent sensor for highly selective detection of bleomycin in actual samples.  SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,      [PMID:34753707] [10.1016/j.saa.2021.120572]

20. Shuangquan Lai, Yong Jin, Liangjie Shi, Yupeng Li, Rong Zhou.  (2021)  Tailoring multifunctional gel for sensitive naked-eye and fluorescence dual-mode detection and effective adsorption of cadmium(Ⅱ) and lead(Ⅱ) ions in water.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2021.132367]

21. Lili Huang, Kaihua Yu, Wenting Zhou, Qiuyi Teng, Zhaoyin Wang, Zhihui Dai.  (2021)  Quantitative principal component analysis of multiple metal ions with lanthanide coordination polymer networks.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2021.130469]

22. Xiaoqing Liu, Yuxuan Shang, Zhong-Ren Chen.  (2021)  Vinyl Groups Containing Tetraphenylethylene Derivatives as Fluorescent Probes Specific for Palladium and the Quenching Mechanism†.  CHINESE JOURNAL OF CHEMISTRY,  39  (6): (1599-1605).  [PMID:] [10.1002/cjoc.202000746]

23. Xiaoqing Liu, Taixin Chen, Feng Yu, Yuxuan Shang, Xue Meng, Zhong-Ren Chen.  (2020)  AIE-Active Random Conjugated Copolymers Synthesized by ADMET Polymerization as a Fluorescent Probe Specific for Palladium Detection.  MACROMOLECULES,      [PMID:] [10.1021/acs.macromol.0c00042]

24. Na Chen, Huan Zhang, Xu-Dong Luo, Chuan-Yu Sun.  (2020)  SiO2-decorated graphite felt electrode by silicic acid etching for iron-chromium redox flow battery.  ELECTROCHIMICA ACTA,      [PMID:] [10.1016/j.electacta.2020.135646]

25. Alula Yohannes, Shun Yao.  (2019)  Preconcentration of tropane alkaloids by a metal organic framework (MOF)-immobilized ionic liquid with the same nucleus for their quantitation in Huashanshen tablets.  ANALYST,  144  (23): (6989-7000).  [PMID:31637371] [10.1039/C9AN01362H]

26. Yue Yuan, Yun Wu, Xinlei Ge, Dongyang Nie, Mei Wang, Haitao Zhou, Mindong Chen.  (2019)  In vitro toxicity evaluation of heavy metals in urban air particulate matter on human lung epithelial cells.  SCIENCE OF THE TOTAL ENVIRONMENT,      [PMID:31075597] [10.1016/j.scitotenv.2019.04.431]

27. Zhengwei Zhang, Kun Yan, Ling Zhang, Qian Wang, Ruixin Guo, Zhengyu Yan, Jianqiu Chen.  (2019)  A novel cadmium-containing wastewater treatment method: Bio-immobilization by microalgae cell and their mechanism.  JOURNAL OF HAZARDOUS MATERIALS,      [PMID:31035092] [10.1016/j.jhazmat.2019.04.072]

28. Syed Niaz Ali Shah, Xiangnan Dou, Mashooq Khan, Katsumi Uchiyama, Jin-Ming Lin.  (2018)  N-doped carbon dots/H2O2 chemiluminescence system for selective detection of Fe2+ ion in environmental samples.  TALANTA,      [PMID:30683378] [10.1016/j.talanta.2018.12.091]

29. Longshi Rao, Yong Tang, Hanguang Lu, Shudong Yu, Xinrui Ding, Ke Xu, Zongtao Li, Jin Z. Zhang.  (2018)  Highly Photoluminescent and Stable N-Doped Carbon Dots as Nanoprobes for Hg2+ Detection.  Nanomaterials,  8  (11): (900).  [PMID:30400227] [10.3390/nano8110900]

