Dichlorobis(triphenylphosphine)nickel(II) - ≥98% , CAS No.14264-16-5

CAS: 14264-16-5 Cat. No.: B106748 Peso molecular: 654.17 Número EC: 238-154-8 PubChem CID: 498315

GRADE & PURITY ≥98%

Synonyms

NiCl2(PPh3)2 | Bis(triphenylphosphine)nickel(II) chloride, 99.99% trace metals basis | Bis(triphenylphosphine)nickel(II)chloride | NiCl2(PPh3)2 | MFCD00009592 | AC-4984 | MONONICKEL(II) BIS(TRIPHENYLPHOSPHONIUM) DICHLORIDE | Bis(triphenylphosphine)nickel(

Storage

Argon charged,Room temperature

Shipped In

Normal

Descripción general

A coordination compund.

Specifications

Sinónimos

NiCl2(PPh3)2 | Bis(triphenylphosphine)nickel(II) chloride, 99.99% trace metals basis | Bis(triphenylphosphine)nickel(II)chloride | NiCl2(PPh3)2 | MFCD00009592 | AC-4984 | MONONICKEL(II) BIS(TRIPHENYLPHOSPHONIUM) DICHLORIDE | Bis(triphenylphosphine)nickel(

Especificaciones y pureza

≥98%

Condiciones de almacenamiento de almacenamiento

Argon charged, Room temperature

Enviado en

Normal

Pureza

≥98%

Nombres e identificadores

• Pubchem Sid: 488189940
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488189940
• Sonrisas canónicas: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ni]Cl
• IUPAC Name: dichloronickel;triphenylphosphane
• InChIKey: ZBRJXVVKPBZPAN-UHFFFAOYSA-L
• INCHI: 1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
• Isómeros SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ni]Cl
• WGK Alemania: 3
• RTECS: QR6170000
• PubChem CID: 498315
• Peso molecular: 654.17
• Reaxy-Rn: 14619310

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Clase Benzene and substituted derivatives
      • Subclass Phenylphosphines and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Clase: Benzene and substituted derivatives
• Subclass: Phenylphosphines and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: Phenylphosphines and derivatives
• Alternative Parents: Organic phosphines and derivatives Organic transition metal salts Organopnictogen compounds Hydrocarbon derivatives
• Molecular Framework: Not available
• Substituents: Triphenylphosphine - Phenylphosphine - Phosphine - Organic metal salt - Organic transition metal salt - Organopnictogen compound - Hydrocarbon derivative - Organic salt - Organophosphorus compound - Aromatic homomonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as phenylphosphines and derivatives. These are compounds containing a phenylphosphine, which consists of phosphine substituent bound to a phenyl group.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Insoluble in water.
• Sensibilidad: air sensitive,heat sensitive,Moisture sensitive
• Punto de fusión (°C): 300°C
• Peso molecular: 654.200 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 652.055 Da
• Monoisotopic Mass: 652.055 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 41
• Formal Charge: 0
• Complexity: 204.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 3

XLogP3

Referencias

1. Jia You, Qianqian Kong, Cuiling Zhang, Yuezhong Xian.  (2022)  Designed synthesis of an sp2 carbon-conjugated fluorescent covalent organic framework for selective detection of Fe3+.  Analytical Methods,  14  (24): (2389-2395).  [PMID:35666475] [10.1039/D2AY00626J]

2. Yun Li, Yueqin Li, Nana Wang, Dong Lin, Xiaohui Liu, Yong Yang, Qinwei Gao.  (2019)  Synthesis, DNA/BSA binding studies and in vitro biological assay of nickel(II) complexes incorporating tridentate aroylhydrazone and triphenylphosphine ligands.  JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS,      [PMID:31739745] [10.1080/07391102.2019.1694995]