30. Wei Zhang, Run-Zhi Zhang, Yong-Qing Huang, Ji-Min Yang.  (2018)  Effect of the Synergetic Interplay between the Electrostatic Interactions, Size of the Dye Molecules, and Adsorption Sites of MIL-101(Cr) on the Adsorption of Organic Dyes from Aqueous Solutions.  CRYSTAL GROWTH & DESIGN,      [PMID:] [10.1021/acs.cgd.8b01340]

31. Juan Huang, Yun Yang, Yaokun Wang, Mingyang Zhang, Youxun Liu.  (2018)  Immobilization of a Laccase/2,2’-azino-bis-(3-ethylbenzothiazoline)-6-sulfonic Acid System to Layered Double Hydroxide/Alginate Biohybrid Beads for Biodegradation of Malachite Green Dye.  Biomed Research International,      [PMID:30345302] [10.1155/2018/5471961]

32. Shao Hong, Xu Dan, Ding Yadan, Hong Xia, Liu Yichun.  (2018)  An “off-on” colorimetric and fluorometric assay for Cu(II) based on the use of NaYF4:Yb(III),Er(III) upconversion nanoparticles functionalized with branched polyethylenimine.  MICROCHIMICA ACTA,  185  (4): (1-8).  [PMID:29594634] [10.1007/s00604-018-2740-7]

33. Zhengwei Zhang, Jiao Chen, Qiulian Yang, Kai Lan, Zhengyu Yan, Jianqiu Chen.  (2018)  Eco-friendly intracellular microalgae synthesis of fluorescent CdSe QDs as a sensitive nanoprobe for determination of imatinib.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2018.02.169]

34. Hong Shao, Yadan Ding, Xia Hong, Yichun Liu.  (2017)  Ultra-facile and rapid colorimetric detection of Cu2+ with branched polyethylenimine in 100% aqueous solution.  ANALYST,  143  (2): (409-414).  [PMID:29292458] [10.1039/C7AN01619K]

35. Qi Yao, Chenying Li, Henghui Huang, Hualin Chen, Bailing Liu.  (2017)  Waterborne carboxyl-terminated hyperbranched oligomer polyester ligand: Synthesis, characterization and chelation with chromium(III).  JOURNAL OF MOLECULAR STRUCTURE,      [PMID:] [10.1016/j.molstruc.2017.04.069]

36. Yating Shen, Yunlei Zhang, Yao Chen, Yongsheng Yan, Jianming Pan, Meng Liu, Weidong Shi.  (2015)  Combination of Brønsted and Lewis Polymeric Catalysts for Efficient Conversion of Cellulose into 5-Hydroxymethylfurfural (HMF) in Ionic Liquids.  Energy Technology,  4  (5): (600-609).  [PMID:] [10.1002/ente.201500415]

37. Wu Jing, Zhi Yunfei, Shan Shaoyun, Su Hongying, Wu Shuisheng, Jia Qingming.  (2015)  Polypyrrole Nanofibers Supported Cr(III)(salen)Cl Catalyst: A Novel Polymer Supported Catalyst for Alternating Copolymerization of Cyclohexene Oxide with Carbon dioxide.  CATALYSIS LETTERS,  145  (10): (1913-1921).  [PMID:] [10.1007/s10562-015-1599-z]

38. Zan Qu, Lili Yan, Liang Li, Jianfang Xu, Mingming Liu, Zhichun Li, Naiqiang Yan.  (2014)  Ultraeffective ZnS Nanocrystals Sorbent for Mercury(II) Removal Based on Size-Dependent Cation Exchange.  ACS Applied Materials & Interfaces,      [PMID:25299972] [10.1021/am504896w]

39. Wenju Wang, Huiling Li, Junli Ren, Runcang Sun, Jie Zheng, Guangwei Sun, Shijie Liu.  (2014)  An efficient process for dehydration of xylose to furfural catalyzed by inorganic salts in water/dimethyl sulfoxide system.  CHINESE JOURNAL OF CATALYSIS,      [PMID:] [10.1016/S1872-2067(14)60031-0]

40. Yong Xie, Rui-Xia Yang, Nian-Yu Huang, Hua-Jun Luo, Wei-Qiao Deng.  (2014)  Efficient fixation of CO2 at mild conditions by a Cr-conjugated microporous polymer.  Journal of Energy Chemistry,      [PMID:] [10.1016/S2095-4956(14)60113-3]

41. Feijin Zhou, Wenying Cui, Chenggang Liu, Cheng Yao, Chan Song.  (2024)  2D-rGO-supported FePc bifunctional nanozyme with enhanced catalytic activity for thiosulfate detection and rhodamine B degradation.  Environmental Science-Nano,  11  (7): (3104-3113).  [PMID:] [10.1039/D4EN00119B]

42. Yadong Hu, Juan Liu, Bin Liu, Donghu Liu, Yingying Hu, Qiang Wu, Xingdao He.  (2024)  Detection of Heavy Metal Ions with Ion Imprinting Microfiber Sensor Arrays.  IEEE SENSORS JOURNAL,      [PMID:] [10.1109/JSEN.2024.3453430]

43. Taiqi Yin, Yongcheng Zhang, Lei Zhang, Tao Bo, Xiaoli Tan, Weiqun Shi.  (2024)  Electrochemical method for determining the solubility of impurities in lead-bismuth eutectic using molten salt electrolytes.  Nuclear Engineering and Technology,      [PMID:] [10.1016/j.net.2024.05.020]

44. Ke Wenrui, Kuang Guochen, Gu Chuangqi, Wang Junhao, Jiang Xiao, Zhu Rongjiao, Wang Haiyuan, Zhang Zhen.  (2025)  Enzyme cascade nanozyme based colorimetric sensor for detection of uric acid as a biomarker of hyperuricemia.  MICROCHIMICA ACTA,  192  (2): (1-10).  [PMID:39812877] [10.1007/s00604-024-06946-5]

45. Bin Li, Aolin Wu, Mengjing Zhou, Ying Wang, Zhigang Hu, Lihua Su.  (2024)  Mechanical, adsorption and detection properties of functionalized N-CQDs/P(AM-U-ChCl) composite hydrogels.  NEW JOURNAL OF CHEMISTRY,      [PMID:] [10.1039/D4NJ02101K]

46. Yong Jiang, Zhong Liang, Hao Fu, Guangtong Hai, Yaping Du.  (2025)  Utilizing oxygen vacancies in cerium oxide to narrow the gap between d and f band centers for efficient alkaline water oxidation.  Nano Today,      [PMID:] [10.1016/j.nantod.2025.102705]

47. Jie Liu, Jinhong Ren, Yunmei Du, Xiao Chen, Mengmeng Wang, Yanru Liu, Lei Wang.  (2024)  V-Doping Strategy Induces the Construction of the Functionally Complementary Ru2P/V-RuP4 Heterostructures to Achieve Amperometric Current Density for HER.  ADVANCED FUNCTIONAL MATERIALS,      [PMID:] [10.1002/adfm.202315773]

48. Ling Yang, Jihao Su, Zhixuan Yu, Yanqing Chang, Dengbin Yu, Zhiquan Zhang, Shaojun Dong.  (2025)  Development of a novel method of biochemical oxygen demand colorimetric detection and its application in actual water.  TALANTA,      [PMID:40639105] [10.1016/j.talanta.2025.128563]

49. Wenju Wang, Junli Ren, Huiling Li, Aojie Deng, Runcang Sun.  (2015)  Direct transformation of xylan-type hemicelluloses to furfural via SnCl4 catalysts in aqueous and biphasic systems.  BIORESOURCE TECHNOLOGY,      [PMID:25742750] [10.1016/j.biortech.2015.02.068]

50. Pengju Ren, Yihan Chi, Lijuan Wang, Yuanyuan Tang.  (2025)  Critical Role of Coexistence Order and Interfacial Forces in the Aggregation of Polystyrene Nanoplastics Induced by Nano-SiO2 and Metal Cations.  Environmental Science-Nano,      [PMID:] [10.1039/D5EN00392J]

51. Feijin Zhou, Wenying Cui, Chenggang Liu, Cheng Yao, Chan Song.  (2025)  Easy detection of S2− using oxidase-like nanozymes of Fe,N co-doped hollow mesoporous carbon nanospheres via colorimetric method.  SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,      [PMID:40328057] [10.1016/j.saa.2025.126322]

52. Lingkang Yu, Yining Wang, Xiaole Xing, Zheng Xu, Mengmeng Shang.  (2025)  Enhancing the NIR Emission in Cs2ScCl5·H2O:Cr3+ Phosphor via Te4+ Sensitization.  INORGANIC CHEMISTRY,      [PMID:40623031] [10.1021/acs.inorgchem.5c02232]

53. Min Li, Mingyang Han, Xinying Song, Yiming Chen, Zepeng Wu, Li Guan, Fenghe Wang, Dawei Wang, Longfeng Lv, Xu Li.  (2025)  A design strategy of ratiometric optical probe for Fe3+ ions and ascorbic acid detection based on europium-doped carbon dots.  JOURNAL OF RARE EARTHS,      [PMID:] [10.1016/j.jre.2025.10.008]

54. Chuntao Ge, Qian Kou, Rong Li, Wenjuan Qi, Junjie Xu, Jun Zhang, Saijun Xiao.  (2025)  Electrochemical Behavior of Cr2+ in NaCl-CaCl2 Molten Salt and Electrodeposition of Chromium Coatings.  JOURNAL OF THE ELECTROCHEMICAL SOCIETY,  172  (9): (092505).  [PMID:] [10.1149/1945-7111/ae00fb]

55. Chunyue Li, Jixiao Li, Yutong Yao, Xiehang Chen, Qingyang Zhang, Jiaozhi Yao, Xiaokun Zhang, Weidong Xue, Yong Xiang.  (2025)  High-entropy heterointerface engineering enables near-zero lattice strain and wide-temperature durable anodes for high-stability lithium-ion batteries.  Journal of Energy Storage,      [PMID:] [10.1016/j.est.2025.119452]

56. Qiu Liang, Yao Lin, Wang Ping, Jiang Zhiwei, Li Jinglin, Li Ying, Li Yixin, Wu Zhaosong, Nasir Muhammad Salman, Wang Ding, Wang Xinqiang, Huang Zhen, Zhou Baowen.  (2025)  Highly efficient heterogeneous thermal catalysis for noble-metal-free hydrogen production from formic acid.  Nature Communications,      [PMID:41453884] [10.1038/s41467-025-67895-y]

57. Bin Bin Chen, Da Jun Wu, Zi Yue Jin, Ming Jie Ye, Ruo Can Qian, Cheng Zhi Huang, Da Wei Li.  (2026)  Real-Time Tracking of Ion Migration Process at the Single-Nanoparticle Level.  ANALYTICAL CHEMISTRY,      [PMID:41693100] [10.1021/acs.analchem.6c00134]

58. Liang Yin, Tiantian Ma, Zibo Zhu, Zhanao Yao, Songlin Yu, Yi Li, Chengbo Li, Nian Ran, Wei Zhou, Jianjun Liu.  (2026)  Decoding active sites in high-entropy catalysts via attention-enhanced model.  Science Advances,  12  (7):   [PMID:41686899] [10.1126/sciadv.aea1170]

59. Yuzuo Liu, Jiawei Li, Bin Li, Zhigang Hu, Haoyu Lv, Ying Wang.  (2026)  Investigation of pressure response, adsorption performance, and detection capability of multifunctional P(AM-Gly-ChCl)/N-CQDs composite hydrogels.  NEW JOURNAL OF CHEMISTRY,      [PMID:] [10.1039/D6NJ00101G]